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A red-emitting Mn(II)-based coordination polymer build on 1,2,4,5-tetrakis(diphenylphosphinyl)benzene. / Berezin, Alexey S.; Davydova, Maria P.; Bagryanskaya, Irina Yu и др.

в: Inorganic Chemistry Communications, Том 107, 107473, 01.09.2019.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Berezin, AS, Davydova, MP, Bagryanskaya, IY, Artyushin, OI, Brel, VK & Artem'ev, AV 2019, 'A red-emitting Mn(II)-based coordination polymer build on 1,2,4,5-tetrakis(diphenylphosphinyl)benzene', Inorganic Chemistry Communications, Том. 107, 107473. https://doi.org/10.1016/j.inoche.2019.107473

APA

Berezin, A. S., Davydova, M. P., Bagryanskaya, I. Y., Artyushin, O. I., Brel, V. K., & Artem'ev, A. V. (2019). A red-emitting Mn(II)-based coordination polymer build on 1,2,4,5-tetrakis(diphenylphosphinyl)benzene. Inorganic Chemistry Communications, 107, [107473]. https://doi.org/10.1016/j.inoche.2019.107473

Vancouver

Berezin AS, Davydova MP, Bagryanskaya IY, Artyushin OI, Brel VK, Artem'ev AV. A red-emitting Mn(II)-based coordination polymer build on 1,2,4,5-tetrakis(diphenylphosphinyl)benzene. Inorganic Chemistry Communications. 2019 сент. 1;107:107473. doi: 10.1016/j.inoche.2019.107473

Author

Berezin, Alexey S. ; Davydova, Maria P. ; Bagryanskaya, Irina Yu и др. / A red-emitting Mn(II)-based coordination polymer build on 1,2,4,5-tetrakis(diphenylphosphinyl)benzene. в: Inorganic Chemistry Communications. 2019 ; Том 107.

BibTeX

@article{ace925a03e294a6eabf0da5b2694a051,
title = "A red-emitting Mn(II)-based coordination polymer build on 1,2,4,5-tetrakis(diphenylphosphinyl)benzene",
abstract = "The reaction of Mn(ClO4)2·6H2O with 1,2,4,5-tetrakis(diphenylphosphinyl)benzene (L) in DMF affords one-dimensional coordination polymer (CP), [MnL(DMF)2](ClO4)2·DMF, in 87% yield. The cationic chains of the CP are assembled from alternating Mn(II) ions and ligand molecules; each metal ion has a octahedral MnO6 environment composed of four oxygen atoms from two adjacent ligands and two DMF oxygen atoms. At the temperatures below 200 K, this CP demonstrates a red phosphorescence with λ [Formula presented] ~660 nm and lifetimes of 1.5–4.5 ms. The EPR study reveals the high-spin state of the Mn(II) ions and the absence of exchange interactions between them.",
keywords = "Coordination polymers, EPR, Manganese luminescence, Phosphine oxide, Phosphorescence, MANGANESE(II), PHOTOLUMINESCENCE, OXIDE, COMPLEXES, TRIBOLUMINESCENCE, ORGANIC-INORGANIC HYBRID, HIGH QUANTUM YIELD, LUMINESCENCE, LIGHT EMISSION, MN2+",
author = "Berezin, {Alexey S.} and Davydova, {Maria P.} and Bagryanskaya, {Irina Yu} and Artyushin, {Oleg I.} and Brel, {Valery K.} and Artem'ev, {Alexander V.}",
note = "Publisher Copyright: {\textcopyright} 2019 Elsevier B.V.",
year = "2019",
month = sep,
day = "1",
doi = "10.1016/j.inoche.2019.107473",
language = "English",
volume = "107",
journal = "Inorganic Chemistry Communication",
issn = "1387-7003",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - A red-emitting Mn(II)-based coordination polymer build on 1,2,4,5-tetrakis(diphenylphosphinyl)benzene

AU - Berezin, Alexey S.

AU - Davydova, Maria P.

AU - Bagryanskaya, Irina Yu

AU - Artyushin, Oleg I.

AU - Brel, Valery K.

AU - Artem'ev, Alexander V.

N1 - Publisher Copyright: © 2019 Elsevier B.V.

PY - 2019/9/1

Y1 - 2019/9/1

N2 - The reaction of Mn(ClO4)2·6H2O with 1,2,4,5-tetrakis(diphenylphosphinyl)benzene (L) in DMF affords one-dimensional coordination polymer (CP), [MnL(DMF)2](ClO4)2·DMF, in 87% yield. The cationic chains of the CP are assembled from alternating Mn(II) ions and ligand molecules; each metal ion has a octahedral MnO6 environment composed of four oxygen atoms from two adjacent ligands and two DMF oxygen atoms. At the temperatures below 200 K, this CP demonstrates a red phosphorescence with λ [Formula presented] ~660 nm and lifetimes of 1.5–4.5 ms. The EPR study reveals the high-spin state of the Mn(II) ions and the absence of exchange interactions between them.

AB - The reaction of Mn(ClO4)2·6H2O with 1,2,4,5-tetrakis(diphenylphosphinyl)benzene (L) in DMF affords one-dimensional coordination polymer (CP), [MnL(DMF)2](ClO4)2·DMF, in 87% yield. The cationic chains of the CP are assembled from alternating Mn(II) ions and ligand molecules; each metal ion has a octahedral MnO6 environment composed of four oxygen atoms from two adjacent ligands and two DMF oxygen atoms. At the temperatures below 200 K, this CP demonstrates a red phosphorescence with λ [Formula presented] ~660 nm and lifetimes of 1.5–4.5 ms. The EPR study reveals the high-spin state of the Mn(II) ions and the absence of exchange interactions between them.

KW - Coordination polymers

KW - EPR

KW - Manganese luminescence

KW - Phosphine oxide

KW - Phosphorescence

KW - MANGANESE(II)

KW - PHOTOLUMINESCENCE

KW - OXIDE

KW - COMPLEXES

KW - TRIBOLUMINESCENCE

KW - ORGANIC-INORGANIC HYBRID

KW - HIGH QUANTUM YIELD

KW - LUMINESCENCE

KW - LIGHT EMISSION

KW - MN2+

UR - http://www.scopus.com/inward/record.url?scp=85068581289&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2019.107473

DO - 10.1016/j.inoche.2019.107473

M3 - Article

AN - SCOPUS:85068581289

VL - 107

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

M1 - 107473

ER -

ID: 20780075