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Coordination compounds of Co(II) and Cu(II) halides with 2,4-dimethyl-1,2,4-triazolo[1,5-a]benzimidazole. / Dyukova, I. I.; Lavrenova, L. G.; Kuz'menko, T. A. и др.

в: Inorganica Chimica Acta, Том 486, 24.02.2019, стр. 406-411.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

Dyukova, II, Lavrenova, LG, Kuz'menko, TA, Komarov, VY, Sukhikh, TS & Vorontsova, EV 2019, 'Coordination compounds of Co(II) and Cu(II) halides with 2,4-dimethyl-1,2,4-triazolo[1,5-a]benzimidazole', Inorganica Chimica Acta, Том. 486, стр. 406-411. https://doi.org/10.1016/j.ica.2018.10.064

APA

Dyukova, I. I., Lavrenova, L. G., Kuz'menko, T. A., Komarov, V. Y., Sukhikh, T. S., & Vorontsova, E. V. (2019). Coordination compounds of Co(II) and Cu(II) halides with 2,4-dimethyl-1,2,4-triazolo[1,5-a]benzimidazole. Inorganica Chimica Acta, 486, 406-411. https://doi.org/10.1016/j.ica.2018.10.064

Vancouver

Dyukova II, Lavrenova LG, Kuz'menko TA, Komarov VY, Sukhikh TS, Vorontsova EV. Coordination compounds of Co(II) and Cu(II) halides with 2,4-dimethyl-1,2,4-triazolo[1,5-a]benzimidazole. Inorganica Chimica Acta. 2019 февр. 24;486:406-411. doi: 10.1016/j.ica.2018.10.064

Author

Dyukova, I. I. ; Lavrenova, L. G. ; Kuz'menko, T. A. и др. / Coordination compounds of Co(II) and Cu(II) halides with 2,4-dimethyl-1,2,4-triazolo[1,5-a]benzimidazole. в: Inorganica Chimica Acta. 2019 ; Том 486. стр. 406-411.

BibTeX

@article{079c5d65ea7047589123d2439237a9c1,
title = "Coordination compounds of Co(II) and Cu(II) halides with 2,4-dimethyl-1,2,4-triazolo[1,5-a]benzimidazole",
abstract = "Coordination compounds based on cobalt(II) and copper(II) halides with 2,4-dimethyl-1,2,4-triazolo[1,5-a]benzimidazole (L) of composition [ML2Cl2] (where M = Co2+ (I) or Cu2+ (II)) and [CuL2Br2] (III) were synthesised. The compounds were characterised by single-crystal X-ray diffraction (XRD) analysis, UV–Vis spectroscopy (diffuse reflectance spectra, DRS) and infrared (IR) spectroscopy. Via XRD structural analysis, crystal structures were determined for [CoL2Cl2] (I), [CuL2Cl2] (II) and [Cu2L2(µ-Cl)2Cl2(H2O)2] (IIa). Cytotoxic effects of the complexes and ligand on cell line Hep-2 were studied, and it was found that the formation of a copper(II) complex with L considerably enhances cytotoxicity.",
keywords = "2,4-Dimethyl-1,2,4-triazolo[1,5-a]benzimidazole, 3d-Metal coordination compounds, Cytotoxicity, UV–Vis/IR spectroscopy, XRD structural analysis, MOLECULAR-STRUCTURE, UV-Vis/IR spectroscopy, COMPLEXES, ANTIBACTERIAL, CRYSTAL, 1,2,4-TRIAZOLE, PLATINUM(II), BENZIMIDAZOLE, IMIDAZOLE, ANTIMICROBIAL ACTIVITY, THIABENDAZOLE",
author = "Dyukova, {I. I.} and Lavrenova, {L. G.} and Kuz'menko, {T. A.} and Komarov, {V. Yu} and Sukhikh, {T. S.} and Vorontsova, {E. V.}",
note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",
year = "2019",
month = feb,
day = "24",
doi = "10.1016/j.ica.2018.10.064",
language = "English",
volume = "486",
pages = "406--411",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Coordination compounds of Co(II) and Cu(II) halides with 2,4-dimethyl-1,2,4-triazolo[1,5-a]benzimidazole

AU - Dyukova, I. I.

AU - Lavrenova, L. G.

AU - Kuz'menko, T. A.

AU - Komarov, V. Yu

AU - Sukhikh, T. S.

AU - Vorontsova, E. V.

N1 - Publisher Copyright: © 2018 Elsevier B.V.

PY - 2019/2/24

Y1 - 2019/2/24

N2 - Coordination compounds based on cobalt(II) and copper(II) halides with 2,4-dimethyl-1,2,4-triazolo[1,5-a]benzimidazole (L) of composition [ML2Cl2] (where M = Co2+ (I) or Cu2+ (II)) and [CuL2Br2] (III) were synthesised. The compounds were characterised by single-crystal X-ray diffraction (XRD) analysis, UV–Vis spectroscopy (diffuse reflectance spectra, DRS) and infrared (IR) spectroscopy. Via XRD structural analysis, crystal structures were determined for [CoL2Cl2] (I), [CuL2Cl2] (II) and [Cu2L2(µ-Cl)2Cl2(H2O)2] (IIa). Cytotoxic effects of the complexes and ligand on cell line Hep-2 were studied, and it was found that the formation of a copper(II) complex with L considerably enhances cytotoxicity.

AB - Coordination compounds based on cobalt(II) and copper(II) halides with 2,4-dimethyl-1,2,4-triazolo[1,5-a]benzimidazole (L) of composition [ML2Cl2] (where M = Co2+ (I) or Cu2+ (II)) and [CuL2Br2] (III) were synthesised. The compounds were characterised by single-crystal X-ray diffraction (XRD) analysis, UV–Vis spectroscopy (diffuse reflectance spectra, DRS) and infrared (IR) spectroscopy. Via XRD structural analysis, crystal structures were determined for [CoL2Cl2] (I), [CuL2Cl2] (II) and [Cu2L2(µ-Cl)2Cl2(H2O)2] (IIa). Cytotoxic effects of the complexes and ligand on cell line Hep-2 were studied, and it was found that the formation of a copper(II) complex with L considerably enhances cytotoxicity.

KW - 2,4-Dimethyl-1,2,4-triazolo[1,5-a]benzimidazole

KW - 3d-Metal coordination compounds

KW - Cytotoxicity

KW - UV–Vis/IR spectroscopy

KW - XRD structural analysis

KW - MOLECULAR-STRUCTURE

KW - UV-Vis/IR spectroscopy

KW - COMPLEXES

KW - ANTIBACTERIAL

KW - CRYSTAL

KW - 1,2,4-TRIAZOLE

KW - PLATINUM(II)

KW - BENZIMIDAZOLE

KW - IMIDAZOLE

KW - ANTIMICROBIAL ACTIVITY

KW - THIABENDAZOLE

UR - http://www.scopus.com/inward/record.url?scp=85056241948&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2018.10.064

DO - 10.1016/j.ica.2018.10.064

M3 - Article

AN - SCOPUS:85056241948

VL - 486

SP - 406

EP - 411

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

ER -

ID: 17407969