Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Conversion of nuclear spin isomers of water molecules under ultracold conditions of space. / Chapovsky, P. L.
в: Quantum Electronics, Том 49, № 5, 01.01.2019, стр. 473-478.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Conversion of nuclear spin isomers of water molecules under ultracold conditions of space
AU - Chapovsky, P. L.
N1 - Publisher Copyright: © 2019 Kvantovaya Elektronika, Turpion Ltd and IOP Publishing Ltd.
PY - 2019/1/1
Y1 - 2019/1/1
N2 - The conversion rate of nuclear spin isomers of water molecules in space is calculated using the model of quantum relaxation in the absence of particle collisions. The model is based on the intramolecular mixing of the ortho and para states of H2O by the spin-rotation interaction and on the interruption of the mixing by radiative transitions of a molecule in a thermal radiation field. The lifetime of water isomers at a thermal radiation temperature T = 50 K is ∼2 × 107 years, and at a temperature T = 100 K it is 3 × 106 years. The lifetimes of the spin isomers of water molecules are found to be large, but still smaller, for example, than the age of the Solar System. The proposed process of conversion of the spin isomers of water molecules is important for areas of space with low (n < 1 cm-3) particle concentrations.
AB - The conversion rate of nuclear spin isomers of water molecules in space is calculated using the model of quantum relaxation in the absence of particle collisions. The model is based on the intramolecular mixing of the ortho and para states of H2O by the spin-rotation interaction and on the interruption of the mixing by radiative transitions of a molecule in a thermal radiation field. The lifetime of water isomers at a thermal radiation temperature T = 50 K is ∼2 × 107 years, and at a temperature T = 100 K it is 3 × 106 years. The lifetimes of the spin isomers of water molecules are found to be large, but still smaller, for example, than the age of the Solar System. The proposed process of conversion of the spin isomers of water molecules is important for areas of space with low (n < 1 cm-3) particle concentrations.
KW - interstellar space
KW - ratio of ortho and para states of molecules in space
KW - Solar System
KW - spin isomers of water molecules
KW - CHEMISTRY
KW - DIFFUSION
KW - TRANSITIONS
UR - http://www.scopus.com/inward/record.url?scp=85067799556&partnerID=8YFLogxK
U2 - 10.1070/QEL17006
DO - 10.1070/QEL17006
M3 - Article
AN - SCOPUS:85067799556
VL - 49
SP - 473
EP - 478
JO - Quantum Electronics
JF - Quantum Electronics
SN - 1063-7818
IS - 5
ER -
ID: 20656259