Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
A new Cu(I) iodide complex showing deep-red luminescence. / Artem′ev, A. V.; Rakhmanova, M. I.; Brylev, K. A. и др.
в: Journal of Structural Chemistry, Том 61, № 7, 01.07.2020, стр. 1068-1071.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - A new Cu(I) iodide complex showing deep-red luminescence
AU - Artem′ev, A. V.
AU - Rakhmanova, M. I.
AU - Brylev, K. A.
AU - Bagryanskaya, I. Yu
PY - 2020/7/1
Y1 - 2020/7/1
N2 - A reaction of a [1,4-C6H4(CH2PPy3)2]Cl2 cationic ligand with CuI (MeCN, r.t.) produces an ionic [C6H4(CH2PPy3)2][C6H4(CH2PPy3Cu3I5)2] complex containing structurally unprecedented [Cu3I5]2– inorganic module in the anionic part. The title complex in the solid manifests a weak deep-red luminescence with λmax = 680 nm and lifetimes of 14 μs and 17 μs at 300 K and 77 K, respectively.
AB - A reaction of a [1,4-C6H4(CH2PPy3)2]Cl2 cationic ligand with CuI (MeCN, r.t.) produces an ionic [C6H4(CH2PPy3)2][C6H4(CH2PPy3Cu3I5)2] complex containing structurally unprecedented [Cu3I5]2– inorganic module in the anionic part. The title complex in the solid manifests a weak deep-red luminescence with λmax = 680 nm and lifetimes of 14 μs and 17 μs at 300 K and 77 K, respectively.
KW - crystal structure
KW - Cu(I) complexes
KW - iodocuprates
KW - photoluminescence
KW - pyridylphosphonium salts
UR - http://www.scopus.com/inward/record.url?scp=85090239792&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/71e17027-0a0e-31bb-ab77-69e3ac34cf80/
U2 - 10.1134/S0022476620070082
DO - 10.1134/S0022476620070082
M3 - Article
AN - SCOPUS:85090239792
VL - 61
SP - 1068
EP - 1071
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 7
ER -
ID: 25288063