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8‐[4‐(2‐hydroxypropane‐2‐yl)phenyl]‐1,3,4,4,5,7‐hexamethyl‐4‐ boron‐3a,4a‐diaza‐s‐indacene. / Zobnina, Anastasiya; Moskalensky, Alexander; Vorob’ev, Aleksey.

в: MolBank, Том 2021, № 4, M1286, 12.2021.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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@article{32e3f969599f4d27a4d5fa2b8670bd9b,
title = "8‐[4‐(2‐hydroxypropane‐2‐yl)phenyl]‐1,3,4,4,5,7‐hexamethyl‐4‐ boron‐3a,4a‐diaza‐s‐indacene",
abstract = "During recent years, the BODIPY core became a popular scaffold for designing photo-removable protecting groups (PPG). In this paper, we report the synthesis of a new mole-cule—8‐[4‐(2‐hydroxypropane‐2‐yl)phenyl]‐1,3,4,4,5,7‐hexamethyl‐4‐boron‐3a,4a‐diaza‐S‐indacene —by the treatment of meso‐(4‐CO2Me‐phenyl)‐BODIPY with excess of MeMgI. The product was characterized by1H,13C NMR and HRMS. The combination of BODIPY core with tertiary benzilyc alcohol might be promising for utilizing this molecule as visible light removable PPG.",
keywords = "BODIPY, Methylmagnesium iodide, Photoremovable protecting group, Tertiary alcohol",
author = "Anastasiya Zobnina and Alexander Moskalensky and Aleksey Vorob{\textquoteright}ev",
note = "Funding Information: Funding: Moskalensky A.E. and Zobnina A.O. acknowledge the Grant of President of Russian Federation for the state support of young scientists (Grant agreement 075‐15‐2021‐453, МК‐4020.2021.1.2). Vorob{\textquoteright}ev A. Yu. thanks the Ministry of Science and Higher Education of the Russian Federation for support (Project No. 0238‐2019‐0005). Publisher Copyright: {\textcopyright} 2021 by the authors. Licensee MDPI, Basel, Switzerland.",
year = "2021",
month = dec,
doi = "10.3390/M1286",
language = "English",
volume = "2021",
journal = "MolBank",
issn = "1422-8599",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "4",

}

RIS

TY - JOUR

T1 - 8‐[4‐(2‐hydroxypropane‐2‐yl)phenyl]‐1,3,4,4,5,7‐hexamethyl‐4‐ boron‐3a,4a‐diaza‐s‐indacene

AU - Zobnina, Anastasiya

AU - Moskalensky, Alexander

AU - Vorob’ev, Aleksey

N1 - Funding Information: Funding: Moskalensky A.E. and Zobnina A.O. acknowledge the Grant of President of Russian Federation for the state support of young scientists (Grant agreement 075‐15‐2021‐453, МК‐4020.2021.1.2). Vorob’ev A. Yu. thanks the Ministry of Science and Higher Education of the Russian Federation for support (Project No. 0238‐2019‐0005). Publisher Copyright: © 2021 by the authors. Licensee MDPI, Basel, Switzerland.

PY - 2021/12

Y1 - 2021/12

N2 - During recent years, the BODIPY core became a popular scaffold for designing photo-removable protecting groups (PPG). In this paper, we report the synthesis of a new mole-cule—8‐[4‐(2‐hydroxypropane‐2‐yl)phenyl]‐1,3,4,4,5,7‐hexamethyl‐4‐boron‐3a,4a‐diaza‐S‐indacene —by the treatment of meso‐(4‐CO2Me‐phenyl)‐BODIPY with excess of MeMgI. The product was characterized by1H,13C NMR and HRMS. The combination of BODIPY core with tertiary benzilyc alcohol might be promising for utilizing this molecule as visible light removable PPG.

AB - During recent years, the BODIPY core became a popular scaffold for designing photo-removable protecting groups (PPG). In this paper, we report the synthesis of a new mole-cule—8‐[4‐(2‐hydroxypropane‐2‐yl)phenyl]‐1,3,4,4,5,7‐hexamethyl‐4‐boron‐3a,4a‐diaza‐S‐indacene —by the treatment of meso‐(4‐CO2Me‐phenyl)‐BODIPY with excess of MeMgI. The product was characterized by1H,13C NMR and HRMS. The combination of BODIPY core with tertiary benzilyc alcohol might be promising for utilizing this molecule as visible light removable PPG.

KW - BODIPY

KW - Methylmagnesium iodide

KW - Photoremovable protecting group

KW - Tertiary alcohol

UR - http://www.scopus.com/inward/record.url?scp=85117348147&partnerID=8YFLogxK

U2 - 10.3390/M1286

DO - 10.3390/M1286

M3 - Article

AN - SCOPUS:85117348147

VL - 2021

JO - MolBank

JF - MolBank

SN - 1422-8599

IS - 4

M1 - M1286

ER -

ID: 34463716