Coordination Chemistry: Part 1. Electronic Structure, Stability, Reaction Mechanisms, Nonaqueous Solvents

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Coordination Chemistry: Part 1. Electronic Structure, Stability, Reaction Mechanisms, Nonaqueous Solvents. / Sokolov, M. N.; Gushchin, A. L.; Samsonenko, D. G.

в: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 51, № 11, 11.2025, стр. 947-1050.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{58ae6bd0ac0f4051bf3201f159110b94,

title = "Coordination Chemistry: Part 1. Electronic Structure, Stability, Reaction Mechanisms, Nonaqueous Solvents",

abstract = "This work contains theoretical material and questions for independent study on selected topics in coordination chemistry and represents an English translation of a textbook on this subject. The material is divided into four parts. The first part addresses the electronic structure of coordination compounds based on ligand field theory and molecular orbital theory, with numerous examples drawn from the contemporary literature. This part serves as a theoretical introduction to the description of coordination compounds. The second part examines factors affecting the stability of coordination compounds, considering both metal-centered and ligand-centered contributions, as well as the principal approaches to ligand design. The third part is devoted to reaction mechanisms of coordination compounds in ligand substitution reactions and in redox processes. The fourth part discusses aspects of the synthesis and reactivity of coordination compounds in nonaqueous solvents.",

keywords = "coordination compounds, electronic structure, ligand design, ligand field theory, molecular orbital method, nonaqueous solvents, reaction mechanisms, stability of coordination compounds",

author = "Sokolov, {M. N.} and Gushchin, {A. L.} and Samsonenko, {D. G.}",

note = "Sokolov, M.N., Gushchin, A.L. & Samsonenko, D.G. Coordination Chemistry: Part 1. Electronic Structure, Stability, Reaction Mechanisms, Nonaqueous Solvents. Russ J Coord Chem 51, 947–1050 (2025).",

year = "2025",

month = nov,

doi = "10.1134/S1070328425601438",

language = "English",

volume = "51",

pages = "947--1050",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

issn = "1070-3284",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "11",

}

RIS

TY - JOUR

T1 - Coordination Chemistry: Part 1. Electronic Structure, Stability, Reaction Mechanisms, Nonaqueous Solvents

AU - Sokolov, M. N.

AU - Gushchin, A. L.

AU - Samsonenko, D. G.

N1 - Sokolov, M.N., Gushchin, A.L. & Samsonenko, D.G. Coordination Chemistry: Part 1. Electronic Structure, Stability, Reaction Mechanisms, Nonaqueous Solvents. Russ J Coord Chem 51, 947–1050 (2025).

PY - 2025/11

Y1 - 2025/11

N2 - This work contains theoretical material and questions for independent study on selected topics in coordination chemistry and represents an English translation of a textbook on this subject. The material is divided into four parts. The first part addresses the electronic structure of coordination compounds based on ligand field theory and molecular orbital theory, with numerous examples drawn from the contemporary literature. This part serves as a theoretical introduction to the description of coordination compounds. The second part examines factors affecting the stability of coordination compounds, considering both metal-centered and ligand-centered contributions, as well as the principal approaches to ligand design. The third part is devoted to reaction mechanisms of coordination compounds in ligand substitution reactions and in redox processes. The fourth part discusses aspects of the synthesis and reactivity of coordination compounds in nonaqueous solvents.

AB - This work contains theoretical material and questions for independent study on selected topics in coordination chemistry and represents an English translation of a textbook on this subject. The material is divided into four parts. The first part addresses the electronic structure of coordination compounds based on ligand field theory and molecular orbital theory, with numerous examples drawn from the contemporary literature. This part serves as a theoretical introduction to the description of coordination compounds. The second part examines factors affecting the stability of coordination compounds, considering both metal-centered and ligand-centered contributions, as well as the principal approaches to ligand design. The third part is devoted to reaction mechanisms of coordination compounds in ligand substitution reactions and in redox processes. The fourth part discusses aspects of the synthesis and reactivity of coordination compounds in nonaqueous solvents.

KW - coordination compounds

KW - electronic structure

KW - ligand design

KW - ligand field theory

KW - molecular orbital method

KW - nonaqueous solvents

KW - reaction mechanisms

KW - stability of coordination compounds

UR - https://www.scopus.com/pages/publications/105035379462

UR - https://www.mendeley.com/catalogue/aea4a2a5-b367-3cb9-a913-7e084de46e12/

U2 - 10.1134/S1070328425601438

DO - 10.1134/S1070328425601438

M3 - Article

VL - 51

SP - 947

EP - 1050

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 11

ER -

ID: 76210920