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A study of structural non-stoichiometry with respect to oxygen in RBaCo4O7+x single crystals. / Podberezskaya, N. V.; Komarov, V. Yu; Kameneva, M. Yu и др.

в: Journal of Structural Chemistry, Том 58, № 5, 01.09.2017, стр. 930-939.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Podberezskaya, NV, Komarov, VY, Kameneva, MY, Kozeeva, LP & Lavrov, AN 2017, 'A study of structural non-stoichiometry with respect to oxygen in RBaCo4O7+x single crystals', Journal of Structural Chemistry, Том. 58, № 5, стр. 930-939. https://doi.org/10.1134/S0022476617050110

APA

Podberezskaya, N. V., Komarov, V. Y., Kameneva, M. Y., Kozeeva, L. P., & Lavrov, A. N. (2017). A study of structural non-stoichiometry with respect to oxygen in RBaCo4O7+x single crystals. Journal of Structural Chemistry, 58(5), 930-939. https://doi.org/10.1134/S0022476617050110

Vancouver

Podberezskaya NV, Komarov VY, Kameneva MY, Kozeeva LP, Lavrov AN. A study of structural non-stoichiometry with respect to oxygen in RBaCo4O7+x single crystals. Journal of Structural Chemistry. 2017 сент. 1;58(5):930-939. doi: 10.1134/S0022476617050110

Author

Podberezskaya, N. V. ; Komarov, V. Yu ; Kameneva, M. Yu и др. / A study of structural non-stoichiometry with respect to oxygen in RBaCo4O7+x single crystals. в: Journal of Structural Chemistry. 2017 ; Том 58, № 5. стр. 930-939.

BibTeX

@article{b96f9768c7a6476e8e8887931619171c,
title = "A study of structural non-stoichiometry with respect to oxygen in RBaCo4O7+x single crystals",
abstract = "Impurity-free RBaCo4O7+x (R = Y, Lu) crystals are grown and the evolution of their structure with varying oxygen concentration in the range 0 ≤ x ≤ 1.3 is studied. The structural features of the studied samples required to develop an extended strategy of the X-ray crystallographic experiment, which made it possible to obtain more accurate data on unit cell parameters and additional information on the features of superstructure modulation and diffuse scattering, along with the phase composition of crystalline samples. A crystal chemical analysis of the known structural models of RBaCo4O7+x is performed and suggestions are made about possible structural changes occurring when the oxygen concentration increases up to the limit.",
keywords = "cobaltates, oxygen non-stoichiometry, single crystals, structural analysis, structural models, X-ray diffraction data processing, SWEDENBORGITE, TEMPERATURE, YBACO4O7+DELTA",
author = "Podberezskaya, {N. V.} and Komarov, {V. Yu} and Kameneva, {M. Yu} and Kozeeva, {L. P.} and Lavrov, {A. N.}",
year = "2017",
month = sep,
day = "1",
doi = "10.1134/S0022476617050110",
language = "English",
volume = "58",
pages = "930--939",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "5",

}

RIS

TY - JOUR

T1 - A study of structural non-stoichiometry with respect to oxygen in RBaCo4O7+x single crystals

AU - Podberezskaya, N. V.

AU - Komarov, V. Yu

AU - Kameneva, M. Yu

AU - Kozeeva, L. P.

AU - Lavrov, A. N.

PY - 2017/9/1

Y1 - 2017/9/1

N2 - Impurity-free RBaCo4O7+x (R = Y, Lu) crystals are grown and the evolution of their structure with varying oxygen concentration in the range 0 ≤ x ≤ 1.3 is studied. The structural features of the studied samples required to develop an extended strategy of the X-ray crystallographic experiment, which made it possible to obtain more accurate data on unit cell parameters and additional information on the features of superstructure modulation and diffuse scattering, along with the phase composition of crystalline samples. A crystal chemical analysis of the known structural models of RBaCo4O7+x is performed and suggestions are made about possible structural changes occurring when the oxygen concentration increases up to the limit.

AB - Impurity-free RBaCo4O7+x (R = Y, Lu) crystals are grown and the evolution of their structure with varying oxygen concentration in the range 0 ≤ x ≤ 1.3 is studied. The structural features of the studied samples required to develop an extended strategy of the X-ray crystallographic experiment, which made it possible to obtain more accurate data on unit cell parameters and additional information on the features of superstructure modulation and diffuse scattering, along with the phase composition of crystalline samples. A crystal chemical analysis of the known structural models of RBaCo4O7+x is performed and suggestions are made about possible structural changes occurring when the oxygen concentration increases up to the limit.

KW - cobaltates

KW - oxygen non-stoichiometry

KW - single crystals

KW - structural analysis

KW - structural models

KW - X-ray diffraction data processing

KW - SWEDENBORGITE

KW - TEMPERATURE

KW - YBACO4O7+DELTA

UR - http://www.scopus.com/inward/record.url?scp=85032012163&partnerID=8YFLogxK

U2 - 10.1134/S0022476617050110

DO - 10.1134/S0022476617050110

M3 - Article

AN - SCOPUS:85032012163

VL - 58

SP - 930

EP - 939

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 5

ER -

ID: 9874712