Standard

Chiral quaternized nopinane-annelated 4,5-diazafluorenes: electrochemical and photochemical properties. / Vasilyev, Eugene S.; Trenikhin, Ivan A.; Matrosov, Grigoriy A. и др.

в: Journal of Molecular Structure, Том 1342, 142718, 15.10.2025.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Vasilyev, ES, Trenikhin, IA, Matrosov, GA, Artyukha, EA, Zaikin, PA, Mikheilis, AV, Agafontsev, AM, Rybalova, TV & Tkachev, AV 2025, 'Chiral quaternized nopinane-annelated 4,5-diazafluorenes: electrochemical and photochemical properties', Journal of Molecular Structure, Том. 1342, 142718. https://doi.org/10.1016/j.molstruc.2025.142718

APA

Vasilyev, E. S., Trenikhin, I. A., Matrosov, G. A., Artyukha, E. A., Zaikin, P. A., Mikheilis, A. V., Agafontsev, A. M., Rybalova, T. V., & Tkachev, A. V. (2025). Chiral quaternized nopinane-annelated 4,5-diazafluorenes: electrochemical and photochemical properties. Journal of Molecular Structure, 1342, [142718]. https://doi.org/10.1016/j.molstruc.2025.142718

Vancouver

Vasilyev ES, Trenikhin IA, Matrosov GA, Artyukha EA, Zaikin PA, Mikheilis AV и др. Chiral quaternized nopinane-annelated 4,5-diazafluorenes: electrochemical and photochemical properties. Journal of Molecular Structure. 2025 окт. 15;1342:142718. doi: 10.1016/j.molstruc.2025.142718

Author

Vasilyev, Eugene S. ; Trenikhin, Ivan A. ; Matrosov, Grigoriy A. и др. / Chiral quaternized nopinane-annelated 4,5-diazafluorenes: electrochemical and photochemical properties. в: Journal of Molecular Structure. 2025 ; Том 1342.

BibTeX

@article{2e3e09f6749d4166b3a08f4f6cf41eb2,
title = "Chiral quaternized nopinane-annelated 4,5-diazafluorenes: electrochemical and photochemical properties",
abstract = "Nopinane-annelated 4,5-diazafluorene and its derivatives can be easily converted into its mono- and diquaternized derivatives by reaction with methyl iodide and 1,2-dibromoethane respectively. 9,9-Dimethylated diquaternized dibromide salt has been converted into PF6-salt by anion-exchange reaction. The chemical structures of new compounds were proven by spectroscopic methods and X-ray study. Electrochemical and photophysical studies for diquaternized compounds were made. PF6-salt of dimethyldiazafluorene derivative demonstrates two-step reversible electrochemical reduction.",
keywords = "4,5-diazafluorene, 4,5-diazafluorenone, Diquats, Nopinane, Quats",
author = "Vasilyev, {Eugene S.} and Trenikhin, {Ivan A.} and Matrosov, {Grigoriy A.} and Artyukha, {Ekaterina A.} and Zaikin, {Pavel A.} and Mikheilis, {Alexandr V.} and Agafontsev, {Alexander M.} and Rybalova, {Tatyana V.} and Tkachev, {Alexey V.}",
note = "This work was supported by Russian Science Foundation Grant 23-73-10157. ",
year = "2025",
month = oct,
day = "15",
doi = "10.1016/j.molstruc.2025.142718",
language = "English",
volume = "1342",
journal = "Journal of Molecular Structure",
issn = "0022-2860",
publisher = "Elsevier Science Publishing Company, Inc.",

}

RIS

TY - JOUR

T1 - Chiral quaternized nopinane-annelated 4,5-diazafluorenes: electrochemical and photochemical properties

AU - Vasilyev, Eugene S.

AU - Trenikhin, Ivan A.

AU - Matrosov, Grigoriy A.

AU - Artyukha, Ekaterina A.

AU - Zaikin, Pavel A.

AU - Mikheilis, Alexandr V.

AU - Agafontsev, Alexander M.

AU - Rybalova, Tatyana V.

AU - Tkachev, Alexey V.

N1 - This work was supported by Russian Science Foundation Grant 23-73-10157.

PY - 2025/10/15

Y1 - 2025/10/15

N2 - Nopinane-annelated 4,5-diazafluorene and its derivatives can be easily converted into its mono- and diquaternized derivatives by reaction with methyl iodide and 1,2-dibromoethane respectively. 9,9-Dimethylated diquaternized dibromide salt has been converted into PF6-salt by anion-exchange reaction. The chemical structures of new compounds were proven by spectroscopic methods and X-ray study. Electrochemical and photophysical studies for diquaternized compounds were made. PF6-salt of dimethyldiazafluorene derivative demonstrates two-step reversible electrochemical reduction.

AB - Nopinane-annelated 4,5-diazafluorene and its derivatives can be easily converted into its mono- and diquaternized derivatives by reaction with methyl iodide and 1,2-dibromoethane respectively. 9,9-Dimethylated diquaternized dibromide salt has been converted into PF6-salt by anion-exchange reaction. The chemical structures of new compounds were proven by spectroscopic methods and X-ray study. Electrochemical and photophysical studies for diquaternized compounds were made. PF6-salt of dimethyldiazafluorene derivative demonstrates two-step reversible electrochemical reduction.

KW - 4,5-diazafluorene

KW - 4,5-diazafluorenone

KW - Diquats

KW - Nopinane

KW - Quats

UR - https://www.mendeley.com/catalogue/49eb7325-7af8-3917-ac5f-0057cef7944e/

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-105005841662&origin=inward&txGid=a71b56dcc51fcf82144f8826d3ea5680

U2 - 10.1016/j.molstruc.2025.142718

DO - 10.1016/j.molstruc.2025.142718

M3 - Article

VL - 1342

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

SN - 0022-2860

M1 - 142718

ER -

ID: 67127042