TY - JOUR

T1 - A comparative kinetic study of ethylene polymerization mediated by iron, cobalt and chromium catalysts bearing the same N,N,N-bis(imino)trihydroquinoline

AU - Huang, Chuanbing

AU - Zakharov, Vladimir A.

AU - Semikolenova, Nina V.

AU - Matsko, Mikhail A.

AU - Solan, Gregory A.

AU - Sun, Wen Hua

N1 - Publisher Copyright: © 2018 Elsevier Inc.

PY - 2019/1/1

Y1 - 2019/1/1

N2 - The iron(II), cobalt(II) and chromium(III) chlorides, [2-{(2,4,6-Me3C6H2)NCMe}-8-{N(2,4,6-Me3C6H2)}C9H8N]MCln (n = 2, M = Fe LFeCl2, Co LCoCl2; n = 3, M = Cr LCrCl3), each bearing the same N,N,N-bis(imino)trihydroquinoline chelating ligand, have been employed as precatalysts for ethylene polymerization with modified methylaluminoxane (MMAO) as the co-catalyst. The kinetic profiles for these homogeneous polymerizations are reported in addition to the properties of the resultant polymers under comparable reaction conditions. All the experimental data indicate that the active metal center plays a key role on the catalytic performances of the complexes, especially the polymerization activity, thermal stability and lifetime of the active species. Under optimized conditions the iron catalyst displays the highest rate of polymerization but displays this for only a short period, while the chromium catalyst shows a lower maximum polymerization rate but sustains its performance over a longer period and at a higher temperature. In terms of the polymer properties, all three metal catalysts afford highly linear polymers with the metal center influencing the molecular weight and type of end group. Specifically, the cobalt and chromium catalysts produce narrowly dispersed low molecular weight polymers incorporating vinyl end groups, while the iron catalyst affords polymers of higher molecular weight displaying broad molecular weight distributions, with both fully saturated and unsaturated chain ends.

AB - The iron(II), cobalt(II) and chromium(III) chlorides, [2-{(2,4,6-Me3C6H2)NCMe}-8-{N(2,4,6-Me3C6H2)}C9H8N]MCln (n = 2, M = Fe LFeCl2, Co LCoCl2; n = 3, M = Cr LCrCl3), each bearing the same N,N,N-bis(imino)trihydroquinoline chelating ligand, have been employed as precatalysts for ethylene polymerization with modified methylaluminoxane (MMAO) as the co-catalyst. The kinetic profiles for these homogeneous polymerizations are reported in addition to the properties of the resultant polymers under comparable reaction conditions. All the experimental data indicate that the active metal center plays a key role on the catalytic performances of the complexes, especially the polymerization activity, thermal stability and lifetime of the active species. Under optimized conditions the iron catalyst displays the highest rate of polymerization but displays this for only a short period, while the chromium catalyst shows a lower maximum polymerization rate but sustains its performance over a longer period and at a higher temperature. In terms of the polymer properties, all three metal catalysts afford highly linear polymers with the metal center influencing the molecular weight and type of end group. Specifically, the cobalt and chromium catalysts produce narrowly dispersed low molecular weight polymers incorporating vinyl end groups, while the iron catalyst affords polymers of higher molecular weight displaying broad molecular weight distributions, with both fully saturated and unsaturated chain ends.

KW - 2-[1-(Arylimino)ethyl]-8-arylimino-5,6,7-trihydroquinoline

KW - Chromium

KW - Cobalt

KW - Ethylene polymerization

KW - Iron

KW - Kinetic data

KW - PRECATALYSTS

KW - BIS(IMINO)PYRIDINES

KW - NMR SPECTROSCOPIC CHARACTERIZATION

KW - ACTIVE-SITES

KW - BEHAVIOR

KW - 2-(1-(Arylimino)ethyl]-8-arylimino-5,6,7-tri hydroquinoline

KW - LIGANDS

KW - DICHLORIDE SYNTHESIS

KW - VINYL-POLYETHYLENES

KW - CHLORIDE COMPLEXES SYNTHESIS

KW - OLIGOMERIZATION

UR - http://www.scopus.com/inward/record.url?scp=85055980167&partnerID=8YFLogxK

U2 - 10.1016/j.jcat.2018.10.028

DO - 10.1016/j.jcat.2018.10.028

M3 - Article

AN - SCOPUS:85055980167

VL - 369

SP - 1

EP - 9

JO - Journal of Catalysis

JF - Journal of Catalysis

SN - 0021-9517

ER -