Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
A Complex Powder X-Ray Diffraction Study of Copper-Cerium Oxide Catalysts Prepared by the Pechini Method. / Pakharukova, V. P.; Moroz, E. M.; Potemkin, D. I. и др.
в: Journal of Structural Chemistry, Том 60, № 9, 01.09.2019, стр. 1496-1506.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - A Complex Powder X-Ray Diffraction Study of Copper-Cerium Oxide Catalysts Prepared by the Pechini Method
AU - Pakharukova, V. P.
AU - Moroz, E. M.
AU - Potemkin, D. I.
AU - Snytnikov, P. V.
N1 - Publisher Copyright: © 2019, Pleiades Publishing, Inc.
PY - 2019/9/1
Y1 - 2019/9/1
N2 - By means of a complex of powder X-ray diffraction techniques the features of the structural organization of highly dispersed copper-cerium CuO-CeO2 catalysts prepared by the Pechini method are studied. The current structural technique for studying nanomaterials, namely the atomic pair (interatomic distances) distribution function analysis, is used to refine the phase composition of materials with revealing highly dispersed compounds, sizes of atomic ordering regions, and possible defects. It is shown that materials synthesized from polymeric precursors represent mixed CuO-CeO2 oxides with a high concentration of structural defects. Highly dispersed individual copper compounds are not detected. The results obtained support the previous assumptions that copper cations can incorporate into the structure of cerium dioxide in the composition of copper-cerium catalysts.
AB - By means of a complex of powder X-ray diffraction techniques the features of the structural organization of highly dispersed copper-cerium CuO-CeO2 catalysts prepared by the Pechini method are studied. The current structural technique for studying nanomaterials, namely the atomic pair (interatomic distances) distribution function analysis, is used to refine the phase composition of materials with revealing highly dispersed compounds, sizes of atomic ordering regions, and possible defects. It is shown that materials synthesized from polymeric precursors represent mixed CuO-CeO2 oxides with a high concentration of structural defects. Highly dispersed individual copper compounds are not detected. The results obtained support the previous assumptions that copper cations can incorporate into the structure of cerium dioxide in the composition of copper-cerium catalysts.
KW - atomic pair distribution function analysis
KW - catalysts
KW - cerium dioxide
KW - copper oxide
KW - powder X-ray diffraction
KW - structure
UR - http://www.scopus.com/inward/record.url?scp=85073190421&partnerID=8YFLogxK
U2 - 10.1134/S0022476619090154
DO - 10.1134/S0022476619090154
M3 - Article
AN - SCOPUS:85073190421
VL - 60
SP - 1496
EP - 1506
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 9
ER -
ID: 21856586