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Cobalt(II) and Copper(II) Complexes with New Ditopic Ligand 5-(2-(1H-Tetrazol-1-yl)phenyl)-1H-tetrazole: Synthesis and Properties. / Lavrenova, L. G.; Grigor’ev, E. Yu; Komarov, V. Yu и др.

в: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 49, № 2, 02.2023, стр. 86-96.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

Lavrenova, LG, Grigor’ev, EY, Komarov, VY, Glinskaya, LA, Lavrov, AN & Grigor’ev, YV 2023, 'Cobalt(II) and Copper(II) Complexes with New Ditopic Ligand 5-(2-(1H-Tetrazol-1-yl)phenyl)-1H-tetrazole: Synthesis and Properties', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том. 49, № 2, стр. 86-96. https://doi.org/10.1134/S1070328422700294

APA

Lavrenova, L. G., Grigor’ev, E. Y., Komarov, V. Y., Glinskaya, L. A., Lavrov, A. N., & Grigor’ev, Y. V. (2023). Cobalt(II) and Copper(II) Complexes with New Ditopic Ligand 5-(2-(1H-Tetrazol-1-yl)phenyl)-1H-tetrazole: Synthesis and Properties. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 49(2), 86-96. https://doi.org/10.1134/S1070328422700294

Vancouver

Lavrenova LG, Grigor’ev EY, Komarov VY, Glinskaya LA, Lavrov AN, Grigor’ev YV. Cobalt(II) and Copper(II) Complexes with New Ditopic Ligand 5-(2-(1H-Tetrazol-1-yl)phenyl)-1H-tetrazole: Synthesis and Properties. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2023 февр.;49(2):86-96. doi: 10.1134/S1070328422700294

Author

Lavrenova, L. G. ; Grigor’ev, E. Yu ; Komarov, V. Yu и др. / Cobalt(II) and Copper(II) Complexes with New Ditopic Ligand 5-(2-(1H-Tetrazol-1-yl)phenyl)-1H-tetrazole: Synthesis and Properties. в: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2023 ; Том 49, № 2. стр. 86-96.

BibTeX

@article{e28e26274f4742af9dabfa89d22fe6fc,
title = "Cobalt(II) and Copper(II) Complexes with New Ditopic Ligand 5-(2-(1H-Tetrazol-1-yl)phenyl)-1H-tetrazole: Synthesis and Properties",
abstract = "A procedure for the synthesis of the new ditopic ligand combining in the structure 1- and 5-substituted tetrazolyl cycles, 5-(2-(1H-tetrazol-1-yl)phenyl)-1H-tetrazole (HL), is developed. The coordination compounds of Co(II) and Cu(II) halides [Co(HL)2Cl2], [Cu(HL)2Cl2], [Cu(HL)2Br2], and [CuL2(H2O)]n based on ligand HL are synthesized. The complexes are studied by elemental analysis, diffuse reflectance spectroscopy, IR spectroscopy, X-ray diffraction (XRD), and static magnetic susceptibility. The crystal structure of the molecular coordination polymer [CuL2(H2O)]n is determined by XRD (CIF file CCDC no. 2127210). The temperature and field dependences of the magnetization show that the magnetic properties of the synthesized Cu(II) complexes are due to exchange interactions in one-dimensional chains of the copper ions (S = 1/2). For complex [Cu(HL)2Br2], the parameters are shifted toward the enhancement of the antiferromagnetic interaction compared to the analog containing the chloride ion.",
keywords = "5-(2-(1H-tetrazol-1-yl)phenyl)-1H-tetrazole, IR spectroscopy, XRD, cobalt(II) and copper(II) complexes, diffuse reflectance spectroscopy, magnetic activity, synthesis",
author = "Lavrenova, {L. G.} and Grigor{\textquoteright}ev, {E. Yu} and Komarov, {V. Yu} and Glinskaya, {L. A.} and Lavrov, {A. N.} and Grigor{\textquoteright}ev, {Yu V.}",
note = "This work was supported by the Russian Science Foundation (project no. 20-63-46026, magnetic properties) and Ministry of Science and Higher Education of the Russian Federation (projects nos. 121031700313-8 and 21031700314-5, synthesis and structure). Публикация для корректировки.",
year = "2023",
month = feb,
doi = "10.1134/S1070328422700294",
language = "English",
volume = "49",
pages = "86--96",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "2",

}

RIS

TY - JOUR

T1 - Cobalt(II) and Copper(II) Complexes with New Ditopic Ligand 5-(2-(1H-Tetrazol-1-yl)phenyl)-1H-tetrazole: Synthesis and Properties

AU - Lavrenova, L. G.

AU - Grigor’ev, E. Yu

AU - Komarov, V. Yu

AU - Glinskaya, L. A.

AU - Lavrov, A. N.

AU - Grigor’ev, Yu V.

N1 - This work was supported by the Russian Science Foundation (project no. 20-63-46026, magnetic properties) and Ministry of Science and Higher Education of the Russian Federation (projects nos. 121031700313-8 and 21031700314-5, synthesis and structure). Публикация для корректировки.

PY - 2023/2

Y1 - 2023/2

N2 - A procedure for the synthesis of the new ditopic ligand combining in the structure 1- and 5-substituted tetrazolyl cycles, 5-(2-(1H-tetrazol-1-yl)phenyl)-1H-tetrazole (HL), is developed. The coordination compounds of Co(II) and Cu(II) halides [Co(HL)2Cl2], [Cu(HL)2Cl2], [Cu(HL)2Br2], and [CuL2(H2O)]n based on ligand HL are synthesized. The complexes are studied by elemental analysis, diffuse reflectance spectroscopy, IR spectroscopy, X-ray diffraction (XRD), and static magnetic susceptibility. The crystal structure of the molecular coordination polymer [CuL2(H2O)]n is determined by XRD (CIF file CCDC no. 2127210). The temperature and field dependences of the magnetization show that the magnetic properties of the synthesized Cu(II) complexes are due to exchange interactions in one-dimensional chains of the copper ions (S = 1/2). For complex [Cu(HL)2Br2], the parameters are shifted toward the enhancement of the antiferromagnetic interaction compared to the analog containing the chloride ion.

AB - A procedure for the synthesis of the new ditopic ligand combining in the structure 1- and 5-substituted tetrazolyl cycles, 5-(2-(1H-tetrazol-1-yl)phenyl)-1H-tetrazole (HL), is developed. The coordination compounds of Co(II) and Cu(II) halides [Co(HL)2Cl2], [Cu(HL)2Cl2], [Cu(HL)2Br2], and [CuL2(H2O)]n based on ligand HL are synthesized. The complexes are studied by elemental analysis, diffuse reflectance spectroscopy, IR spectroscopy, X-ray diffraction (XRD), and static magnetic susceptibility. The crystal structure of the molecular coordination polymer [CuL2(H2O)]n is determined by XRD (CIF file CCDC no. 2127210). The temperature and field dependences of the magnetization show that the magnetic properties of the synthesized Cu(II) complexes are due to exchange interactions in one-dimensional chains of the copper ions (S = 1/2). For complex [Cu(HL)2Br2], the parameters are shifted toward the enhancement of the antiferromagnetic interaction compared to the analog containing the chloride ion.

KW - 5-(2-(1H-tetrazol-1-yl)phenyl)-1H-tetrazole

KW - IR spectroscopy

KW - XRD

KW - cobalt(II) and copper(II) complexes

KW - diffuse reflectance spectroscopy

KW - magnetic activity

KW - synthesis

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85160019682&origin=inward&txGid=80ba5f14cc218cc86ed2050cc7928dee

UR - https://www.mendeley.com/catalogue/557d47cb-a5a4-3989-a07e-284275dedc11/

U2 - 10.1134/S1070328422700294

DO - 10.1134/S1070328422700294

M3 - Article

VL - 49

SP - 86

EP - 96

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 2

ER -

ID: 59663318