TY - JOUR

T1 - Catalytic Asymmetric Oxygenations with the Environmentally Benign Oxidants H2O2 and O2

AU - Bryliakov, Konstantin P.

N1 - Funding Information: This work was conducted within the framework of Budget Project 0303-2016-0005 for the Boreskov Institute of Catalysis. Financial support from the Russian Foundation for Basic Research (Project 16-29-10666) is gratefully acknowledged. Publisher Copyright: © 2017 American Chemical Society.

PY - 2017/9/13

Y1 - 2017/9/13

N2 - The discovery of simple and efficient catalyst systems for the asymmetric oxofunctionalization of hydrocarbons is a challenging task of catalytic chemistry. In this paper, we give an overview of catalyst systems capable of conducting asymmetric oxygenative transformations of organic molecules and, in line with the major trend to sustainability, relying on green oxidants H2O2 and O2 as the ultimate oxygen source. The full historical period of asymmetric oxidation catalysis (1970 to the present day) is covered; both transition-metal-based and organocatalytic systems are considered. The focus of this review is the catalytic properties of the existing catalyst systems, in particular stereoselectivity, activity, efficiency, and synthetic outlook. At the same time, mechanistic peculiarities of stereoselective oxygen transfer are given attention.

AB - The discovery of simple and efficient catalyst systems for the asymmetric oxofunctionalization of hydrocarbons is a challenging task of catalytic chemistry. In this paper, we give an overview of catalyst systems capable of conducting asymmetric oxygenative transformations of organic molecules and, in line with the major trend to sustainability, relying on green oxidants H2O2 and O2 as the ultimate oxygen source. The full historical period of asymmetric oxidation catalysis (1970 to the present day) is covered; both transition-metal-based and organocatalytic systems are considered. The focus of this review is the catalytic properties of the existing catalyst systems, in particular stereoselectivity, activity, efficiency, and synthetic outlook. At the same time, mechanistic peculiarities of stereoselective oxygen transfer are given attention.

UR - http://www.scopus.com/inward/record.url?scp=85029370341&partnerID=8YFLogxK

U2 - 10.1021/acs.chemrev.7b00167

DO - 10.1021/acs.chemrev.7b00167

M3 - Review article

C2 - 28816037

AN - SCOPUS:85029370341

VL - 117

SP - 11406

EP - 11459

JO - Chemical Reviews

JF - Chemical Reviews

SN - 0009-2665

IS - 17

ER -