Standard

Composite Rh/Zr0.25Ce0.75O2-δ-ƞ-Al2O3/Fecralloy wire mesh honeycomb module for natural gas, LPG and diesel catalytic conversion to syngas. / Shoynkhorova, T. B.; Rogozhnikov, V. N.; Ruban, N. V. и др.

в: International Journal of Hydrogen Energy, Том 44, № 20, 19.04.2019, стр. 9941-9948.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

Shoynkhorova, TB, Rogozhnikov, VN, Ruban, NV, Shilov, VA, Potemkin, DI, Simonov, PA, Belyaev, VD, Snytnikov, PV & Sobyanin, VA 2019, 'Composite Rh/Zr0.25Ce0.75O2-δ-ƞ-Al2O3/Fecralloy wire mesh honeycomb module for natural gas, LPG and diesel catalytic conversion to syngas', International Journal of Hydrogen Energy, Том. 44, № 20, стр. 9941-9948. https://doi.org/10.1016/j.ijhydene.2018.12.148

APA

Shoynkhorova, T. B., Rogozhnikov, V. N., Ruban, N. V., Shilov, V. A., Potemkin, D. I., Simonov, P. A., Belyaev, V. D., Snytnikov, P. V., & Sobyanin, V. A. (2019). Composite Rh/Zr0.25Ce0.75O2-δ-ƞ-Al2O3/Fecralloy wire mesh honeycomb module for natural gas, LPG and diesel catalytic conversion to syngas. International Journal of Hydrogen Energy, 44(20), 9941-9948. https://doi.org/10.1016/j.ijhydene.2018.12.148

Vancouver

Shoynkhorova TB, Rogozhnikov VN, Ruban NV, Shilov VA, Potemkin DI, Simonov PA и др. Composite Rh/Zr0.25Ce0.75O2-δ-ƞ-Al2O3/Fecralloy wire mesh honeycomb module for natural gas, LPG and diesel catalytic conversion to syngas. International Journal of Hydrogen Energy. 2019 апр. 19;44(20):9941-9948. doi: 10.1016/j.ijhydene.2018.12.148

Author

Shoynkhorova, T. B. ; Rogozhnikov, V. N. ; Ruban, N. V. и др. / Composite Rh/Zr0.25Ce0.75O2-δ-ƞ-Al2O3/Fecralloy wire mesh honeycomb module for natural gas, LPG and diesel catalytic conversion to syngas. в: International Journal of Hydrogen Energy. 2019 ; Том 44, № 20. стр. 9941-9948.

BibTeX

@article{29127736ab374ce793aa9ef5b638edad,
title = "Composite Rh/Zr0.25Ce0.75O2-δ-ƞ-Al2O3/Fecralloy wire mesh honeycomb module for natural gas, LPG and diesel catalytic conversion to syngas",
abstract = "The reactions of catalytic autothermal and steam conversion of n – C16H34 (model compound simulating diesel fuel), and partial oxidation of natural gas and LPG were studied using 0.24wt%Rh/(12wt%Zr0.25Ce0.75O2-δ-ƞ-Al2O3)/Fecralloy wire mesh honeycomb modules. The experiments were carried out in a flow setup in the temperature range of 550–960 °C and at atmospheric pressure. It was shown that the observed syngas (CO + H2) productivities were 65 and 53 m3Lcat−1h−1 (STP) at GHSV of 100,000 and 80,000 h−1 in natural gas and liquid petroleum gas catalytic partial oxidation processes, respectively. The product distributions were still close to the calculated equilibrium values. The catalyst activity was very high and, potentially, the maximum syngas productivity may even exceed experimentally demonstrated values. It was shown also that 0.24wt%Rh/(12wt%Zr0.25Ce0.75O2-δ-ƞ-Al2O3)/Fecralloy catalyst provided complete n-hexadecane conversion with the maximum syngas (CO + H2) productivity of 6.2 m3Lcat−1h−1 (STP) at GHSV of 13,300 h−1. The proposed concept of hydrogen-rich gas production from various hydrocarbon feedstocks in a multi-fuel catalytic reformer over single composite catalyst was proved feasible. The produced synthesis gas can be supplied as a fuel for power generation units based on high-temperature solid oxide fuel cells.",
keywords = "Hexadecane, Liquid petroleum gas, Natural gas, Partial oxidation, Steam and autothermal reforming, Structured catalyst, STEAM, CO, REACTOR, LA, RH, FUEL, HYDROGEN-PRODUCTION, PARTIAL OXIDATION",
author = "Shoynkhorova, {T. B.} and Rogozhnikov, {V. N.} and Ruban, {N. V.} and Shilov, {V. A.} and Potemkin, {D. I.} and Simonov, {P. A.} and Belyaev, {V. D.} and Snytnikov, {P. V.} and Sobyanin, {V. A.}",
note = "Publisher Copyright: {\textcopyright} 2018 Hydrogen Energy Publications LLC",
year = "2019",
month = apr,
day = "19",
doi = "10.1016/j.ijhydene.2018.12.148",
language = "English",
volume = "44",
pages = "9941--9948",
journal = "International Journal of Hydrogen Energy",
issn = "0360-3199",
publisher = "Elsevier Ltd",
number = "20",

}

RIS

TY - JOUR

T1 - Composite Rh/Zr0.25Ce0.75O2-δ-ƞ-Al2O3/Fecralloy wire mesh honeycomb module for natural gas, LPG and diesel catalytic conversion to syngas

AU - Shoynkhorova, T. B.

AU - Rogozhnikov, V. N.

AU - Ruban, N. V.

AU - Shilov, V. A.

AU - Potemkin, D. I.

AU - Simonov, P. A.

AU - Belyaev, V. D.

AU - Snytnikov, P. V.

AU - Sobyanin, V. A.

N1 - Publisher Copyright: © 2018 Hydrogen Energy Publications LLC

PY - 2019/4/19

Y1 - 2019/4/19

N2 - The reactions of catalytic autothermal and steam conversion of n – C16H34 (model compound simulating diesel fuel), and partial oxidation of natural gas and LPG were studied using 0.24wt%Rh/(12wt%Zr0.25Ce0.75O2-δ-ƞ-Al2O3)/Fecralloy wire mesh honeycomb modules. The experiments were carried out in a flow setup in the temperature range of 550–960 °C and at atmospheric pressure. It was shown that the observed syngas (CO + H2) productivities were 65 and 53 m3Lcat−1h−1 (STP) at GHSV of 100,000 and 80,000 h−1 in natural gas and liquid petroleum gas catalytic partial oxidation processes, respectively. The product distributions were still close to the calculated equilibrium values. The catalyst activity was very high and, potentially, the maximum syngas productivity may even exceed experimentally demonstrated values. It was shown also that 0.24wt%Rh/(12wt%Zr0.25Ce0.75O2-δ-ƞ-Al2O3)/Fecralloy catalyst provided complete n-hexadecane conversion with the maximum syngas (CO + H2) productivity of 6.2 m3Lcat−1h−1 (STP) at GHSV of 13,300 h−1. The proposed concept of hydrogen-rich gas production from various hydrocarbon feedstocks in a multi-fuel catalytic reformer over single composite catalyst was proved feasible. The produced synthesis gas can be supplied as a fuel for power generation units based on high-temperature solid oxide fuel cells.

AB - The reactions of catalytic autothermal and steam conversion of n – C16H34 (model compound simulating diesel fuel), and partial oxidation of natural gas and LPG were studied using 0.24wt%Rh/(12wt%Zr0.25Ce0.75O2-δ-ƞ-Al2O3)/Fecralloy wire mesh honeycomb modules. The experiments were carried out in a flow setup in the temperature range of 550–960 °C and at atmospheric pressure. It was shown that the observed syngas (CO + H2) productivities were 65 and 53 m3Lcat−1h−1 (STP) at GHSV of 100,000 and 80,000 h−1 in natural gas and liquid petroleum gas catalytic partial oxidation processes, respectively. The product distributions were still close to the calculated equilibrium values. The catalyst activity was very high and, potentially, the maximum syngas productivity may even exceed experimentally demonstrated values. It was shown also that 0.24wt%Rh/(12wt%Zr0.25Ce0.75O2-δ-ƞ-Al2O3)/Fecralloy catalyst provided complete n-hexadecane conversion with the maximum syngas (CO + H2) productivity of 6.2 m3Lcat−1h−1 (STP) at GHSV of 13,300 h−1. The proposed concept of hydrogen-rich gas production from various hydrocarbon feedstocks in a multi-fuel catalytic reformer over single composite catalyst was proved feasible. The produced synthesis gas can be supplied as a fuel for power generation units based on high-temperature solid oxide fuel cells.

KW - Hexadecane

KW - Liquid petroleum gas

KW - Natural gas

KW - Partial oxidation

KW - Steam and autothermal reforming

KW - Structured catalyst

KW - STEAM

KW - CO

KW - REACTOR

KW - LA

KW - RH

KW - FUEL

KW - HYDROGEN-PRODUCTION

KW - PARTIAL OXIDATION

UR - http://www.scopus.com/inward/record.url?scp=85059743979&partnerID=8YFLogxK

U2 - 10.1016/j.ijhydene.2018.12.148

DO - 10.1016/j.ijhydene.2018.12.148

M3 - Article

AN - SCOPUS:85059743979

VL - 44

SP - 9941

EP - 9948

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

SN - 0360-3199

IS - 20

ER -

ID: 18110827