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A Homochiral Coordination Polymer Based on Copper(II), S-Malic Acid, and Biphenyl-3,3′,5,5′-Tetracarboxilic Acid. / Zavakhina, M. S.; Samsonenko, D. G.; Fedin, V. P.

в: Journal of Structural Chemistry, Том 60, № 2, 01.02.2019, стр. 279-283.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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@article{bcd5ca44e9cb437c9f64aaef10a6db79,
title = "A Homochiral Coordination Polymer Based on Copper(II), S-Malic Acid, and Biphenyl-3,3′,5,5′-Tetracarboxilic Acid",
abstract = " The [Cu 8 (S-mal) 4 (bptc)(H 2 O) 12 ] · 0.5H 4 bptc · 7.5H 2 O coordination polymer is obtained by heating the copper(II) nitrate, S-malic acid (H 3 mal), and biphenyl-3,3′,5,5′-tetracarboxylic (H 4 bptc) acid solution in the water-N,N-diethylformamide mixture. The crystal structure is determined from XRD data. The compound has a three-dimensional homochiral framework with channels filled by crystallization molecules of tetracarboxylic acid and water. The composition and structure of the coordination polymer obtained are confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis. ",
keywords = "chiral complexes, coordination polymers, copper(II) complexes, crystal structure, malic acid",
author = "Zavakhina, {M. S.} and Samsonenko, {D. G.} and Fedin, {V. P.}",
year = "2019",
month = feb,
day = "1",
doi = "10.1134/S0022476619020136",
language = "English",
volume = "60",
pages = "279--283",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "2",

}

RIS

TY - JOUR

T1 - A Homochiral Coordination Polymer Based on Copper(II), S-Malic Acid, and Biphenyl-3,3′,5,5′-Tetracarboxilic Acid

AU - Zavakhina, M. S.

AU - Samsonenko, D. G.

AU - Fedin, V. P.

PY - 2019/2/1

Y1 - 2019/2/1

N2 - The [Cu 8 (S-mal) 4 (bptc)(H 2 O) 12 ] · 0.5H 4 bptc · 7.5H 2 O coordination polymer is obtained by heating the copper(II) nitrate, S-malic acid (H 3 mal), and biphenyl-3,3′,5,5′-tetracarboxylic (H 4 bptc) acid solution in the water-N,N-diethylformamide mixture. The crystal structure is determined from XRD data. The compound has a three-dimensional homochiral framework with channels filled by crystallization molecules of tetracarboxylic acid and water. The composition and structure of the coordination polymer obtained are confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.

AB - The [Cu 8 (S-mal) 4 (bptc)(H 2 O) 12 ] · 0.5H 4 bptc · 7.5H 2 O coordination polymer is obtained by heating the copper(II) nitrate, S-malic acid (H 3 mal), and biphenyl-3,3′,5,5′-tetracarboxylic (H 4 bptc) acid solution in the water-N,N-diethylformamide mixture. The crystal structure is determined from XRD data. The compound has a three-dimensional homochiral framework with channels filled by crystallization molecules of tetracarboxylic acid and water. The composition and structure of the coordination polymer obtained are confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.

KW - chiral complexes

KW - coordination polymers

KW - copper(II) complexes

KW - crystal structure

KW - malic acid

UR - http://www.scopus.com/inward/record.url?scp=85065438454&partnerID=8YFLogxK

U2 - 10.1134/S0022476619020136

DO - 10.1134/S0022476619020136

M3 - Article

AN - SCOPUS:85065438454

VL - 60

SP - 279

EP - 283

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 2

ER -

ID: 20161815