Standard

1D, 2D and 3D networks based on group 11 metal ions and (pyrazin-2-ylmethyl)phosphines: synthesis, metallophilic interactions and emission properties. / Artem'ev, Alexander V.; Sadykov, Evgeniy H.; Shilo, Stepan S. и др.

в: Inorganica Chimica Acta, Том 564, 121964, 01.05.2024.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

Artem'ev, AV, Sadykov, EH, Shilo, SS, Yu. Baranov, A, Rakhmanova, MI, Novikov, AS, Samsonenko, DG & Yu. Bagryanskaya, I 2024, '1D, 2D and 3D networks based on group 11 metal ions and (pyrazin-2-ylmethyl)phosphines: synthesis, metallophilic interactions and emission properties', Inorganica Chimica Acta, Том. 564, 121964. https://doi.org/10.1016/j.ica.2024.121964

APA

Artem'ev, A. V., Sadykov, E. H., Shilo, S. S., Yu. Baranov, A., Rakhmanova, M. I., Novikov, A. S., Samsonenko, D. G., & Yu. Bagryanskaya, I. (2024). 1D, 2D and 3D networks based on group 11 metal ions and (pyrazin-2-ylmethyl)phosphines: synthesis, metallophilic interactions and emission properties. Inorganica Chimica Acta, 564, [121964]. https://doi.org/10.1016/j.ica.2024.121964

Vancouver

Artem'ev AV, Sadykov EH, Shilo SS, Yu. Baranov A, Rakhmanova MI, Novikov AS и др. 1D, 2D and 3D networks based on group 11 metal ions and (pyrazin-2-ylmethyl)phosphines: synthesis, metallophilic interactions and emission properties. Inorganica Chimica Acta. 2024 май 1;564:121964. doi: 10.1016/j.ica.2024.121964

Author

Artem'ev, Alexander V. ; Sadykov, Evgeniy H. ; Shilo, Stepan S. и др. / 1D, 2D and 3D networks based on group 11 metal ions and (pyrazin-2-ylmethyl)phosphines: synthesis, metallophilic interactions and emission properties. в: Inorganica Chimica Acta. 2024 ; Том 564.

BibTeX

@article{1c6be3ef42b349bb89b7beed16248aaf,
title = "1D, 2D and 3D networks based on group 11 metal ions and (pyrazin-2-ylmethyl)phosphines: synthesis, metallophilic interactions and emission properties",
abstract = "An original series of 1D, 2D and 3D networks based on group 11 metal ions was synthesized using tris(pyrazin-2-ylmethyl)phosphine (L1) and bis(pyrazin-2-ylmethyl)phenylphosphine (L2). The reaction of L1 with CuI results in either 1D chains [Cu2I2(L1)2]n or 2D networks [Cu2I2(L1)]n, while the treatment of L1 and L2 with [Ag(MeCN)4]PF6 in aqueous MeCN produces 3D cationic frameworks [Ag(L1)]n(PF6)n and [Ag(L2)(H2O)]n(PF6)n, respectively. Finally, 1D polymer [Ag3Au(L1)2(MeCN)3]n(BF4)4n containing {AuAg2} cluster units was assembled from phosphine L1, Au(tht)Cl and AgBF4. QTAIM analysis of [Cu2I2(L1)]n and [Ag3Au(L1)2(MeCN)3]n(BF4)4n polymers revealed the presence of pronounced metallophilic Cu∙∙∙Cu and Au∙∙∙Ag interactions. Moreover, the CuI-based networks exhibited a yellow and red emission, which was tentatively attributed to thermally activated delayed fluorescence (TADF) of (M+X)LCT type.",
keywords = "Copper(I), Metal-organic frameworks, Metallophilic interactions, Pyrazine-based phosphines, Silver(I), Thermally activated delayed fluorescence",
author = "Artem'ev, {Alexander V.} and Sadykov, {Evgeniy H.} and Shilo, {Stepan S.} and {Yu. Baranov}, Andrey and Rakhmanova, {Mariana I.} and Novikov, {Alexander S.} and Samsonenko, {Denis G.} and {Yu. Bagryanskaya}, Irina",
note = "This work was supported by Russian Science Foundation (Project № 21-73-10110 ).",
year = "2024",
month = may,
day = "1",
doi = "10.1016/j.ica.2024.121964",
language = "English",
volume = "564",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - 1D, 2D and 3D networks based on group 11 metal ions and (pyrazin-2-ylmethyl)phosphines: synthesis, metallophilic interactions and emission properties

AU - Artem'ev, Alexander V.

AU - Sadykov, Evgeniy H.

AU - Shilo, Stepan S.

AU - Yu. Baranov, Andrey

AU - Rakhmanova, Mariana I.

AU - Novikov, Alexander S.

AU - Samsonenko, Denis G.

AU - Yu. Bagryanskaya, Irina

N1 - This work was supported by Russian Science Foundation (Project № 21-73-10110 ).

PY - 2024/5/1

Y1 - 2024/5/1

N2 - An original series of 1D, 2D and 3D networks based on group 11 metal ions was synthesized using tris(pyrazin-2-ylmethyl)phosphine (L1) and bis(pyrazin-2-ylmethyl)phenylphosphine (L2). The reaction of L1 with CuI results in either 1D chains [Cu2I2(L1)2]n or 2D networks [Cu2I2(L1)]n, while the treatment of L1 and L2 with [Ag(MeCN)4]PF6 in aqueous MeCN produces 3D cationic frameworks [Ag(L1)]n(PF6)n and [Ag(L2)(H2O)]n(PF6)n, respectively. Finally, 1D polymer [Ag3Au(L1)2(MeCN)3]n(BF4)4n containing {AuAg2} cluster units was assembled from phosphine L1, Au(tht)Cl and AgBF4. QTAIM analysis of [Cu2I2(L1)]n and [Ag3Au(L1)2(MeCN)3]n(BF4)4n polymers revealed the presence of pronounced metallophilic Cu∙∙∙Cu and Au∙∙∙Ag interactions. Moreover, the CuI-based networks exhibited a yellow and red emission, which was tentatively attributed to thermally activated delayed fluorescence (TADF) of (M+X)LCT type.

AB - An original series of 1D, 2D and 3D networks based on group 11 metal ions was synthesized using tris(pyrazin-2-ylmethyl)phosphine (L1) and bis(pyrazin-2-ylmethyl)phenylphosphine (L2). The reaction of L1 with CuI results in either 1D chains [Cu2I2(L1)2]n or 2D networks [Cu2I2(L1)]n, while the treatment of L1 and L2 with [Ag(MeCN)4]PF6 in aqueous MeCN produces 3D cationic frameworks [Ag(L1)]n(PF6)n and [Ag(L2)(H2O)]n(PF6)n, respectively. Finally, 1D polymer [Ag3Au(L1)2(MeCN)3]n(BF4)4n containing {AuAg2} cluster units was assembled from phosphine L1, Au(tht)Cl and AgBF4. QTAIM analysis of [Cu2I2(L1)]n and [Ag3Au(L1)2(MeCN)3]n(BF4)4n polymers revealed the presence of pronounced metallophilic Cu∙∙∙Cu and Au∙∙∙Ag interactions. Moreover, the CuI-based networks exhibited a yellow and red emission, which was tentatively attributed to thermally activated delayed fluorescence (TADF) of (M+X)LCT type.

KW - Copper(I)

KW - Metal-organic frameworks

KW - Metallophilic interactions

KW - Pyrazine-based phosphines

KW - Silver(I)

KW - Thermally activated delayed fluorescence

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85185315530&origin=inward&txGid=7adde128c967fc476d882f6904e2adc2

UR - https://www.mendeley.com/catalogue/6600cc4d-5f03-36ca-af35-656b6b6de33d/

U2 - 10.1016/j.ica.2024.121964

DO - 10.1016/j.ica.2024.121964

M3 - Article

VL - 564

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

M1 - 121964

ER -

ID: 61051961