Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
[6]–[9]Metacyclophanes : Synthesis, Crystal Structures, and NMR and UV Spectroscopy. / Shuvalov, Vladislav Yu; Eltsov, Ilia V.; Tumanov, Nikolay A. и др.
в: European Journal of Organic Chemistry, Том 2017, № 36, 02.10.2017, стр. 5410-5416.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - [6]–[9]Metacyclophanes
T2 - Synthesis, Crystal Structures, and NMR and UV Spectroscopy
AU - Shuvalov, Vladislav Yu
AU - Eltsov, Ilia V.
AU - Tumanov, Nikolay A.
AU - Boldyreva, Elena V.
AU - Nefedov, Andrey A.
AU - Sagitullina, Galina P.
N1 - Publisher Copyright: © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2017/10/2
Y1 - 2017/10/2
N2 - Metacyclophanes have been developed as non-planar aromatic compounds with unusual physical properties. [6]–[9]Metacyclophanes were synthesized by rearrangement of 3-nitro(perhydrocycloalka)[b]pyridinium salts, and analysis of their spectroscopic data and X-ray diffraction patterns indicates the aromaticity and flexibility of their benzene rings. The effectiveness and simplicity of the synthesis makes it possible to use them as available precursors in the synthesis of retinoids, indolophanes, and carbazolophanes.
AB - Metacyclophanes have been developed as non-planar aromatic compounds with unusual physical properties. [6]–[9]Metacyclophanes were synthesized by rearrangement of 3-nitro(perhydrocycloalka)[b]pyridinium salts, and analysis of their spectroscopic data and X-ray diffraction patterns indicates the aromaticity and flexibility of their benzene rings. The effectiveness and simplicity of the synthesis makes it possible to use them as available precursors in the synthesis of retinoids, indolophanes, and carbazolophanes.
KW - Aromaticity
KW - Cyclophanes
KW - N-Methylpyridinium salts
KW - Nitropyridines
KW - Rearrangement
UR - http://www.scopus.com/inward/record.url?scp=85030169118&partnerID=8YFLogxK
U2 - 10.1002/ejoc.201700946
DO - 10.1002/ejoc.201700946
M3 - Article
AN - SCOPUS:85030169118
VL - 2017
SP - 5410
EP - 5416
JO - European Journal of Organic Chemistry
JF - European Journal of Organic Chemistry
SN - 1434-193X
IS - 36
ER -
ID: 9032934