Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Configurational Stability of 1,1′-Bi-2-naphthol in Superacid System HSO3F–SbF5–SO2ClF. / Salnikov, G. E.; Genaev, A. M.; Shernyukov, A. V. и др.
в: Russian Journal of Organic Chemistry, Том 54, № 5, 01.05.2018, стр. 792-794.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Configurational Stability of 1,1′-Bi-2-naphthol in Superacid System HSO3F–SbF5–SO2ClF
AU - Salnikov, G. E.
AU - Genaev, A. M.
AU - Shernyukov, A. V.
AU - Zhu, Z.
AU - Tkachenko, N. V.
AU - Koltunov, K. Yu
N1 - Publisher Copyright: © 2018, Pleiades Publishing, Ltd.
PY - 2018/5/1
Y1 - 2018/5/1
N2 - Although 1,1′-bi-2-naphthol (BINOL) is known to racemize in aqueous mineral acids and much more readily in superacids, it retains its initial configuration in one of the strongest superacid system, HSO3F-SbF5-SO2ClF due to protective C8,C8′-diprotonation.
AB - Although 1,1′-bi-2-naphthol (BINOL) is known to racemize in aqueous mineral acids and much more readily in superacids, it retains its initial configuration in one of the strongest superacid system, HSO3F-SbF5-SO2ClF due to protective C8,C8′-diprotonation.
UR - http://www.scopus.com/inward/record.url?scp=85049154732&partnerID=8YFLogxK
U2 - 10.1134/S1070428018050214
DO - 10.1134/S1070428018050214
M3 - Article
AN - SCOPUS:85049154732
VL - 54
SP - 792
EP - 794
JO - Russian Journal of Organic Chemistry
JF - Russian Journal of Organic Chemistry
SN - 1070-4280
IS - 5
ER -
ID: 14277573