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Crystal structure and properties of (1,5-cyclooctadiene) (η5-pentamethylcyclopentadienyl) iridium(I) [Ir(cod)Cp*]. / Bonegardt, D. V.; Il’in, I. Yu; Sukhikh, T. S. и др.

в: Journal of Structural Chemistry, Том 58, № 5, 01.09.2017, стр. 983-988.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Bonegardt, DV, Il’in, IY, Sukhikh, TS & Morozova, NB 2017, 'Crystal structure and properties of (1,5-cyclooctadiene) (η5-pentamethylcyclopentadienyl) iridium(I) [Ir(cod)Cp*]', Journal of Structural Chemistry, Том. 58, № 5, стр. 983-988. https://doi.org/10.1134/S0022476617050183

APA

Bonegardt, D. V., Il’in, I. Y., Sukhikh, T. S., & Morozova, N. B. (2017). Crystal structure and properties of (1,5-cyclooctadiene) (η5-pentamethylcyclopentadienyl) iridium(I) [Ir(cod)Cp*]. Journal of Structural Chemistry, 58(5), 983-988. https://doi.org/10.1134/S0022476617050183

Vancouver

Bonegardt DV, Il’in IY, Sukhikh TS, Morozova NB. Crystal structure and properties of (1,5-cyclooctadiene) (η5-pentamethylcyclopentadienyl) iridium(I) [Ir(cod)Cp*]. Journal of Structural Chemistry. 2017 сент. 1;58(5):983-988. doi: 10.1134/S0022476617050183

Author

Bonegardt, D. V. ; Il’in, I. Yu ; Sukhikh, T. S. и др. / Crystal structure and properties of (1,5-cyclooctadiene) (η5-pentamethylcyclopentadienyl) iridium(I) [Ir(cod)Cp*]. в: Journal of Structural Chemistry. 2017 ; Том 58, № 5. стр. 983-988.

BibTeX

@article{8a3cae4a94524499b8f0872991c93920,
title = "Crystal structure and properties of (1,5-cyclooctadiene) (η5-pentamethylcyclopentadienyl) iridium(I) [Ir(cod)Cp*]",
abstract = "Volatile iridium(I) complexes [Ir(cod)Cpx] (Cpx = pentamethylcyclopentadienyl Cp*, ethylcyclopentadienyl CpEt, cod = 1,5-cyclooctadiene) are synthesized and characterized by IR and NMR spectroscopy. The [Ir(cod)Cp*] complex is a solid and the [Ir(cod)CpEt] complex is a liquid (SATP). The XRD method is used to determine the structure of the [Ir(cod)Cp*] complex: chemical formula C18H27Ir, space group P21/c, a = 8,4418(2) {\AA}, b = 9,4764(3) {\AA}, c = 19.2682(5) {\AA}, β = 96.128(1) °, V = 1532.61(7) {\AA}3, Z = 4, dcalc = 1.888 g/cm3, μ = 8.697 mm–1. The cyclopentadienyl ligand is η5-type coordinated; 1,5-cyclooctadiene have a cis-cis conformation and is η4-type coordinated. The thermal properties of the complexes are studied by thermogravimetry.",
keywords = "1,5-cyclooctadiene, iridium(I), pentamethylcyclopentadiene, single crystal X-ray diffraction analysis, thermogravimetry, THIN-FILMS, PRECURSOR, CHEMICAL-VAPOR-DEPOSITION, MEMORY, COMPLEXES, DIFFUSION BARRIER, TECHNOLOGY",
author = "Bonegardt, {D. V.} and Il{\textquoteright}in, {I. Yu} and Sukhikh, {T. S.} and Morozova, {N. B.}",
year = "2017",
month = sep,
day = "1",
doi = "10.1134/S0022476617050183",
language = "English",
volume = "58",
pages = "983--988",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "5",

}

RIS

TY - JOUR

T1 - Crystal structure and properties of (1,5-cyclooctadiene) (η5-pentamethylcyclopentadienyl) iridium(I) [Ir(cod)Cp*]

AU - Bonegardt, D. V.

AU - Il’in, I. Yu

AU - Sukhikh, T. S.

AU - Morozova, N. B.

PY - 2017/9/1

Y1 - 2017/9/1

N2 - Volatile iridium(I) complexes [Ir(cod)Cpx] (Cpx = pentamethylcyclopentadienyl Cp*, ethylcyclopentadienyl CpEt, cod = 1,5-cyclooctadiene) are synthesized and characterized by IR and NMR spectroscopy. The [Ir(cod)Cp*] complex is a solid and the [Ir(cod)CpEt] complex is a liquid (SATP). The XRD method is used to determine the structure of the [Ir(cod)Cp*] complex: chemical formula C18H27Ir, space group P21/c, a = 8,4418(2) Å, b = 9,4764(3) Å, c = 19.2682(5) Å, β = 96.128(1) °, V = 1532.61(7) Å3, Z = 4, dcalc = 1.888 g/cm3, μ = 8.697 mm–1. The cyclopentadienyl ligand is η5-type coordinated; 1,5-cyclooctadiene have a cis-cis conformation and is η4-type coordinated. The thermal properties of the complexes are studied by thermogravimetry.

AB - Volatile iridium(I) complexes [Ir(cod)Cpx] (Cpx = pentamethylcyclopentadienyl Cp*, ethylcyclopentadienyl CpEt, cod = 1,5-cyclooctadiene) are synthesized and characterized by IR and NMR spectroscopy. The [Ir(cod)Cp*] complex is a solid and the [Ir(cod)CpEt] complex is a liquid (SATP). The XRD method is used to determine the structure of the [Ir(cod)Cp*] complex: chemical formula C18H27Ir, space group P21/c, a = 8,4418(2) Å, b = 9,4764(3) Å, c = 19.2682(5) Å, β = 96.128(1) °, V = 1532.61(7) Å3, Z = 4, dcalc = 1.888 g/cm3, μ = 8.697 mm–1. The cyclopentadienyl ligand is η5-type coordinated; 1,5-cyclooctadiene have a cis-cis conformation and is η4-type coordinated. The thermal properties of the complexes are studied by thermogravimetry.

KW - 1,5-cyclooctadiene

KW - iridium(I)

KW - pentamethylcyclopentadiene

KW - single crystal X-ray diffraction analysis

KW - thermogravimetry

KW - THIN-FILMS

KW - PRECURSOR

KW - CHEMICAL-VAPOR-DEPOSITION

KW - MEMORY

KW - COMPLEXES

KW - DIFFUSION BARRIER

KW - TECHNOLOGY

UR - http://www.scopus.com/inward/record.url?scp=85032270371&partnerID=8YFLogxK

U2 - 10.1134/S0022476617050183

DO - 10.1134/S0022476617050183

M3 - Article

AN - SCOPUS:85032270371

VL - 58

SP - 983

EP - 988

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 5

ER -

ID: 9873849