TY - JOUR

T1 - A photoinert member of a photosensitive family. Structural studies of cobalt(III) nitropentammine malonate, [Co(NH3)5NO2]C3H2O4, under variable temperature and pressure help to explain the phenomenon

AU - Kalinina, Polina P.

AU - Zakharov, Boris A.

AU - Boldyreva, Elena V.

PY - 2025/10

Y1 - 2025/10

N2 - A large family of photosensitive [Co(NH3)5NO2] XY compounds is known to manifest mechanical effects accompanying intramolecular photochemical linkage nitro–nitrito isomerization. A new member of this family, a malonate, [Co(NH3)5 NO2]C3H2O4, was synthesized for the first time and shown to be photoinert. The compound appears to be the first photoinert member of the family. The crystal structure was analysed both at ambient conditions and under variable temperature and pressure, and compared to previously known members of the family in order to rationalize such behaviour. A reversible isosymmetric single-crystal to single-crystal phase transition was observed at pressures between 2.4 and 3.0 GPa, and the crystal structure of a new high-pressure phase was solved and refined. Possible driving forces for the phase transition are discussed.

AB - A large family of photosensitive [Co(NH3)5NO2] XY compounds is known to manifest mechanical effects accompanying intramolecular photochemical linkage nitro–nitrito isomerization. A new member of this family, a malonate, [Co(NH3)5 NO2]C3H2O4, was synthesized for the first time and shown to be photoinert. The compound appears to be the first photoinert member of the family. The crystal structure was analysed both at ambient conditions and under variable temperature and pressure, and compared to previously known members of the family in order to rationalize such behaviour. A reversible isosymmetric single-crystal to single-crystal phase transition was observed at pressures between 2.4 and 3.0 GPa, and the crystal structure of a new high-pressure phase was solved and refined. Possible driving forces for the phase transition are discussed.

KW - photomechanical effects

KW - linkage isomerization

KW - photocrystallography

KW - coordination compounds

KW - hydrogen bonds

UR - https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=105018691689&origin=inward

UR - https://www.mendeley.com/catalogue/65044fc1-443f-3e32-8baf-093b9fa23996/

U2 - 10.1107/s2052520625006742

DO - 10.1107/s2052520625006742

M3 - Article

C2 - 40906550

VL - 81

SP - 445

EP - 456

JO - Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials

JF - Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials

SN - 2052-5192

IS - 5

ER -