Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
A Novel Family of Polyiodo-Bromoantimonate(III) Complexes : Cation-Driven Self-Assembly of Photoconductive Metal-Polyhalide Frameworks. / Adonin, Sergey A.; Udalova, Liubov I.; Abramov, Pavel A. и др.
в: Chemistry - A European Journal, Том 24, № 55, 01.10.2018, стр. 14707-14711.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - A Novel Family of Polyiodo-Bromoantimonate(III) Complexes
T2 - Cation-Driven Self-Assembly of Photoconductive Metal-Polyhalide Frameworks
AU - Adonin, Sergey A.
AU - Udalova, Liubov I.
AU - Abramov, Pavel A.
AU - Novikov, Alexander S.
AU - Yushina, Irina V.
AU - Korolkov, Ilya V.
AU - Semitut, Evgeniy Y.
AU - Derzhavskaya, Tatiyana A.
AU - Stevenson, Keith J.
AU - Troshin, Pavel A.
AU - Sokolov, Maxim N.
AU - Fedin, Vladimir P.
N1 - © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
PY - 2018/10/1
Y1 - 2018/10/1
N2 - In the presence of different cations, reactions of [SbBr6]3− and I2 result in a new family of diverse supramolecular 1D polyiodide-bromoantimonate networks. The coordination number of Sb, as well as geometry of assembling {Ix}n− polyhalide units, can vary, resulting in unprecedented structural types. The nature of I⋅⋅⋅Br interactions was studied by DFT calculations; estimated energy values are 1.6–6.9 kcal mol−1. Some of the compounds showed strong photoconductivity in thin films, suggesting multiple feasible applications in optoelectronics and solar energy conversion.
AB - In the presence of different cations, reactions of [SbBr6]3− and I2 result in a new family of diverse supramolecular 1D polyiodide-bromoantimonate networks. The coordination number of Sb, as well as geometry of assembling {Ix}n− polyhalide units, can vary, resulting in unprecedented structural types. The nature of I⋅⋅⋅Br interactions was studied by DFT calculations; estimated energy values are 1.6–6.9 kcal mol−1. Some of the compounds showed strong photoconductivity in thin films, suggesting multiple feasible applications in optoelectronics and solar energy conversion.
KW - antimony
KW - DFT calculations
KW - halometalate
KW - photoconductivity
KW - polyhalide
KW - ANIONS
KW - POLYIODIDE NETWORKS
KW - CRYSTAL-STRUCTURE
KW - NONABROMOANTIMONATE(V)
KW - COMPOUND
KW - HALOGEN
KW - I-2
KW - IODIDES
KW - BROMINE
KW - CHEMISTRY
UR - http://www.scopus.com/inward/record.url?scp=85052955781&partnerID=8YFLogxK
U2 - 10.1002/chem.201802100
DO - 10.1002/chem.201802100
M3 - Article
C2 - 30020549
AN - SCOPUS:85052955781
VL - 24
SP - 14707
EP - 14711
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
SN - 0947-6539
IS - 55
ER -
ID: 16482727