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Controlling the phase behavior and ion mobility of trialkylammonium-based protic ionic liquids: the role of asymmetry. / Zhalnina, Tatiana V.; Tatarintseva, Ekaterina V.; Prikhod’ko, Sergey A. и др.

в: Physical Chemistry Chemical Physics, 2026.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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Zhalnina, Tatiana V. ; Tatarintseva, Ekaterina V. ; Prikhod’ko, Sergey A. и др. / Controlling the phase behavior and ion mobility of trialkylammonium-based protic ionic liquids: the role of asymmetry. в: Physical Chemistry Chemical Physics. 2026.

BibTeX

@article{2616c2e54fc246d98ffc1a8949447f9b,
title = "Controlling the phase behavior and ion mobility of trialkylammonium-based protic ionic liquids: the role of asymmetry",
abstract = "The size, shape, and symmetry of cations and anions in ionic liquids determine the adjustable properties of these industrially relevant liquid salts. In this work, we show how the deliberately introduced asymmetry of cations can change and even control the phase behavior and rotational diffusion in protic ionic liquids. The method of choice here is solid-state NMR spectroscopy, which provides structural and dynamic information about the heterogeneous material. In addition, we show that the chosen trialkyl ammonium-based ionic liquids are excellent model systems for studying Coulomb-enhanced hydrogen bonding and anisotropic molecular motion.",
author = "Zhalnina, {Tatiana V.} and Tatarintseva, {Ekaterina V.} and Prikhod{\textquoteright}ko, {Sergey A.} and Khudozhitkov, {Alexander E.} and Stepanov, {Alexander G.} and Kolokolov, {Daniil I.} and Ralf Ludwig",
year = "2026",
doi = "10.1039/d5cp03993b",
language = "English",
journal = "Physical Chemistry Chemical Physics",
issn = "1463-9076",
publisher = "Royal Society of Chemistry",

}

RIS

TY - JOUR

T1 - Controlling the phase behavior and ion mobility of trialkylammonium-based protic ionic liquids: the role of asymmetry

AU - Zhalnina, Tatiana V.

AU - Tatarintseva, Ekaterina V.

AU - Prikhod’ko, Sergey A.

AU - Khudozhitkov, Alexander E.

AU - Stepanov, Alexander G.

AU - Kolokolov, Daniil I.

AU - Ludwig, Ralf

PY - 2026

Y1 - 2026

N2 - The size, shape, and symmetry of cations and anions in ionic liquids determine the adjustable properties of these industrially relevant liquid salts. In this work, we show how the deliberately introduced asymmetry of cations can change and even control the phase behavior and rotational diffusion in protic ionic liquids. The method of choice here is solid-state NMR spectroscopy, which provides structural and dynamic information about the heterogeneous material. In addition, we show that the chosen trialkyl ammonium-based ionic liquids are excellent model systems for studying Coulomb-enhanced hydrogen bonding and anisotropic molecular motion.

AB - The size, shape, and symmetry of cations and anions in ionic liquids determine the adjustable properties of these industrially relevant liquid salts. In this work, we show how the deliberately introduced asymmetry of cations can change and even control the phase behavior and rotational diffusion in protic ionic liquids. The method of choice here is solid-state NMR spectroscopy, which provides structural and dynamic information about the heterogeneous material. In addition, we show that the chosen trialkyl ammonium-based ionic liquids are excellent model systems for studying Coulomb-enhanced hydrogen bonding and anisotropic molecular motion.

UR - https://www.scopus.com/pages/publications/105027337738

UR - https://www.mendeley.com/catalogue/c0a27dce-0854-311b-b5de-2a2622d55a87/

U2 - 10.1039/d5cp03993b

DO - 10.1039/d5cp03993b

M3 - Article

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

SN - 1463-9076

ER -

ID: 74197320