TY - JOUR

T1 - 2D diffusion of oxygen in Ln10Mo2O21 (Ln = Nd, Ho) oxides

AU - Sadykov, Vladislav

AU - Shlyakhtina, Anna

AU - Sadovskaya, Ekaterina

AU - Eremeev, Nikita

AU - Skazka, Valeriy

AU - Goncharov, Vladimir

PY - 2020/3

Y1 - 2020/3

N2 - Ln molybdates are promising materials for hydrogen/oxygen separation membranes. This work aims at elucidating features of oxygen transport in Ln10Mo2O21 (Ln = Nd, Ho) oxides using novel 2D diffusion models. Nd10Mo2O21 and Ho10Mo2O21 were synthesized by the mechanical activation followed by sintering in the 1600–1650 °C temperature range and characterized by XRD as a complex rhombohedral phase and fluorite one, respectively. Oxygen transport features were studied by the oxygen isotope heteroexchange with C18O2 in a flow reactor using temperature-programmed and isothermal modes. According to numerical analysis, isotope exchange in Ln10Mo2O21 cannot be described by a single diffusion coefficient, which is explained by nonuniformity of the oxygen diffusion pathways. The mathematical model including equations for a faster diffusion along grain boundaries and a slower diffusion within grain bulk (2D diffusion model) gives the best fit. The same accuracy was achieved using the model including 2D diffusion and exchange between grain bulk oxygen forms with different M-O bonds strength. The values of oxygen tracer diffusion coefficient are ~10−7–10−6 cm2/s and ~10−11–10−8 cm2/s at 700 °C along grain boundaries and within grain bulk, respectively. Hence, new 2D models were developed to describe oxygen diffusion in polycrystalline oxides. A fast oxygen diffusion demonstrated for Ln10Mo2O21 oxides makes them promising for design of hydrogen/oxygen separation membranes.

AB - Ln molybdates are promising materials for hydrogen/oxygen separation membranes. This work aims at elucidating features of oxygen transport in Ln10Mo2O21 (Ln = Nd, Ho) oxides using novel 2D diffusion models. Nd10Mo2O21 and Ho10Mo2O21 were synthesized by the mechanical activation followed by sintering in the 1600–1650 °C temperature range and characterized by XRD as a complex rhombohedral phase and fluorite one, respectively. Oxygen transport features were studied by the oxygen isotope heteroexchange with C18O2 in a flow reactor using temperature-programmed and isothermal modes. According to numerical analysis, isotope exchange in Ln10Mo2O21 cannot be described by a single diffusion coefficient, which is explained by nonuniformity of the oxygen diffusion pathways. The mathematical model including equations for a faster diffusion along grain boundaries and a slower diffusion within grain bulk (2D diffusion model) gives the best fit. The same accuracy was achieved using the model including 2D diffusion and exchange between grain bulk oxygen forms with different M-O bonds strength. The values of oxygen tracer diffusion coefficient are ~10−7–10−6 cm2/s and ~10−11–10−8 cm2/s at 700 °C along grain boundaries and within grain bulk, respectively. Hence, new 2D models were developed to describe oxygen diffusion in polycrystalline oxides. A fast oxygen diffusion demonstrated for Ln10Mo2O21 oxides makes them promising for design of hydrogen/oxygen separation membranes.

KW - 2D diffusion

KW - 6170N

KW - 6610M

KW - 6630D

KW - 8220P

KW - 8220W

KW - 8610B

KW - Isotope exchange of oxygen

KW - Ln molybdates

KW - Mathematical modeling

KW - Oxygen diffusion

KW - TRANSPORT-PROPERTIES

KW - ANOMALOUS TRANSPORT

KW - ION

KW - MODEL

KW - NONSTOICHIOMETRIC PEROVSKITES

KW - GRAIN-BOUNDARY

KW - MICROSTRUCTURE

UR - http://www.scopus.com/inward/record.url?scp=85078570565&partnerID=8YFLogxK

U2 - 10.1016/j.ssi.2020.115229

DO - 10.1016/j.ssi.2020.115229

M3 - Article

AN - SCOPUS:85078570565

VL - 346

JO - Solid State Ionics

JF - Solid State Ionics

SN - 0167-2738

M1 - 115229

ER -