Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
8‐[4‐(2‐hydroxypropane‐2‐yl)phenyl]‐1,3,4,4,5,7‐hexamethyl‐4‐ boron‐3a,4a‐diaza‐s‐indacene. / Zobnina, Anastasiya; Moskalensky, Alexander; Vorob’ev, Aleksey.
в: MolBank, Том 2021, № 4, M1286, 12.2021.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - 8‐[4‐(2‐hydroxypropane‐2‐yl)phenyl]‐1,3,4,4,5,7‐hexamethyl‐4‐ boron‐3a,4a‐diaza‐s‐indacene
AU - Zobnina, Anastasiya
AU - Moskalensky, Alexander
AU - Vorob’ev, Aleksey
N1 - Funding Information: Funding: Moskalensky A.E. and Zobnina A.O. acknowledge the Grant of President of Russian Federation for the state support of young scientists (Grant agreement 075‐15‐2021‐453, МК‐4020.2021.1.2). Vorob’ev A. Yu. thanks the Ministry of Science and Higher Education of the Russian Federation for support (Project No. 0238‐2019‐0005). Publisher Copyright: © 2021 by the authors. Licensee MDPI, Basel, Switzerland.
PY - 2021/12
Y1 - 2021/12
N2 - During recent years, the BODIPY core became a popular scaffold for designing photo-removable protecting groups (PPG). In this paper, we report the synthesis of a new mole-cule—8‐[4‐(2‐hydroxypropane‐2‐yl)phenyl]‐1,3,4,4,5,7‐hexamethyl‐4‐boron‐3a,4a‐diaza‐S‐indacene —by the treatment of meso‐(4‐CO2Me‐phenyl)‐BODIPY with excess of MeMgI. The product was characterized by1H,13C NMR and HRMS. The combination of BODIPY core with tertiary benzilyc alcohol might be promising for utilizing this molecule as visible light removable PPG.
AB - During recent years, the BODIPY core became a popular scaffold for designing photo-removable protecting groups (PPG). In this paper, we report the synthesis of a new mole-cule—8‐[4‐(2‐hydroxypropane‐2‐yl)phenyl]‐1,3,4,4,5,7‐hexamethyl‐4‐boron‐3a,4a‐diaza‐S‐indacene —by the treatment of meso‐(4‐CO2Me‐phenyl)‐BODIPY with excess of MeMgI. The product was characterized by1H,13C NMR and HRMS. The combination of BODIPY core with tertiary benzilyc alcohol might be promising for utilizing this molecule as visible light removable PPG.
KW - BODIPY
KW - Methylmagnesium iodide
KW - Photoremovable protecting group
KW - Tertiary alcohol
UR - http://www.scopus.com/inward/record.url?scp=85117348147&partnerID=8YFLogxK
U2 - 10.3390/M1286
DO - 10.3390/M1286
M3 - Article
AN - SCOPUS:85117348147
VL - 2021
JO - MolBank
JF - MolBank
SN - 1422-8599
IS - 4
M1 - M1286
ER -
ID: 34463716