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1,3-dipolar cycloaddition of a nitronyl nitroxide-substituted alkyne to heteroaromatic n-imines. / Romanov, Vasiliy; Vorob'ev, Aleksey; Bagryanskaya, Irina и др.

в: Australian Journal of Chemistry, Том 70, № 12, 01.01.2017, стр. 1317-1320.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Romanov, V, Vorob'ev, A, Bagryanskaya, I, Parkhomenko, D & Tretyakov, E 2017, '1,3-dipolar cycloaddition of a nitronyl nitroxide-substituted alkyne to heteroaromatic n-imines', Australian Journal of Chemistry, Том. 70, № 12, стр. 1317-1320. https://doi.org/10.1071/CH17476

APA

Romanov, V., Vorob'ev, A., Bagryanskaya, I., Parkhomenko, D., & Tretyakov, E. (2017). 1,3-dipolar cycloaddition of a nitronyl nitroxide-substituted alkyne to heteroaromatic n-imines. Australian Journal of Chemistry, 70(12), 1317-1320. https://doi.org/10.1071/CH17476

Vancouver

Romanov V, Vorob'ev A, Bagryanskaya I, Parkhomenko D, Tretyakov E. 1,3-dipolar cycloaddition of a nitronyl nitroxide-substituted alkyne to heteroaromatic n-imines. Australian Journal of Chemistry. 2017 янв. 1;70(12):1317-1320. doi: 10.1071/CH17476

Author

Romanov, Vasiliy ; Vorob'ev, Aleksey ; Bagryanskaya, Irina и др. / 1,3-dipolar cycloaddition of a nitronyl nitroxide-substituted alkyne to heteroaromatic n-imines. в: Australian Journal of Chemistry. 2017 ; Том 70, № 12. стр. 1317-1320.

BibTeX

@article{b683e9a0236c466e89071eaa46ed9373,
title = "1,3-dipolar cycloaddition of a nitronyl nitroxide-substituted alkyne to heteroaromatic n-imines",
abstract = "1,3-Dipolar cycloaddition of the triple bond in an ethynyl-substituted nitronyl nitroxide to heteroaromatic N-imines is described. The reaction opens a pathway to polyfunctional nitronyl nitroxides with pyrazolo[1,5-a]pyridine or related substituents. According to X-ray diffraction analysis, dihedral angles between the plane of the paramagnetic moiety and heteroaromatic cycle do not exceed 24°. Reactions between Cu(hfac)2 (hfac≤hexafluoroacetylacetonate ion) and a pyrazolo[1,5-a]pyridine-substituted radical produced a polymer chain complex with a 'head-to-tail' motif resembling that in breathing crystals.",
keywords = "MAGNETOSTRUCTURAL ANOMALIES, MOLECULAR MAGNET, CU(HFAC)(2), BIRADICALS, CHEMISTRY, RADICALS, COMPLEX",
author = "Vasiliy Romanov and Aleksey Vorob'ev and Irina Bagryanskaya and Dmitriy Parkhomenko and Evgeny Tretyakov",
year = "2017",
month = jan,
day = "1",
doi = "10.1071/CH17476",
language = "English",
volume = "70",
pages = "1317--1320",
journal = "Australian Journal of Chemistry",
issn = "0004-9425",
publisher = "CSIRO",
number = "12",

}

RIS

TY - JOUR

T1 - 1,3-dipolar cycloaddition of a nitronyl nitroxide-substituted alkyne to heteroaromatic n-imines

AU - Romanov, Vasiliy

AU - Vorob'ev, Aleksey

AU - Bagryanskaya, Irina

AU - Parkhomenko, Dmitriy

AU - Tretyakov, Evgeny

PY - 2017/1/1

Y1 - 2017/1/1

N2 - 1,3-Dipolar cycloaddition of the triple bond in an ethynyl-substituted nitronyl nitroxide to heteroaromatic N-imines is described. The reaction opens a pathway to polyfunctional nitronyl nitroxides with pyrazolo[1,5-a]pyridine or related substituents. According to X-ray diffraction analysis, dihedral angles between the plane of the paramagnetic moiety and heteroaromatic cycle do not exceed 24°. Reactions between Cu(hfac)2 (hfac≤hexafluoroacetylacetonate ion) and a pyrazolo[1,5-a]pyridine-substituted radical produced a polymer chain complex with a 'head-to-tail' motif resembling that in breathing crystals.

AB - 1,3-Dipolar cycloaddition of the triple bond in an ethynyl-substituted nitronyl nitroxide to heteroaromatic N-imines is described. The reaction opens a pathway to polyfunctional nitronyl nitroxides with pyrazolo[1,5-a]pyridine or related substituents. According to X-ray diffraction analysis, dihedral angles between the plane of the paramagnetic moiety and heteroaromatic cycle do not exceed 24°. Reactions between Cu(hfac)2 (hfac≤hexafluoroacetylacetonate ion) and a pyrazolo[1,5-a]pyridine-substituted radical produced a polymer chain complex with a 'head-to-tail' motif resembling that in breathing crystals.

KW - MAGNETOSTRUCTURAL ANOMALIES

KW - MOLECULAR MAGNET

KW - CU(HFAC)(2)

KW - BIRADICALS

KW - CHEMISTRY

KW - RADICALS

KW - COMPLEX

UR - http://www.scopus.com/inward/record.url?scp=85034788365&partnerID=8YFLogxK

U2 - 10.1071/CH17476

DO - 10.1071/CH17476

M3 - Article

AN - SCOPUS:85034788365

VL - 70

SP - 1317

EP - 1320

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

SN - 0004-9425

IS - 12

ER -

ID: 10347184