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Apical Cyanide Ligand Substitution in Heterometallic Clusters [Re3Mo3Q8(CN)6]n– (Q = S, Se). / Muravieva, Viktoria K.; Gayfulin, Yakov M.; Lappi, Tatiana I. и др.

в: European Journal of Inorganic Chemistry, Том 2019, № 22, 16.06.2019, стр. 2685-2690.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Muravieva, VK, Gayfulin, YM, Lappi, TI, Dorcet, V, Sukhikh, TS, Lemoine, P, Ryzhikov, MR, Mironov, YV, Cordier, S & Naumov, NG 2019, 'Apical Cyanide Ligand Substitution in Heterometallic Clusters [Re3Mo3Q8(CN)6]n– (Q = S, Se)', European Journal of Inorganic Chemistry, Том. 2019, № 22, стр. 2685-2690. https://doi.org/10.1002/ejic.201900198

APA

Muravieva, V. K., Gayfulin, Y. M., Lappi, T. I., Dorcet, V., Sukhikh, T. S., Lemoine, P., Ryzhikov, M. R., Mironov, Y. V., Cordier, S., & Naumov, N. G. (2019). Apical Cyanide Ligand Substitution in Heterometallic Clusters [Re3Mo3Q8(CN)6]n– (Q = S, Se). European Journal of Inorganic Chemistry, 2019(22), 2685-2690. https://doi.org/10.1002/ejic.201900198

Vancouver

Muravieva VK, Gayfulin YM, Lappi TI, Dorcet V, Sukhikh TS, Lemoine P и др. Apical Cyanide Ligand Substitution in Heterometallic Clusters [Re3Mo3Q8(CN)6]n– (Q = S, Se). European Journal of Inorganic Chemistry. 2019 июнь 16;2019(22):2685-2690. doi: 10.1002/ejic.201900198

Author

Muravieva, Viktoria K. ; Gayfulin, Yakov M. ; Lappi, Tatiana I. и др. / Apical Cyanide Ligand Substitution in Heterometallic Clusters [Re3Mo3Q8(CN)6]n– (Q = S, Se). в: European Journal of Inorganic Chemistry. 2019 ; Том 2019, № 22. стр. 2685-2690.

BibTeX

@article{65d7437d1e8e4f969bcaaa8adda53304,
title = "Apical Cyanide Ligand Substitution in Heterometallic Clusters [Re3Mo3Q8(CN)6]n– (Q = S, Se)",
abstract = "A number of transition metal cluster compounds can be obtained only in the melt of inorganic cyanides and, therefore, contain terminal cyanide ligands. Substitution of these ligands, which is often necessary to change the physicochemical properties of the clusters, is an urgent problem because of their low reactivity in substitution reactions. In this work, a synthetic approach has been developed for the substitution of CN-ligands in the heterometallic cluster anions [Re3Mo3Q8(CN)6]n– (Q = S, n = 6; Q = Se, n = 5) by the 4-tert-butylpyridine (TBP) molecules. Two new compounds, namely [Re3Mo3S8(TBP)6] (1) and [Re3Mo3Se8(TBP)6] (2), were obtained with high yields and crystallized under solvothermal conditions. It has been shown that compounds 1 and 2 are based on the paramagnetic cluster cores {Re3Mo3Q8}0 containing 23 cluster valence electrons (CVE). The geometry of the new compounds has been investigated using X-ray structural analysis. The electronic structure has been analyzed using the DFT calculations showing large distortion of M6 cluster core.",
keywords = "Cluster compounds, Electronic structure, Ligand exchange, Molybdenum, Rhenium",
author = "Muravieva, {Viktoria K.} and Gayfulin, {Yakov M.} and Lappi, {Tatiana I.} and Vincent Dorcet and Sukhikh, {Taisiya S.} and Pierric Lemoine and Ryzhikov, {Maxim R.} and Mironov, {Yuri V.} and St{\'e}phane Cordier and Naumov, {Nikolay G.}",
note = "Publisher Copyright: {\textcopyright} 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",
year = "2019",
month = jun,
day = "16",
doi = "10.1002/ejic.201900198",
language = "English",
volume = "2019",
pages = "2685--2690",
journal = "European Journal of Inorganic Chemistry",
issn = "1434-1948",
publisher = "Wiley-VCH Verlag",
number = "22",

}

RIS

TY - JOUR

T1 - Apical Cyanide Ligand Substitution in Heterometallic Clusters [Re3Mo3Q8(CN)6]n– (Q = S, Se)

AU - Muravieva, Viktoria K.

AU - Gayfulin, Yakov M.

AU - Lappi, Tatiana I.

AU - Dorcet, Vincent

AU - Sukhikh, Taisiya S.

AU - Lemoine, Pierric

AU - Ryzhikov, Maxim R.

AU - Mironov, Yuri V.

AU - Cordier, Stéphane

AU - Naumov, Nikolay G.

N1 - Publisher Copyright: © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

PY - 2019/6/16

Y1 - 2019/6/16

N2 - A number of transition metal cluster compounds can be obtained only in the melt of inorganic cyanides and, therefore, contain terminal cyanide ligands. Substitution of these ligands, which is often necessary to change the physicochemical properties of the clusters, is an urgent problem because of their low reactivity in substitution reactions. In this work, a synthetic approach has been developed for the substitution of CN-ligands in the heterometallic cluster anions [Re3Mo3Q8(CN)6]n– (Q = S, n = 6; Q = Se, n = 5) by the 4-tert-butylpyridine (TBP) molecules. Two new compounds, namely [Re3Mo3S8(TBP)6] (1) and [Re3Mo3Se8(TBP)6] (2), were obtained with high yields and crystallized under solvothermal conditions. It has been shown that compounds 1 and 2 are based on the paramagnetic cluster cores {Re3Mo3Q8}0 containing 23 cluster valence electrons (CVE). The geometry of the new compounds has been investigated using X-ray structural analysis. The electronic structure has been analyzed using the DFT calculations showing large distortion of M6 cluster core.

AB - A number of transition metal cluster compounds can be obtained only in the melt of inorganic cyanides and, therefore, contain terminal cyanide ligands. Substitution of these ligands, which is often necessary to change the physicochemical properties of the clusters, is an urgent problem because of their low reactivity in substitution reactions. In this work, a synthetic approach has been developed for the substitution of CN-ligands in the heterometallic cluster anions [Re3Mo3Q8(CN)6]n– (Q = S, n = 6; Q = Se, n = 5) by the 4-tert-butylpyridine (TBP) molecules. Two new compounds, namely [Re3Mo3S8(TBP)6] (1) and [Re3Mo3Se8(TBP)6] (2), were obtained with high yields and crystallized under solvothermal conditions. It has been shown that compounds 1 and 2 are based on the paramagnetic cluster cores {Re3Mo3Q8}0 containing 23 cluster valence electrons (CVE). The geometry of the new compounds has been investigated using X-ray structural analysis. The electronic structure has been analyzed using the DFT calculations showing large distortion of M6 cluster core.

KW - Cluster compounds

KW - Electronic structure

KW - Ligand exchange

KW - Molybdenum

KW - Rhenium

UR - http://www.scopus.com/inward/record.url?scp=85067311878&partnerID=8YFLogxK

U2 - 10.1002/ejic.201900198

DO - 10.1002/ejic.201900198

M3 - Article

AN - SCOPUS:85067311878

VL - 2019

SP - 2685

EP - 2690

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

SN - 1434-1948

IS - 22

ER -

ID: 20582191