TY - JOUR

T1 - An XPS and TPD study of gold oxide films obtained by exposure to RF-activated oxygen

AU - Stadnichenko, A. I.

AU - Koshcheev, S. V.

AU - Boronin, A. I.

PY - 2015/6/29

Y1 - 2015/6/29

N2 - Low-temperature oxidation of the polycrystalline surface of bulk metallic gold with radio-frequency activated oxygen is used to obtain oxide films, which are investigated by a combination of X-ray photoelectron spectroscopy (XPS) and temperature programmed desorption (TPD). The XPS estimate for the composition and thickness of the oxide films is close to Au2O3 and is 6-10 nm. The analysis of the Au4f and O1s lines reveals only one state of the oxidized gold, which is described by Eb(Au4f) = 85.5 eV, and two nonequivalent states of oxygen with Eb(O1s) = 529.3 eV and 530.3 eV, which are uniformly distributed over the oxide film and may be attributed to nonequivalent oxygen states in the gold oxide structure. The thermal stability study shows that the gold oxide decomposes in one stage into metal at a temperature of Tdes = 530 K. According to the TPD data, the desorption activation energy is Edes = 140 kJ/mol. The high-temperature oxidation of the gold surface reveals the formation of dissolved oxygen in bulk gold. This oxygen is characterized by a broad TPD peak with a maximum at Tdes = 800 K. This oxygen state is not detected by XPS. The concentration of dissolved oxygen is supposed to be below the XPS sensitivity threshold and is estimated at about 1% or less.

AB - Low-temperature oxidation of the polycrystalline surface of bulk metallic gold with radio-frequency activated oxygen is used to obtain oxide films, which are investigated by a combination of X-ray photoelectron spectroscopy (XPS) and temperature programmed desorption (TPD). The XPS estimate for the composition and thickness of the oxide films is close to Au2O3 and is 6-10 nm. The analysis of the Au4f and O1s lines reveals only one state of the oxidized gold, which is described by Eb(Au4f) = 85.5 eV, and two nonequivalent states of oxygen with Eb(O1s) = 529.3 eV and 530.3 eV, which are uniformly distributed over the oxide film and may be attributed to nonequivalent oxygen states in the gold oxide structure. The thermal stability study shows that the gold oxide decomposes in one stage into metal at a temperature of Tdes = 530 K. According to the TPD data, the desorption activation energy is Edes = 140 kJ/mol. The high-temperature oxidation of the gold surface reveals the formation of dissolved oxygen in bulk gold. This oxygen is characterized by a broad TPD peak with a maximum at Tdes = 800 K. This oxygen state is not detected by XPS. The concentration of dissolved oxygen is supposed to be below the XPS sensitivity threshold and is estimated at about 1% or less.

KW - adsorbed oxygen

KW - gold

KW - gold oxide

KW - oxide film

KW - plasma

KW - surface

KW - TPD

KW - XPS

UR - http://www.scopus.com/inward/record.url?scp=84938405850&partnerID=8YFLogxK

U2 - 10.1134/S0022476615030245

DO - 10.1134/S0022476615030245

M3 - Article

AN - SCOPUS:84938405850

VL - 56

SP - 557

EP - 565

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 3

ER -