TY - JOUR

T1 - Cluster aqua/hydroxocomplexes supporting extended hydrogen bonding networks. Preparation and structure of a unique series of cluster hydrates [Mo6I8(OH)4(H2O)2]·nH2O (n = 2, 12, 14)

AU - Mikhaylov, Maxim A.

AU - Abramov, Pavel A.

AU - Komarov, Vladislav Y.

AU - Sokolov, Maxim N.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - Isolation and structural characterization of three hydrates of a unique series of cluster hydrates [Mo6I8(OH)4(H2O)2]·nH2O (n = 14 (h14), 12 (h12), 2 (h2)) by controlled hydrolysis of [K(diglyme)(CH3CN)]2[Mo6I14] in borate buffer solutions is reported. The structures of h14 and h12 feature three-dimensional hydrogen bond-based frameworks. In particular, the framework in h12 is close to the frameworks observed in classical clathrate hydrates. In the structure of h2 the water of crystallization forms discrete (H2O)2 dimers.

AB - Isolation and structural characterization of three hydrates of a unique series of cluster hydrates [Mo6I8(OH)4(H2O)2]·nH2O (n = 14 (h14), 12 (h12), 2 (h2)) by controlled hydrolysis of [K(diglyme)(CH3CN)]2[Mo6I14] in borate buffer solutions is reported. The structures of h14 and h12 feature three-dimensional hydrogen bond-based frameworks. In particular, the framework in h12 is close to the frameworks observed in classical clathrate hydrates. In the structure of h2 the water of crystallization forms discrete (H2O)2 dimers.

KW - Aquacomplexes

KW - Clathrate

KW - Hydrates

KW - Hydrolysis

KW - Octahedral Mo clusters

KW - BR

KW - SE

KW - LUMINESCENCE

KW - BRIDGING LIGAND

KW - COMPLEXES

KW - CL

KW - FAMILY

UR - http://www.scopus.com/inward/record.url?scp=85010917070&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2016.11.011

DO - 10.1016/j.poly.2016.11.011

M3 - Article

AN - SCOPUS:85010917070

VL - 122

SP - 241

EP - 246

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

ER -