Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Cerium(III) Nitrate Derived CeO2 Support Stabilising PtOx Active Species for Room Temperature CO Oxidation. / Vasilchenko, Danila; Asanova, Tatyana; Kolesov, Boris и др.
в: ChemCatChem, Том 12, № 5, 06.03.2020, стр. 1413-1428.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Cerium(III) Nitrate Derived CeO2 Support Stabilising PtOx Active Species for Room Temperature CO Oxidation
AU - Vasilchenko, Danila
AU - Asanova, Tatyana
AU - Kolesov, Boris
AU - Tsygankova, Alphiya
AU - Stadnichenko, Andrey
AU - Slavinskaya, Elena
AU - Gerasimov, Evgeny
AU - Lomachenko, Kirill
AU - Boronin, Andrey
AU - Korenev, Sergey
N1 - Publisher Copyright: © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2020/3/6
Y1 - 2020/3/6
N2 - A new approach for preparing a PtOx/CeO2 catalyst for low-temperature CO oxidation has been developed. The approach includes; i) preparation of a CeO2 support through the controllable thermal decomposition of Ce(NO3)3 ⋅ 6H2O, and then ii) deposition of polynuclear platinum nitrato complexes ([H3O⊂18-crown-6]2[Pt2(μ2-OH)2(NO3)8][Pt4(μ3-OH)2(μ2-OH)4(NO3)10]) on the CeO2 support. The NO3 −-rich ceria support produced at the onset temperature of Ce(NO3)3 -> CeO2 transformation (220 °C) yields the “PtOx/CeO2-220” catalyst that shows intriguingly high activity in CO oxidation, at room temperature and below. To understand the nature of the low-temperature catalytic activity, prepared catalysts have been studied using X-ray photoelectron spectroscopy (XPS), Raman and operando X-ray absorption fine structure spectroscopy (XAFS) and transmission electron microscopy (TEM).
AB - A new approach for preparing a PtOx/CeO2 catalyst for low-temperature CO oxidation has been developed. The approach includes; i) preparation of a CeO2 support through the controllable thermal decomposition of Ce(NO3)3 ⋅ 6H2O, and then ii) deposition of polynuclear platinum nitrato complexes ([H3O⊂18-crown-6]2[Pt2(μ2-OH)2(NO3)8][Pt4(μ3-OH)2(μ2-OH)4(NO3)10]) on the CeO2 support. The NO3 −-rich ceria support produced at the onset temperature of Ce(NO3)3 -> CeO2 transformation (220 °C) yields the “PtOx/CeO2-220” catalyst that shows intriguingly high activity in CO oxidation, at room temperature and below. To understand the nature of the low-temperature catalytic activity, prepared catalysts have been studied using X-ray photoelectron spectroscopy (XPS), Raman and operando X-ray absorption fine structure spectroscopy (XAFS) and transmission electron microscopy (TEM).
KW - catalysis, ceria, low-temperature CO oxidation, operando XAS, platinum(IV) nitrato complexes
KW - operando XAS
KW - X-RAY-ABSORPTION
KW - catalysis
KW - STATE
KW - ceria
KW - platinum(IV) nitrato complexes
KW - PT/CEO2 CATALYSTS
KW - low-temperature CO oxidation
KW - CATALYTIC PERFORMANCE
KW - DISPERSED PT/CEO2
KW - PLATINUM NANOPARTICLES
KW - CERIA
KW - DEFECT SITES
KW - IN-SITU
KW - PHOTOELECTRON-SPECTROSCOPY
UR - http://www.scopus.com/inward/record.url?scp=85078768315&partnerID=8YFLogxK
U2 - 10.1002/cctc.201902146
DO - 10.1002/cctc.201902146
M3 - Article
AN - SCOPUS:85078768315
VL - 12
SP - 1413
EP - 1428
JO - ChemCatChem
JF - ChemCatChem
SN - 1867-3880
IS - 5
ER -
ID: 23328648