Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
A new subclass of copper(I) hybrid emitters showing TADF with near-unity quantum yields and a strong solvatochromic effect. / Baranov, Andrey Yu; Rakhmanova, Mariana I; Hei, Xiuze и др.
в: Chemical communications (Cambridge, England), Том 59, № 20, 07.03.2023, стр. 2923-2926.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - A new subclass of copper(I) hybrid emitters showing TADF with near-unity quantum yields and a strong solvatochromic effect
AU - Baranov, Andrey Yu
AU - Rakhmanova, Mariana I
AU - Hei, Xiuze
AU - Samsonenko, Denis G
AU - Stass, Dmitri V
AU - Bagryanskaya, Irina Yu
AU - Ryzhikov, Maxim R
AU - Fedin, Vladimir P
AU - Li, Jing
AU - Artem'ev, Alexander V
PY - 2023/3/7
Y1 - 2023/3/7
N2 - We introduce here a new subclass of copper(I) hybrid emitters simultaneously containing [CuxIy]z- anions and Cu+ cations, separated in space by a Janus head ligand. When UV-irradiated at 298 K, these unique "Two-In-One" hybrids exhibit a short-lived green TADF with near-unity quantum yield and a strong solvatochromic effect. Moreover, they manifest a strong radioluminescence upon X-ray irradiation. These findings open up new possibilities for the design of highly performing TADF materials.
AB - We introduce here a new subclass of copper(I) hybrid emitters simultaneously containing [CuxIy]z- anions and Cu+ cations, separated in space by a Janus head ligand. When UV-irradiated at 298 K, these unique "Two-In-One" hybrids exhibit a short-lived green TADF with near-unity quantum yield and a strong solvatochromic effect. Moreover, they manifest a strong radioluminescence upon X-ray irradiation. These findings open up new possibilities for the design of highly performing TADF materials.
UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85149005740&origin=inward&txGid=2b5d3aa503ad2c47a1e41d4ab7ea88f8
UR - https://www.mendeley.com/catalogue/a513d06f-cd67-38e0-9925-eb0a23137a98/
U2 - 10.1039/d3cc00119a
DO - 10.1039/d3cc00119a
M3 - Article
C2 - 36799209
VL - 59
SP - 2923
EP - 2926
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 20
ER -
ID: 44572627