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A new nonlinear optical crystal Li0.81Ag0.19InSe2 with balanced properties for efficient nonlinear conversion in the mid-IR region. / Isaenko, Ludmila; Dong, Linfeng; Yelisseyev, Alexander и др.

в: Journal of Alloys and Compounds, Том 969, 172382, 25.12.2023.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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Isaenko L, Dong L, Yelisseyev A, Lobanov S, Korzhneva K, Gromilov S и др. A new nonlinear optical crystal Li0.81Ag0.19InSe2 with balanced properties for efficient nonlinear conversion in the mid-IR region. Journal of Alloys and Compounds. 2023 дек. 25;969:172382. doi: 10.1016/j.jallcom.2023.172382

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BibTeX

@article{63f80fa7cd174b068f7f3e56a5796658,
title = "A new nonlinear optical crystal Li0.81Ag0.19InSe2 with balanced properties for efficient nonlinear conversion in the mid-IR region",
abstract = "The achievement of balanced properties among nonlinear optical (NLO) effect, laser induced damage threshold (LIDT) and optical birefringence is the key to obtain the excellent NLO crystals for harmonic mid-IR coherent radiation generation. In this work, we successfully synthesize and grow a new NLO chalcogenide crystal Li0.81Ag0.19InSe2 by utilizing a molecular design strategy with rational replacement between Li and Ag. This crystal not only enlarges the very low birefringence in AgInSe2 from ∼ 0.017 to ∼ 0.047, but also improves the rather small NLO effect in LiInSe2 from 11.8 pm/V to ∼26 pm/V while maintaining the LIDT almost unchanged. Based on the large size Li0.81Ag0.19InSe2 single crystals of optical quality, the spectroscopic properties are measured and the main parameters important for NLO output are determined. All these results demonstrate that Li0.81Ag0.19InSe2 is a promising mid-IR NLO crystal with balanced properties.",
keywords = "Birefringence and phase-matching, Chalcogenides, Damage threshold, Energy band gap, Laser induced, Mid-IR nonlinear optical crystals, Second harmonic generation, Structure analysis",
author = "Ludmila Isaenko and Linfeng Dong and Alexander Yelisseyev and Sergei Lobanov and Ksenia Korzhneva and Sergey Gromilov and Alexander Sukhih and Alexei Pugachev and Vitaly Vedenyapin and Alexei Kurus and Avag Khamoyan and Zheshuai Lin",
note = "This work was supported by the National Natural Science Foundation of China (Grant No. 22133004 ), Russian Science Foundation , grant # 19-12-00085-P (crystal growth, crystal structure analysis, band gap measurement), Ministry of Education and Science of the Russian Federation , grant FSUS-2020-0036 (SHG coefficients measurements), and partly done on state assignment of IGM SB RAS No. 122041400031-2 (composition chemical analysis). Публикация для корректировки.",
year = "2023",
month = dec,
day = "25",
doi = "10.1016/j.jallcom.2023.172382",
language = "English",
volume = "969",
journal = "Journal of Alloys and Compounds",
issn = "0925-8388",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - A new nonlinear optical crystal Li0.81Ag0.19InSe2 with balanced properties for efficient nonlinear conversion in the mid-IR region

AU - Isaenko, Ludmila

AU - Dong, Linfeng

AU - Yelisseyev, Alexander

AU - Lobanov, Sergei

AU - Korzhneva, Ksenia

AU - Gromilov, Sergey

AU - Sukhih, Alexander

AU - Pugachev, Alexei

AU - Vedenyapin, Vitaly

AU - Kurus, Alexei

AU - Khamoyan, Avag

AU - Lin, Zheshuai

N1 - This work was supported by the National Natural Science Foundation of China (Grant No. 22133004 ), Russian Science Foundation , grant # 19-12-00085-P (crystal growth, crystal structure analysis, band gap measurement), Ministry of Education and Science of the Russian Federation , grant FSUS-2020-0036 (SHG coefficients measurements), and partly done on state assignment of IGM SB RAS No. 122041400031-2 (composition chemical analysis). Публикация для корректировки.

PY - 2023/12/25

Y1 - 2023/12/25

N2 - The achievement of balanced properties among nonlinear optical (NLO) effect, laser induced damage threshold (LIDT) and optical birefringence is the key to obtain the excellent NLO crystals for harmonic mid-IR coherent radiation generation. In this work, we successfully synthesize and grow a new NLO chalcogenide crystal Li0.81Ag0.19InSe2 by utilizing a molecular design strategy with rational replacement between Li and Ag. This crystal not only enlarges the very low birefringence in AgInSe2 from ∼ 0.017 to ∼ 0.047, but also improves the rather small NLO effect in LiInSe2 from 11.8 pm/V to ∼26 pm/V while maintaining the LIDT almost unchanged. Based on the large size Li0.81Ag0.19InSe2 single crystals of optical quality, the spectroscopic properties are measured and the main parameters important for NLO output are determined. All these results demonstrate that Li0.81Ag0.19InSe2 is a promising mid-IR NLO crystal with balanced properties.

AB - The achievement of balanced properties among nonlinear optical (NLO) effect, laser induced damage threshold (LIDT) and optical birefringence is the key to obtain the excellent NLO crystals for harmonic mid-IR coherent radiation generation. In this work, we successfully synthesize and grow a new NLO chalcogenide crystal Li0.81Ag0.19InSe2 by utilizing a molecular design strategy with rational replacement between Li and Ag. This crystal not only enlarges the very low birefringence in AgInSe2 from ∼ 0.017 to ∼ 0.047, but also improves the rather small NLO effect in LiInSe2 from 11.8 pm/V to ∼26 pm/V while maintaining the LIDT almost unchanged. Based on the large size Li0.81Ag0.19InSe2 single crystals of optical quality, the spectroscopic properties are measured and the main parameters important for NLO output are determined. All these results demonstrate that Li0.81Ag0.19InSe2 is a promising mid-IR NLO crystal with balanced properties.

KW - Birefringence and phase-matching

KW - Chalcogenides

KW - Damage threshold

KW - Energy band gap

KW - Laser induced

KW - Mid-IR nonlinear optical crystals

KW - Second harmonic generation

KW - Structure analysis

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85169422494&origin=inward&txGid=3e0bb0ab3f6f06e9bb1517196647c0d9

UR - https://www.mendeley.com/catalogue/1594cb9c-5915-3b59-91ef-fdf168a20d95/

U2 - 10.1016/j.jallcom.2023.172382

DO - 10.1016/j.jallcom.2023.172382

M3 - Article

VL - 969

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

SN - 0925-8388

M1 - 172382

ER -

ID: 59208699