Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
A layered Ag(I)-based coordination polymer showing sky-blue luminescence and antibacterial activity. / Rogovoy, Maxim I.; Berezin, Alexey S.; Kozlova, Yuliya N. и др.
в: Inorganic Chemistry Communications, Том 108, 107513, 01.10.2019.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - A layered Ag(I)-based coordination polymer showing sky-blue luminescence and antibacterial activity
AU - Rogovoy, Maxim I.
AU - Berezin, Alexey S.
AU - Kozlova, Yuliya N.
AU - Samsonenko, Denis G.
AU - Artem'ev, Alexander V.
N1 - Publisher Copyright: © 2019 Elsevier B.V. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.
PY - 2019/10/1
Y1 - 2019/10/1
N2 - Reaction of 2-methylthiopyrazine (L) with AgClO4 produces layered coordination polymer (CP), [Ag2L2(ClO4)] n(ClO4)n, in 95% yield. The two-dimensional layers of the latter are assembled from the [Ag2L2(ClO4)] units, in which two metal atoms are bridged by two 2-methylthiopyrazine ligands (μ2-N,S) and one [ClO4]− anion to provide short Ag⋯Ag contact of 2.9776(3) Å. At ambient temperature, this CP manifests solid state sky-blue emission consisting of fluorescence and phosphorescence components with the lifetimes of 3.5 ns and 7 ms, respectively. Moreover, the CP being water soluble exhibits antibacterial activity against Staphylococcus aureus.
AB - Reaction of 2-methylthiopyrazine (L) with AgClO4 produces layered coordination polymer (CP), [Ag2L2(ClO4)] n(ClO4)n, in 95% yield. The two-dimensional layers of the latter are assembled from the [Ag2L2(ClO4)] units, in which two metal atoms are bridged by two 2-methylthiopyrazine ligands (μ2-N,S) and one [ClO4]− anion to provide short Ag⋯Ag contact of 2.9776(3) Å. At ambient temperature, this CP manifests solid state sky-blue emission consisting of fluorescence and phosphorescence components with the lifetimes of 3.5 ns and 7 ms, respectively. Moreover, the CP being water soluble exhibits antibacterial activity against Staphylococcus aureus.
KW - Antibacterial activity
KW - Fluorescence
KW - Layered polymer
KW - Phosphorescence
KW - Pyrazine ligands
KW - Silver(I)
KW - ANIONS
KW - AG(I) COMPLEXES
KW - ACID
KW - PHOTOLUMINESCENCE
KW - SILVER(I) COMPLEXES
KW - CRYSTAL-STRUCTURES
KW - PYRAZINE
KW - LIGANDS SYNTHESES
KW - FLUORESCENCE
KW - EMISSION
UR - http://www.scopus.com/inward/record.url?scp=85070486791&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2019.107513
DO - 10.1016/j.inoche.2019.107513
M3 - Article
AN - SCOPUS:85070486791
VL - 108
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
SN - 1387-7003
M1 - 107513
ER -
ID: 21241410