Cadmium(ii) terephthalates based on trinuclear units {Cd3(bdc)3}

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Cadmium(ii) terephthalates based on trinuclear units {Cd₃(bdc)₃} : control of coordination structure dimensionality and luminescence properties. / Lysova, A. A.; Samsonenko, D. G.; Dybtsev, D. N. и др.

в: Russian Chemical Bulletin, Том 66, № 9, 01.09.2017, стр. 1580-1588.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{260eee58697347498c6406fd5c678d01,

title = "Cadmium(ii) terephthalates based on trinuclear units {Cd3(bdc)3}: control of coordination structure dimensionality and luminescence properties",

abstract = "Two metal-organic coordination polymers based on cadmium(ii) ions and terephthalic (1,4-benzenedicarboxylic) acid were synthesized in dimethylformamide or a mixture of dimethylformamide and methanol: [Cd3(bdc)3(dmf)4] (1, bdc is 1,4-benzenedicarboxylate, dmf is N,N´-dimethylformamide) and [Cd3(bdc)3(dmf)2] (2), respectively. According to the single-crystal X-ray diffraction data, both compounds are built up by the trinuclear carboxylate units {Cd3(O2CR)6}. Compound 1 has a layered structure, whereas compound 2 has a three-dimensional structure due to the presence of additional coordination interactions between adjacent trinuclear units and the formation of polymer chains {Cd3(dmf)2(μ2-O2CR-κ1,κ1)2(μ2-O2CR-κ2,κ1)4(O2CR-κ1)2}. The synthesized compounds were characterized by IR spectroscopy, thermogravimetric analysis, elemental analysis, and powder X-ray diffrac- tion. The luminescence properties of these compounds provide evidence for the existence of both intraligand and charge-transfer transitions. The luminescence quantum yields for both compounds are 10%.",

keywords = "cadmium, luminescence, metal-organic frameworks, terephthalate, X-ray diffraction, CARBOXYLATE FRAMEWORKS, POLYMERS, METAL-ORGANIC FRAMEWORKS, ADSORPTION, MOF-5",

author = "Lysova, {A. A.} and Samsonenko, {D. G.} and Dybtsev, {D. N.} and Fedin, {V. P.}",

note = "Publisher Copyright: {\textcopyright} 2017, Springer Science+Business Media, LLC, part of Springer Nature.",

year = "2017",

month = sep,

day = "1",

doi = "10.1007/s11172-017-1927-0",

language = "English",

volume = "66",

pages = "1580--1588",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer Nature",

number = "9",

}

RIS

TY - JOUR

T1 - Cadmium(ii) terephthalates based on trinuclear units {Cd3(bdc)3}

T2 - control of coordination structure dimensionality and luminescence properties

AU - Lysova, A. A.

AU - Samsonenko, D. G.

AU - Dybtsev, D. N.

AU - Fedin, V. P.

PY - 2017/9/1

Y1 - 2017/9/1

N2 - Two metal-organic coordination polymers based on cadmium(ii) ions and terephthalic (1,4-benzenedicarboxylic) acid were synthesized in dimethylformamide or a mixture of dimethylformamide and methanol: [Cd3(bdc)3(dmf)4] (1, bdc is 1,4-benzenedicarboxylate, dmf is N,N´-dimethylformamide) and [Cd3(bdc)3(dmf)2] (2), respectively. According to the single-crystal X-ray diffraction data, both compounds are built up by the trinuclear carboxylate units {Cd3(O2CR)6}. Compound 1 has a layered structure, whereas compound 2 has a three-dimensional structure due to the presence of additional coordination interactions between adjacent trinuclear units and the formation of polymer chains {Cd3(dmf)2(μ2-O2CR-κ1,κ1)2(μ2-O2CR-κ2,κ1)4(O2CR-κ1)2}. The synthesized compounds were characterized by IR spectroscopy, thermogravimetric analysis, elemental analysis, and powder X-ray diffrac- tion. The luminescence properties of these compounds provide evidence for the existence of both intraligand and charge-transfer transitions. The luminescence quantum yields for both compounds are 10%.

AB - Two metal-organic coordination polymers based on cadmium(ii) ions and terephthalic (1,4-benzenedicarboxylic) acid were synthesized in dimethylformamide or a mixture of dimethylformamide and methanol: [Cd3(bdc)3(dmf)4] (1, bdc is 1,4-benzenedicarboxylate, dmf is N,N´-dimethylformamide) and [Cd3(bdc)3(dmf)2] (2), respectively. According to the single-crystal X-ray diffraction data, both compounds are built up by the trinuclear carboxylate units {Cd3(O2CR)6}. Compound 1 has a layered structure, whereas compound 2 has a three-dimensional structure due to the presence of additional coordination interactions between adjacent trinuclear units and the formation of polymer chains {Cd3(dmf)2(μ2-O2CR-κ1,κ1)2(μ2-O2CR-κ2,κ1)4(O2CR-κ1)2}. The synthesized compounds were characterized by IR spectroscopy, thermogravimetric analysis, elemental analysis, and powder X-ray diffrac- tion. The luminescence properties of these compounds provide evidence for the existence of both intraligand and charge-transfer transitions. The luminescence quantum yields for both compounds are 10%.

KW - cadmium

KW - luminescence

KW - metal-organic frameworks

KW - terephthalate

KW - X-ray diffraction

KW - CARBOXYLATE FRAMEWORKS

KW - POLYMERS

KW - METAL-ORGANIC FRAMEWORKS

KW - ADSORPTION

KW - MOF-5

UR - http://www.scopus.com/inward/record.url?scp=85039420160&partnerID=8YFLogxK

U2 - 10.1007/s11172-017-1927-0

DO - 10.1007/s11172-017-1927-0

M3 - Article

AN - SCOPUS:85039420160

VL - 66

SP - 1580

EP - 1588

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 9

ER -

ID: 9643273

Cadmium(ii) terephthalates based on trinuclear units {Cd3(bdc)3}: control of coordination structure dimensionality and luminescence properties

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Cadmium(ii) terephthalates based on trinuclear units {Cd₃(bdc)₃}: control of coordination structure dimensionality and luminescence properties