Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Compressibility and pressure-induced structural evolution of kokchetavite, hexagonal polymorph of KAlSi3O8, by single-crystal X-ray diffraction. / Romanenko, Alexandr V.; Rashchenko, Sergey V.; Korsakov, Andrey V. и др.
в: American Mineralogist, Том 109, № 7, 07.2024, стр. 1284-1291.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Compressibility and pressure-induced structural evolution of kokchetavite, hexagonal polymorph of KAlSi3O8, by single-crystal X-ray diffraction
AU - Romanenko, Alexandr V.
AU - Rashchenko, Sergey V.
AU - Korsakov, Andrey V.
AU - Sokol, Alexander G.
AU - Kokh, Konstantin A.
PY - 2024/7
Y1 - 2024/7
N2 - Compressibility and pressure-induced structural evolution of kokchetavite, the hexagonal polymorph of KAlSi3O8, has been studied up to 11.8 GPa using synchrotron single-crystal X-ray diffraction. Two phase transitions were observed at pressures of ~0.3 and 10.4 GPa. Kokchetavite-I (as-synthesized, P6/mcc) transforms into kokchetavite-II with the P6c2 space group. Kokchetavite-II → kokchetavite-III phase transition at ~10.4 GPa is accompanied by a change of symmetry to probably orthorhombic. After pressure release, kokchetavite reverts to the initial single-crystal state with P6/mcc space group. A second-order Birch-Murnaghan equation of state was calculated for phase kokchetavite-II with coefficients V0 = 1486(3) Å3, K0 = 59(2) GPa.
AB - Compressibility and pressure-induced structural evolution of kokchetavite, the hexagonal polymorph of KAlSi3O8, has been studied up to 11.8 GPa using synchrotron single-crystal X-ray diffraction. Two phase transitions were observed at pressures of ~0.3 and 10.4 GPa. Kokchetavite-I (as-synthesized, P6/mcc) transforms into kokchetavite-II with the P6c2 space group. Kokchetavite-II → kokchetavite-III phase transition at ~10.4 GPa is accompanied by a change of symmetry to probably orthorhombic. After pressure release, kokchetavite reverts to the initial single-crystal state with P6/mcc space group. A second-order Birch-Murnaghan equation of state was calculated for phase kokchetavite-II with coefficients V0 = 1486(3) Å3, K0 = 59(2) GPa.
KW - K-cymrite
KW - KAlSi3O8
KW - Kokchetavite
KW - feldspar polymorphism
KW - high-pressure crystallography
KW - synchrotron X-ray diffraction
UR - https://www.mendeley.com/catalogue/b1a5f05f-4648-37fa-9305-928af2afc324/
U2 - 10.2138/am-2023-9120
DO - 10.2138/am-2023-9120
M3 - Article
VL - 109
SP - 1284
EP - 1291
JO - American Mineralogist
JF - American Mineralogist
SN - 0003-004X
IS - 7
ER -
ID: 60863351