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Cobalt(II) Complexes with Fluorinated β-Diketones and Their Derivatives for MOCVD Applications. / Dorovskikh, S. I.; Sukhikh, A. S.; Yatygin, V. A. и др.

в: Russian Journal of General Chemistry, Том 95, № 3, 27.03.2025, стр. 690-703.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

Dorovskikh, SI, Sukhikh, AS, Yatygin, VA, Turgambaeva, AE, Maximovskiy, EA, Pishchur, DP & Vikulova, ES 2025, 'Cobalt(II) Complexes with Fluorinated β-Diketones and Their Derivatives for MOCVD Applications', Russian Journal of General Chemistry, Том. 95, № 3, стр. 690-703. https://doi.org/10.1134/S1070363224613292

APA

Dorovskikh, S. I., Sukhikh, A. S., Yatygin, V. A., Turgambaeva, A. E., Maximovskiy, E. A., Pishchur, D. P., & Vikulova, E. S. (2025). Cobalt(II) Complexes with Fluorinated β-Diketones and Their Derivatives for MOCVD Applications. Russian Journal of General Chemistry, 95(3), 690-703. https://doi.org/10.1134/S1070363224613292

Vancouver

Dorovskikh SI, Sukhikh AS, Yatygin VA, Turgambaeva AE, Maximovskiy EA, Pishchur DP и др. Cobalt(II) Complexes with Fluorinated β-Diketones and Their Derivatives for MOCVD Applications. Russian Journal of General Chemistry. 2025 март 27;95(3):690-703. doi: 10.1134/S1070363224613292

Author

Dorovskikh, S. I. ; Sukhikh, A. S. ; Yatygin, V. A. и др. / Cobalt(II) Complexes with Fluorinated β-Diketones and Their Derivatives for MOCVD Applications. в: Russian Journal of General Chemistry. 2025 ; Том 95, № 3. стр. 690-703.

BibTeX

@article{302394baa0434dc69997771f513cf40c,
title = "Cobalt(II) Complexes with Fluorinated β-Diketones and Their Derivatives for MOCVD Applications",
abstract = "Abstract: A series of new volatile cobalt(II) chelates with ligands containing an extended perfluoroalkyl group, [CH3C(X)CHC(O)R]–, R = C2F5, X = O (L1) or NH (NL1); R = C3F7, X = O (L2) or NH (NL2), were obtained via a salt metathesis reaction. Elemental analysis and IR spectroscopy were used to confirm the formation of heteroligand complexes [Со(H2O)2(L1)2] and [Со(H2O)2(L2)2]·nH2O (n = 1, 2) in the case of β-diketonates, while homoligand complexes [Со(NL1)2] and [Со(NL2)2] were obtained for β-iminoketonates. Single-crystal X-ray diffraction revealed the structures of [Со(CH3OH)2(L1)2] (Im, CCDC 2374366) and [Со(H2O)2(L2)2]·H2O (CCDC 2374367), and comparison with related compounds allowed for the identification of specific structural features of heteroligand cobalt(II) complexes. The thermal behavior of the synthesized complexes was investigated using thermogravimetry and differential scanning calorimetry. The feasibility of chemical vapor deposition of Cо3О4 nanomaterials from [Со(NL1)2]. was demonstrated. The obtained samples were characterized by X-ray phase analysis, Raman spectroscopy, and scanning electron microscopy.",
keywords = "Co3O4 films, DSC, MOCVD, XRD, cobalt(II) complexes, fluorinated β-diketones, fluorinated β-iminoketones, thermogravimetry",
author = "Dorovskikh, {S. I.} and Sukhikh, {A. S.} and Yatygin, {V. A.} and Turgambaeva, {A. E.} and Maximovskiy, {E. A.} and Pishchur, {D. P.} and Vikulova, {E. S.}",
note = "The study was funded by the Russian Science Foundation, grant 24-79-10272 (https://rscf.ru/project/24-79-10272/).",
year = "2025",
month = mar,
day = "27",
doi = "10.1134/S1070363224613292",
language = "English",
volume = "95",
pages = "690--703",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "3",

}

RIS

TY - JOUR

T1 - Cobalt(II) Complexes with Fluorinated β-Diketones and Their Derivatives for MOCVD Applications

AU - Dorovskikh, S. I.

AU - Sukhikh, A. S.

AU - Yatygin, V. A.

AU - Turgambaeva, A. E.

AU - Maximovskiy, E. A.

AU - Pishchur, D. P.

AU - Vikulova, E. S.

N1 - The study was funded by the Russian Science Foundation, grant 24-79-10272 (https://rscf.ru/project/24-79-10272/).

PY - 2025/3/27

Y1 - 2025/3/27

N2 - Abstract: A series of new volatile cobalt(II) chelates with ligands containing an extended perfluoroalkyl group, [CH3C(X)CHC(O)R]–, R = C2F5, X = O (L1) or NH (NL1); R = C3F7, X = O (L2) or NH (NL2), were obtained via a salt metathesis reaction. Elemental analysis and IR spectroscopy were used to confirm the formation of heteroligand complexes [Со(H2O)2(L1)2] and [Со(H2O)2(L2)2]·nH2O (n = 1, 2) in the case of β-diketonates, while homoligand complexes [Со(NL1)2] and [Со(NL2)2] were obtained for β-iminoketonates. Single-crystal X-ray diffraction revealed the structures of [Со(CH3OH)2(L1)2] (Im, CCDC 2374366) and [Со(H2O)2(L2)2]·H2O (CCDC 2374367), and comparison with related compounds allowed for the identification of specific structural features of heteroligand cobalt(II) complexes. The thermal behavior of the synthesized complexes was investigated using thermogravimetry and differential scanning calorimetry. The feasibility of chemical vapor deposition of Cо3О4 nanomaterials from [Со(NL1)2]. was demonstrated. The obtained samples were characterized by X-ray phase analysis, Raman spectroscopy, and scanning electron microscopy.

AB - Abstract: A series of new volatile cobalt(II) chelates with ligands containing an extended perfluoroalkyl group, [CH3C(X)CHC(O)R]–, R = C2F5, X = O (L1) or NH (NL1); R = C3F7, X = O (L2) or NH (NL2), were obtained via a salt metathesis reaction. Elemental analysis and IR spectroscopy were used to confirm the formation of heteroligand complexes [Со(H2O)2(L1)2] and [Со(H2O)2(L2)2]·nH2O (n = 1, 2) in the case of β-diketonates, while homoligand complexes [Со(NL1)2] and [Со(NL2)2] were obtained for β-iminoketonates. Single-crystal X-ray diffraction revealed the structures of [Со(CH3OH)2(L1)2] (Im, CCDC 2374366) and [Со(H2O)2(L2)2]·H2O (CCDC 2374367), and comparison with related compounds allowed for the identification of specific structural features of heteroligand cobalt(II) complexes. The thermal behavior of the synthesized complexes was investigated using thermogravimetry and differential scanning calorimetry. The feasibility of chemical vapor deposition of Cо3О4 nanomaterials from [Со(NL1)2]. was demonstrated. The obtained samples were characterized by X-ray phase analysis, Raman spectroscopy, and scanning electron microscopy.

KW - Co3O4 films

KW - DSC

KW - MOCVD

KW - XRD

KW - cobalt(II) complexes

KW - fluorinated β-diketones

KW - fluorinated β-iminoketones

KW - thermogravimetry

UR - https://www.mendeley.com/catalogue/09bd01f9-04f4-32f6-bd02-bd1468ae6493/

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-105001165326&origin=inward&txGid=b23b9c353062f673db2d617e16d775ae

U2 - 10.1134/S1070363224613292

DO - 10.1134/S1070363224613292

M3 - Article

VL - 95

SP - 690

EP - 703

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 3

ER -

ID: 65140023