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Alkane/alkene mixture diffusion in silicalite-1 studied by MAS PFG NMR. / Dvoyashkina, Nina; Freude, Dieter; Stepanov, Alexander G. и др.

в: Microporous and Mesoporous Materials, Том 257, 01.02.2018, стр. 128-134.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Dvoyashkina, N, Freude, D, Stepanov, AG, Böhlmann, W, Krishna, R, Kärger, J & Haase, J 2018, 'Alkane/alkene mixture diffusion in silicalite-1 studied by MAS PFG NMR', Microporous and Mesoporous Materials, Том. 257, стр. 128-134. https://doi.org/10.1016/j.micromeso.2017.08.015

APA

Dvoyashkina, N., Freude, D., Stepanov, A. G., Böhlmann, W., Krishna, R., Kärger, J., & Haase, J. (2018). Alkane/alkene mixture diffusion in silicalite-1 studied by MAS PFG NMR. Microporous and Mesoporous Materials, 257, 128-134. https://doi.org/10.1016/j.micromeso.2017.08.015

Vancouver

Dvoyashkina N, Freude D, Stepanov AG, Böhlmann W, Krishna R, Kärger J и др. Alkane/alkene mixture diffusion in silicalite-1 studied by MAS PFG NMR. Microporous and Mesoporous Materials. 2018 февр. 1;257:128-134. doi: 10.1016/j.micromeso.2017.08.015

Author

Dvoyashkina, Nina ; Freude, Dieter ; Stepanov, Alexander G. и др. / Alkane/alkene mixture diffusion in silicalite-1 studied by MAS PFG NMR. в: Microporous and Mesoporous Materials. 2018 ; Том 257. стр. 128-134.

BibTeX

@article{78105c8698864e01bb11f208f9153cb1,
title = "Alkane/alkene mixture diffusion in silicalite-1 studied by MAS PFG NMR",
abstract = "The diffusivity of n-alkanes and n-alkenes (C2 to C6) and their mixtures in silicalite-1 was studied by magic-angle spinning pulsed field-gradient nuclear magnetic resonance (MAS PFG NMR) at the temperatures of 273 K, 313 K and 373 K. It could be proved that there is no significant difference between the diffusivities of alkanes, alkenes and their mixtures for equal carbon numbers and equal total loading. The diffusivities of the alkanes, alkenes and their mixtures are found to monotonically decrease with increasing carbon number, in agreement with the results obtained in MD simulations with n-alkanes in silicalite-1.",
keywords = "MFI-TYPE ZEOLITES, ELASTIC NEUTRON-SCATTERING, SELF-DIFFUSION, N-ALKANES, CRYSTALLINE MATERIALS, LOADING DEPENDENCE, DIFFUSIVITIES, SIMULATIONS, DYNAMICS, TRANSPORT",
author = "Nina Dvoyashkina and Dieter Freude and Stepanov, {Alexander G.} and Winfried B{\"o}hlmann and Rajamani Krishna and J{\"o}rg K{\"a}rger and J{\"u}rgen Haase",
year = "2018",
month = feb,
day = "1",
doi = "10.1016/j.micromeso.2017.08.015",
language = "English",
volume = "257",
pages = "128--134",
journal = "Microporous and Mesoporous Materials",
issn = "1387-1811",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Alkane/alkene mixture diffusion in silicalite-1 studied by MAS PFG NMR

AU - Dvoyashkina, Nina

AU - Freude, Dieter

AU - Stepanov, Alexander G.

AU - Böhlmann, Winfried

AU - Krishna, Rajamani

AU - Kärger, Jörg

AU - Haase, Jürgen

PY - 2018/2/1

Y1 - 2018/2/1

N2 - The diffusivity of n-alkanes and n-alkenes (C2 to C6) and their mixtures in silicalite-1 was studied by magic-angle spinning pulsed field-gradient nuclear magnetic resonance (MAS PFG NMR) at the temperatures of 273 K, 313 K and 373 K. It could be proved that there is no significant difference between the diffusivities of alkanes, alkenes and their mixtures for equal carbon numbers and equal total loading. The diffusivities of the alkanes, alkenes and their mixtures are found to monotonically decrease with increasing carbon number, in agreement with the results obtained in MD simulations with n-alkanes in silicalite-1.

AB - The diffusivity of n-alkanes and n-alkenes (C2 to C6) and their mixtures in silicalite-1 was studied by magic-angle spinning pulsed field-gradient nuclear magnetic resonance (MAS PFG NMR) at the temperatures of 273 K, 313 K and 373 K. It could be proved that there is no significant difference between the diffusivities of alkanes, alkenes and their mixtures for equal carbon numbers and equal total loading. The diffusivities of the alkanes, alkenes and their mixtures are found to monotonically decrease with increasing carbon number, in agreement with the results obtained in MD simulations with n-alkanes in silicalite-1.

KW - MFI-TYPE ZEOLITES

KW - ELASTIC NEUTRON-SCATTERING

KW - SELF-DIFFUSION

KW - N-ALKANES

KW - CRYSTALLINE MATERIALS

KW - LOADING DEPENDENCE

KW - DIFFUSIVITIES

KW - SIMULATIONS

KW - DYNAMICS

KW - TRANSPORT

UR - http://www.scopus.com/inward/record.url?scp=85028053939&partnerID=8YFLogxK

U2 - 10.1016/j.micromeso.2017.08.015

DO - 10.1016/j.micromeso.2017.08.015

M3 - Article

AN - SCOPUS:85028053939

VL - 257

SP - 128

EP - 134

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

SN - 1387-1811

ER -

ID: 9264947