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Binuclear Niobium Complex with Coordinated N-Heterocyclic Carbene. / Petrov, P. A.; Golubitskaya, E. A.; Kompankov, N. B. и др.
в: Journal of Structural Chemistry, Том 60, № 12, 01.12.2019, стр. 1989-1994.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Binuclear Niobium Complex with Coordinated N-Heterocyclic Carbene
AU - Petrov, P. A.
AU - Golubitskaya, E. A.
AU - Kompankov, N. B.
AU - Eltsov, I. V.
AU - Sukhikh, T. S.
AU - Sokolov, M. N.
N1 - Publisher Copyright: © 2019, Pleiades Publishing, Ltd.
PY - 2019/12/1
Y1 - 2019/12/1
N2 - By the interaction of Nb(NMe2)5 and 1,3-(2,6-diisopropylphenyl)imidazolium (IPr·HBF4) tetrafluoroborate a binuclear complex with coordinated N-heterocyclic carbene [(IPr)Nb(=NMe)(NMe2)(μ-F)2(μ-NMe2) NbF2(NMe2)] (1) is obtained. The reaction of Nb(NMe2)5 and 1,3-(2,4,6-trimethylphenyl)imidazolium (IMes·HBF4) tetrafluoroborate yields [(IMes)2H][NbF6] salt (2). The structure of the complexes is determined by single crystal X-ray diffraction.
AB - By the interaction of Nb(NMe2)5 and 1,3-(2,6-diisopropylphenyl)imidazolium (IPr·HBF4) tetrafluoroborate a binuclear complex with coordinated N-heterocyclic carbene [(IPr)Nb(=NMe)(NMe2)(μ-F)2(μ-NMe2) NbF2(NMe2)] (1) is obtained. The reaction of Nb(NMe2)5 and 1,3-(2,4,6-trimethylphenyl)imidazolium (IMes·HBF4) tetrafluoroborate yields [(IMes)2H][NbF6] salt (2). The structure of the complexes is determined by single crystal X-ray diffraction.
KW - amides
KW - N-heterocyclic carbenes
KW - niobium
KW - single crystal XRD
KW - TANTALUM
KW - CHLORIDE
UR - http://www.scopus.com/inward/record.url?scp=85077602792&partnerID=8YFLogxK
U2 - 10.1134/S0022476619120151
DO - 10.1134/S0022476619120151
M3 - Article
AN - SCOPUS:85077602792
VL - 60
SP - 1989
EP - 1994
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 12
ER -
ID: 23123276