Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
An Acid-Catalyzed Cascade Synthesis of Oxaazatetracyclo [5.5.0.03,11.05,9]dodecane Derivatives. / Paromov, Artyom E.; Sysolyatin, Sergey V.; Gatilov, Yuri V.
в: Journal of Energetic Materials, Том 35, № 3, 03.07.2017, стр. 363-373.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - An Acid-Catalyzed Cascade Synthesis of Oxaazatetracyclo [5.5.0.03,11.05,9]dodecane Derivatives
AU - Paromov, Artyom E.
AU - Sysolyatin, Sergey V.
AU - Gatilov, Yuri V.
PY - 2017/7/3
Y1 - 2017/7/3
N2 - A condensation between mesylamide and glyoxal under highly acidic conditions was studied. A series of new compounds whose structures contain a moiety of oxaazatetracyclo[5.5.0.03,11.05,9]dodecane were synthesized. The synthesis processes were optimized and main factors affecting the assembling of cage products were revealed. Assumptions are made regarding the formation mechanism of these chemical entities. For the first time, compounds have been obtained that include moieties of 2,6,8-trioxa-4,10,12-triazatetracyclo[5.5.0.03,11.05,9]dodecane and 2,4,6-trioxa-8,10,12-triazatetracyclo[5.5.0.03,11.05,9]dodecane. An X-ray diffraction analysis of the new compounds was performed.
AB - A condensation between mesylamide and glyoxal under highly acidic conditions was studied. A series of new compounds whose structures contain a moiety of oxaazatetracyclo[5.5.0.03,11.05,9]dodecane were synthesized. The synthesis processes were optimized and main factors affecting the assembling of cage products were revealed. Assumptions are made regarding the formation mechanism of these chemical entities. For the first time, compounds have been obtained that include moieties of 2,6,8-trioxa-4,10,12-triazatetracyclo[5.5.0.03,11.05,9]dodecane and 2,4,6-trioxa-8,10,12-triazatetracyclo[5.5.0.03,11.05,9]dodecane. An X-ray diffraction analysis of the new compounds was performed.
KW - Cage compounds
KW - cyclization
KW - domino reactions
KW - nitrogen heterocycles
KW - oxygen heterocycles
UR - http://www.scopus.com/inward/record.url?scp=84975298251&partnerID=8YFLogxK
U2 - 10.1080/07370652.2016.1194499
DO - 10.1080/07370652.2016.1194499
M3 - Article
AN - SCOPUS:84975298251
VL - 35
SP - 363
EP - 373
JO - Journal of Energetic Materials
JF - Journal of Energetic Materials
SN - 0737-0652
IS - 3
ER -
ID: 9976975