Standard

Carbonylation of Perfluorinated Propenylbenzenes, Indenes, and 1-Alkylideneindans in Antimony Pentafluoride. / Zonov, Ya V.; Karpov, V. M.; Mezhenkova, T. V.

в: Russian Journal of Organic Chemistry, Том 61, № 7, 18.08.2025, стр. 1359-1368.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Zonov, YV, Karpov, VM & Mezhenkova, TV 2025, 'Carbonylation of Perfluorinated Propenylbenzenes, Indenes, and 1-Alkylideneindans in Antimony Pentafluoride', Russian Journal of Organic Chemistry, Том. 61, № 7, стр. 1359-1368. https://doi.org/10.1134/S1070428025603322

APA

Zonov, Y. V., Karpov, V. M., & Mezhenkova, T. V. (2025). Carbonylation of Perfluorinated Propenylbenzenes, Indenes, and 1-Alkylideneindans in Antimony Pentafluoride. Russian Journal of Organic Chemistry, 61(7), 1359-1368. https://doi.org/10.1134/S1070428025603322

Vancouver

Zonov YV, Karpov VM, Mezhenkova TV. Carbonylation of Perfluorinated Propenylbenzenes, Indenes, and 1-Alkylideneindans in Antimony Pentafluoride. Russian Journal of Organic Chemistry. 2025 авг. 18;61(7):1359-1368. doi: 10.1134/S1070428025603322

Author

Zonov, Ya V. ; Karpov, V. M. ; Mezhenkova, T. V. / Carbonylation of Perfluorinated Propenylbenzenes, Indenes, and 1-Alkylideneindans in Antimony Pentafluoride. в: Russian Journal of Organic Chemistry. 2025 ; Том 61, № 7. стр. 1359-1368.

BibTeX

@article{0dd849aa42854e589928e511bd11c9ac,
title = "Carbonylation of Perfluorinated Propenylbenzenes, Indenes, and 1-Alkylideneindans in Antimony Pentafluoride",
abstract = "Abstract: The carbonylation of perfluorinated 3-arylpropenes ArCF2CF=CF2 (Ar = C6F5, 3-CF3C6F4) in SbF5 under atmospheric CO pressure at room temperature, followed by treatment of the reaction mixture with water or methanol, afforded (Z)-perfluoro-2-arylbut-2-enoic acids or their methyl esters, respectively. In contrast, perfluoro-2-phenylpropene failed to undergo carbonylation under similar conditions. Perfluorinated 3-methyl-1H-indene and 1-methylidene- and 1-ethylideneindanes in antimony pentafluoride added two carbon monoxide molecules, and the subsequent treatment of the reaction mixture with methanol gave dimethyl perfluoro-1-alkyl-1H-indene-1,3-dicarboxylate as the major carbonylation product.",
keywords = "alkylideneindan, antimony pentafluoride, carbon monoxide, carbonylation, indene, polyfluorinated propenylbenzene",
author = "Zonov, {Ya V.} and Karpov, {V. M.} and Mezhenkova, {T. V.}",
year = "2025",
month = aug,
day = "18",
doi = "10.1134/S1070428025603322",
language = "English",
volume = "61",
pages = "1359--1368",
journal = "Russian Journal of Organic Chemistry",
issn = "1070-4280",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "7",

}

RIS

TY - JOUR

T1 - Carbonylation of Perfluorinated Propenylbenzenes, Indenes, and 1-Alkylideneindans in Antimony Pentafluoride

AU - Zonov, Ya V.

AU - Karpov, V. M.

AU - Mezhenkova, T. V.

PY - 2025/8/18

Y1 - 2025/8/18

N2 - Abstract: The carbonylation of perfluorinated 3-arylpropenes ArCF2CF=CF2 (Ar = C6F5, 3-CF3C6F4) in SbF5 under atmospheric CO pressure at room temperature, followed by treatment of the reaction mixture with water or methanol, afforded (Z)-perfluoro-2-arylbut-2-enoic acids or their methyl esters, respectively. In contrast, perfluoro-2-phenylpropene failed to undergo carbonylation under similar conditions. Perfluorinated 3-methyl-1H-indene and 1-methylidene- and 1-ethylideneindanes in antimony pentafluoride added two carbon monoxide molecules, and the subsequent treatment of the reaction mixture with methanol gave dimethyl perfluoro-1-alkyl-1H-indene-1,3-dicarboxylate as the major carbonylation product.

AB - Abstract: The carbonylation of perfluorinated 3-arylpropenes ArCF2CF=CF2 (Ar = C6F5, 3-CF3C6F4) in SbF5 under atmospheric CO pressure at room temperature, followed by treatment of the reaction mixture with water or methanol, afforded (Z)-perfluoro-2-arylbut-2-enoic acids or their methyl esters, respectively. In contrast, perfluoro-2-phenylpropene failed to undergo carbonylation under similar conditions. Perfluorinated 3-methyl-1H-indene and 1-methylidene- and 1-ethylideneindanes in antimony pentafluoride added two carbon monoxide molecules, and the subsequent treatment of the reaction mixture with methanol gave dimethyl perfluoro-1-alkyl-1H-indene-1,3-dicarboxylate as the major carbonylation product.

KW - alkylideneindan

KW - antimony pentafluoride

KW - carbon monoxide

KW - carbonylation

KW - indene

KW - polyfluorinated propenylbenzene

UR - https://www.mendeley.com/catalogue/bf1d0177-db66-386c-8c54-ed934a89f4e3/

UR - https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=105013506841&origin=inward

U2 - 10.1134/S1070428025603322

DO - 10.1134/S1070428025603322

M3 - Article

VL - 61

SP - 1359

EP - 1368

JO - Russian Journal of Organic Chemistry

JF - Russian Journal of Organic Chemistry

SN - 1070-4280

IS - 7

ER -

ID: 68829091