TY - JOUR

T1 - An Xps and Low-Temperature Nitrogen Adsorption Study of the Structure of Carbon-Fluorocarbon Nanocomposites

AU - Mitkin, V. N.

AU - Asanov, I. P.

AU - Sagidullin, A. K.

N1 - Publisher Copyright: © 2018, Pleiades Publishing, Ltd.

PY - 2018/12/1

Y1 - 2018/12/1

N2 - The products of mechanosynthesis in the systems “superstoichiometric fluorocarbon nanomaterial CF1.2–thermally expanded graphite” are studied using X-ray photoelectron spectroscopy and low-temperature nitrogen adsorption to identify texture characteristics. A correlation is revealed between the conductivity of the composites and functional composition of their surface layers. The obtained results are explained by the fact that mechanosynthesis products contain mesoporous carbon-fluorocarbon nanocomposites consisting of micro- and nanoparticles CF1+x coated by an outer nanolayer sp2-C–sp3-C–F.

AB - The products of mechanosynthesis in the systems “superstoichiometric fluorocarbon nanomaterial CF1.2–thermally expanded graphite” are studied using X-ray photoelectron spectroscopy and low-temperature nitrogen adsorption to identify texture characteristics. A correlation is revealed between the conductivity of the composites and functional composition of their surface layers. The obtained results are explained by the fact that mechanosynthesis products contain mesoporous carbon-fluorocarbon nanocomposites consisting of micro- and nanoparticles CF1+x coated by an outer nanolayer sp2-C–sp3-C–F.

KW - mesopores

KW - nanocomposites

KW - superstoichiometric fluorocarbon material

KW - texture

KW - thermally expanded graphite

KW - X-ray photoelectron spectroscopy

UR - http://www.scopus.com/inward/record.url?scp=85059780048&partnerID=8YFLogxK

U2 - 10.1134/S0022476618080127

DO - 10.1134/S0022476618080127

M3 - Article

AN - SCOPUS:85059780048

VL - 59

SP - 1841

EP - 1848

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 8

ER -