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A New Approach for the Synthesis of 2,3,4а,6,7,8а,9,10-Octaaza-4,8-dioxo-3,4,4a,7,8,8а,9,9a,10,10а-decahydroanthracene and High-Energy Performance Characterization of Its Dinitramide Salt. / Glukhacheva, Vera S; Il'yasov, Sergey G; Il'yasov, Dmitri S и др.

в: Materials, Том 16, № 23, 7437, 29.11.2023.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Glukhacheva, VS, Il'yasov, SG, Il'yasov, DS, Zhukov, EE, Eltsov, IV & Nefedov, AA 2023, 'A New Approach for the Synthesis of 2,3,4а,6,7,8а,9,10-Octaaza-4,8-dioxo-3,4,4a,7,8,8а,9,9a,10,10а-decahydroanthracene and High-Energy Performance Characterization of Its Dinitramide Salt', Materials, Том. 16, № 23, 7437. https://doi.org/10.3390/ma16237437

APA

Glukhacheva, V. S., Il'yasov, S. G., Il'yasov, D. S., Zhukov, E. E., Eltsov, I. V., & Nefedov, A. A. (2023). A New Approach for the Synthesis of 2,3,4а,6,7,8а,9,10-Octaaza-4,8-dioxo-3,4,4a,7,8,8а,9,9a,10,10а-decahydroanthracene and High-Energy Performance Characterization of Its Dinitramide Salt. Materials, 16(23), [7437]. https://doi.org/10.3390/ma16237437

Vancouver

Glukhacheva VS, Il'yasov SG, Il'yasov DS, Zhukov EE, Eltsov IV, Nefedov AA. A New Approach for the Synthesis of 2,3,4а,6,7,8а,9,10-Octaaza-4,8-dioxo-3,4,4a,7,8,8а,9,9a,10,10а-decahydroanthracene and High-Energy Performance Characterization of Its Dinitramide Salt. Materials. 2023 нояб. 29;16(23):7437. doi: 10.3390/ma16237437

Author

Glukhacheva, Vera S ; Il'yasov, Sergey G ; Il'yasov, Dmitri S и др. / A New Approach for the Synthesis of 2,3,4а,6,7,8а,9,10-Octaaza-4,8-dioxo-3,4,4a,7,8,8а,9,9a,10,10а-decahydroanthracene and High-Energy Performance Characterization of Its Dinitramide Salt. в: Materials. 2023 ; Том 16, № 23.

BibTeX

@article{97265f1e521e4fb7ba198c8e2f3e15b9,
title = "A New Approach for the Synthesis of 2,3,4а,6,7,8а,9,10-Octaaza-4,8-dioxo-3,4,4a,7,8,8а,9,9a,10,10а-decahydroanthracene and High-Energy Performance Characterization of Its Dinitramide Salt",
abstract = "A simple, one-pot regioselective method for the synthesis of a high-nitrogen tricycle, 2,3,4а,6,7,8а,9,10-octaaza-4,8-dioxo-3,4,4a,7,8,8а,9,9a,10,10а-decahydroanthracene, with a yield of 27% was developed on a starting urea basis as a result of studies focused on finding new, more efficient approaches to the synthesis of high-energy derivatives of dinitramic acid (DNA). This tricycle was further treated to furnish 2,3,4а,6,7,8а,9,10-octaaza-4,8-dioxo-3,4,4a,7,8,8а,9a,10а-octohydroanthracene-9,10-ion-bis(dinitramide). The resultant salt of dinitramic acid exhibited inhibitory properties towards the burning rate of pyrotechnic compositions, reducing it by 30%, and possessed good thermal stability due to a high decomposition temperature above 260 °C and a low sensitivity to mechanical stimuli. The structural features of the new tricycle-based dinitramide salt were characterized via 2D NMR spectroscopy and double-focusing sector mass spectrometry (DFS).",
author = "Glukhacheva, {Vera S} and Il'yasov, {Sergey G} and Il'yasov, {Dmitri S} and Zhukov, {Egor E} and Eltsov, {Ilia V} and Nefedov, {Andrey A}",
note = "This research was supported by the Ministry of Science and Higher Education of the Russian Federation (grant No. 075-15-2020-803 with the Zelinsky Institute of Organic Chemistry of the RAS).",
year = "2023",
month = nov,
day = "29",
doi = "10.3390/ma16237437",
language = "English",
volume = "16",
journal = "Materials",
issn = "1996-1944",
publisher = "MDPI AG",
number = "23",

}

RIS

TY - JOUR

T1 - A New Approach for the Synthesis of 2,3,4а,6,7,8а,9,10-Octaaza-4,8-dioxo-3,4,4a,7,8,8а,9,9a,10,10а-decahydroanthracene and High-Energy Performance Characterization of Its Dinitramide Salt

AU - Glukhacheva, Vera S

AU - Il'yasov, Sergey G

AU - Il'yasov, Dmitri S

AU - Zhukov, Egor E

AU - Eltsov, Ilia V

AU - Nefedov, Andrey A

N1 - This research was supported by the Ministry of Science and Higher Education of the Russian Federation (grant No. 075-15-2020-803 with the Zelinsky Institute of Organic Chemistry of the RAS).

PY - 2023/11/29

Y1 - 2023/11/29

N2 - A simple, one-pot regioselective method for the synthesis of a high-nitrogen tricycle, 2,3,4а,6,7,8а,9,10-octaaza-4,8-dioxo-3,4,4a,7,8,8а,9,9a,10,10а-decahydroanthracene, with a yield of 27% was developed on a starting urea basis as a result of studies focused on finding new, more efficient approaches to the synthesis of high-energy derivatives of dinitramic acid (DNA). This tricycle was further treated to furnish 2,3,4а,6,7,8а,9,10-octaaza-4,8-dioxo-3,4,4a,7,8,8а,9a,10а-octohydroanthracene-9,10-ion-bis(dinitramide). The resultant salt of dinitramic acid exhibited inhibitory properties towards the burning rate of pyrotechnic compositions, reducing it by 30%, and possessed good thermal stability due to a high decomposition temperature above 260 °C and a low sensitivity to mechanical stimuli. The structural features of the new tricycle-based dinitramide salt were characterized via 2D NMR spectroscopy and double-focusing sector mass spectrometry (DFS).

AB - A simple, one-pot regioselective method for the synthesis of a high-nitrogen tricycle, 2,3,4а,6,7,8а,9,10-octaaza-4,8-dioxo-3,4,4a,7,8,8а,9,9a,10,10а-decahydroanthracene, with a yield of 27% was developed on a starting urea basis as a result of studies focused on finding new, more efficient approaches to the synthesis of high-energy derivatives of dinitramic acid (DNA). This tricycle was further treated to furnish 2,3,4а,6,7,8а,9,10-octaaza-4,8-dioxo-3,4,4a,7,8,8а,9a,10а-octohydroanthracene-9,10-ion-bis(dinitramide). The resultant salt of dinitramic acid exhibited inhibitory properties towards the burning rate of pyrotechnic compositions, reducing it by 30%, and possessed good thermal stability due to a high decomposition temperature above 260 °C and a low sensitivity to mechanical stimuli. The structural features of the new tricycle-based dinitramide salt were characterized via 2D NMR spectroscopy and double-focusing sector mass spectrometry (DFS).

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85179135745&origin=inward&txGid=68b8b717e6f80b1ca31998e37e6bec34

U2 - 10.3390/ma16237437

DO - 10.3390/ma16237437

M3 - Article

C2 - 38068181

VL - 16

JO - Materials

JF - Materials

SN - 1996-1944

IS - 23

M1 - 7437

ER -

ID: 59330452