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Breaking structure sensitivity in CO2 hydrogenation by tuning metal–oxide interfaces in supported cobalt nanoparticles. / Parastaev, Alexander; Muravev, Valery; Osta, Elisabet Huertas и др.

в: Nature Catalysis, Том 5, № 11, 11.2022, стр. 1051–1060.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Parastaev, A, Muravev, V, Osta, EH, Kimpel, TF, Simons, JFM, van Hoof, AJF, Uslamin, E, Zhang, L, Struijs, JJC, Burueva, DB, Pokochueva, EV, Kovtunov, KV, Koptyug, IV, Villar-Garcia, IJ, Escudero, C, Altantzis, T, Liu, P, Béché, A, Bals, S, Kosinov, N & Hensen, EJM 2022, 'Breaking structure sensitivity in CO2 hydrogenation by tuning metal–oxide interfaces in supported cobalt nanoparticles', Nature Catalysis, Том. 5, № 11, стр. 1051–1060. https://doi.org/10.1038/s41929-022-00874-4

APA

Parastaev, A., Muravev, V., Osta, E. H., Kimpel, T. F., Simons, J. F. M., van Hoof, A. J. F., Uslamin, E., Zhang, L., Struijs, J. J. C., Burueva, D. B., Pokochueva, E. V., Kovtunov, K. V., Koptyug, I. V., Villar-Garcia, I. J., Escudero, C., Altantzis, T., Liu, P., Béché, A., Bals, S., ... Hensen, E. J. M. (2022). Breaking structure sensitivity in CO2 hydrogenation by tuning metal–oxide interfaces in supported cobalt nanoparticles. Nature Catalysis, 5(11), 1051–1060. https://doi.org/10.1038/s41929-022-00874-4

Vancouver

Parastaev A, Muravev V, Osta EH, Kimpel TF, Simons JFM, van Hoof AJF и др. Breaking structure sensitivity in CO2 hydrogenation by tuning metal–oxide interfaces in supported cobalt nanoparticles. Nature Catalysis. 2022 нояб.;5(11):1051–1060. doi: 10.1038/s41929-022-00874-4

Author

Parastaev, Alexander ; Muravev, Valery ; Osta, Elisabet Huertas и др. / Breaking structure sensitivity in CO2 hydrogenation by tuning metal–oxide interfaces in supported cobalt nanoparticles. в: Nature Catalysis. 2022 ; Том 5, № 11. стр. 1051–1060.

BibTeX

@article{99e891f54df0421db9d99d795295deeb,
title = "Breaking structure sensitivity in CO2 hydrogenation by tuning metal–oxide interfaces in supported cobalt nanoparticles",
abstract = "A high dispersion of the active metal phase of transition metals on oxide supports is important when designing efficient heterogeneous catalysts. Besides nanoparticles, clusters and even single metal atoms can be attractive for a wide range of reactions. However, many industrially relevant catalytic transformations suffer from structure sensitivity, where reducing the size of the metal particles below a certain size substantially lowers catalytic performance. A case in point is the low activity of small cobalt nanoparticles in the hydrogenation of CO and CO2. Here we show how engineering of catalytic sites at the metal–oxide interface in cerium oxide–zirconium dioxide (ceria–zirconia)-supported cobalt can overcome this structure sensitivity. Few-atom cobalt clusters dispersed on 3 nm cobalt(II)-oxide particles stabilized by ceria–zirconia yielded a highly active CO2 methanation catalyst with a specific activity higher than that of larger particles under the same conditions.",
author = "Alexander Parastaev and Valery Muravev and Osta, {Elisabet Huertas} and Kimpel, {Tobias F.} and Simons, {J{\'e}r{\^o}me F.M.} and {van Hoof}, {Arno J.F.} and Evgeny Uslamin and Long Zhang and Struijs, {Job J.C.} and Burueva, {Dudari B.} and Pokochueva, {Ekaterina V.} and Kovtunov, {Kirill V.} and Koptyug, {Igor V.} and Villar-Garcia, {Ignacio J.} and Carlos Escudero and Thomas Altantzis and Pei Liu and Armand B{\'e}ch{\'e} and Sara Bals and Nikolay Kosinov and Hensen, {Emiel J.M.}",
note = "Funding Information: This research was supported by the Applied and Engineering Sciences division of the Netherlands Organization for Scientific Research through the Alliander (now Qirion) Perspective programme on Plasma Conversion of CO. We acknowledge Diamond Light Source for time on beamline B18 under proposal no. SP20715-1. This project has received funding from the European Union{\textquoteright}s Horizon 2020 research and innovation programme under grant agreement no. 823717 – ESTEEM3. S.B. acknowledges support from the European Research Council (ERC Consolidator Grant no. 815128 REALNANO) and T.A. acknowledges funding from the University of Antwerp Research fund (BOF). A.B. received funding from the European Union under grant agreement no. 823717 – ESTEEM3. The authors acknowledge funding through the Hercules grant (FWO, University of Antwerp) no. I003218N, {\textquoteleft}Infrastructure for imaging nanoscale processes in gas/vapour or liquid environments{\textquoteright}. I.V.K., D.B.B. and E.V.P. acknowledge the Russian Ministry of Science and Higher Education (contract no. 075-15-2021-580) for financial support with parahydrogen-based studies. Experiments using synchrotron radiation XPS were performed at the CIRCE beamline at ALBA Synchrotron with the collaboration of ALBA staff. F. Oropeza Palacio and R. C. J. van de Poll are acknowledged for help with RPES measurements. 2 Publisher Copyright: {\textcopyright} 2022, The Author(s), under exclusive licence to Springer Nature Limited.",
year = "2022",
month = nov,
doi = "10.1038/s41929-022-00874-4",
language = "English",
volume = "5",
pages = "1051–1060",
journal = "Nature Catalysis",
issn = "2520-1158",
publisher = "Nature Publishing Group",
number = "11",

}

RIS

TY - JOUR

T1 - Breaking structure sensitivity in CO2 hydrogenation by tuning metal–oxide interfaces in supported cobalt nanoparticles

AU - Parastaev, Alexander

AU - Muravev, Valery

AU - Osta, Elisabet Huertas

AU - Kimpel, Tobias F.

AU - Simons, Jérôme F.M.

AU - van Hoof, Arno J.F.

AU - Uslamin, Evgeny

AU - Zhang, Long

AU - Struijs, Job J.C.

AU - Burueva, Dudari B.

AU - Pokochueva, Ekaterina V.

AU - Kovtunov, Kirill V.

AU - Koptyug, Igor V.

AU - Villar-Garcia, Ignacio J.

AU - Escudero, Carlos

AU - Altantzis, Thomas

AU - Liu, Pei

AU - Béché, Armand

AU - Bals, Sara

AU - Kosinov, Nikolay

AU - Hensen, Emiel J.M.

N1 - Funding Information: This research was supported by the Applied and Engineering Sciences division of the Netherlands Organization for Scientific Research through the Alliander (now Qirion) Perspective programme on Plasma Conversion of CO. We acknowledge Diamond Light Source for time on beamline B18 under proposal no. SP20715-1. This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement no. 823717 – ESTEEM3. S.B. acknowledges support from the European Research Council (ERC Consolidator Grant no. 815128 REALNANO) and T.A. acknowledges funding from the University of Antwerp Research fund (BOF). A.B. received funding from the European Union under grant agreement no. 823717 – ESTEEM3. The authors acknowledge funding through the Hercules grant (FWO, University of Antwerp) no. I003218N, ‘Infrastructure for imaging nanoscale processes in gas/vapour or liquid environments’. I.V.K., D.B.B. and E.V.P. acknowledge the Russian Ministry of Science and Higher Education (contract no. 075-15-2021-580) for financial support with parahydrogen-based studies. Experiments using synchrotron radiation XPS were performed at the CIRCE beamline at ALBA Synchrotron with the collaboration of ALBA staff. F. Oropeza Palacio and R. C. J. van de Poll are acknowledged for help with RPES measurements. 2 Publisher Copyright: © 2022, The Author(s), under exclusive licence to Springer Nature Limited.

PY - 2022/11

Y1 - 2022/11

N2 - A high dispersion of the active metal phase of transition metals on oxide supports is important when designing efficient heterogeneous catalysts. Besides nanoparticles, clusters and even single metal atoms can be attractive for a wide range of reactions. However, many industrially relevant catalytic transformations suffer from structure sensitivity, where reducing the size of the metal particles below a certain size substantially lowers catalytic performance. A case in point is the low activity of small cobalt nanoparticles in the hydrogenation of CO and CO2. Here we show how engineering of catalytic sites at the metal–oxide interface in cerium oxide–zirconium dioxide (ceria–zirconia)-supported cobalt can overcome this structure sensitivity. Few-atom cobalt clusters dispersed on 3 nm cobalt(II)-oxide particles stabilized by ceria–zirconia yielded a highly active CO2 methanation catalyst with a specific activity higher than that of larger particles under the same conditions.

AB - A high dispersion of the active metal phase of transition metals on oxide supports is important when designing efficient heterogeneous catalysts. Besides nanoparticles, clusters and even single metal atoms can be attractive for a wide range of reactions. However, many industrially relevant catalytic transformations suffer from structure sensitivity, where reducing the size of the metal particles below a certain size substantially lowers catalytic performance. A case in point is the low activity of small cobalt nanoparticles in the hydrogenation of CO and CO2. Here we show how engineering of catalytic sites at the metal–oxide interface in cerium oxide–zirconium dioxide (ceria–zirconia)-supported cobalt can overcome this structure sensitivity. Few-atom cobalt clusters dispersed on 3 nm cobalt(II)-oxide particles stabilized by ceria–zirconia yielded a highly active CO2 methanation catalyst with a specific activity higher than that of larger particles under the same conditions.

UR - http://www.scopus.com/inward/record.url?scp=85142152521&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/2aa52d20-947b-33f9-ba96-84a4e37903ee/

U2 - 10.1038/s41929-022-00874-4

DO - 10.1038/s41929-022-00874-4

M3 - Article

AN - SCOPUS:85142152521

VL - 5

SP - 1051

EP - 1060

JO - Nature Catalysis

JF - Nature Catalysis

SN - 2520-1158

IS - 11

ER -

ID: 39709714