Результаты исследований: Научные публикации в периодических изданиях › письмо/краткое сообщение › Рецензирование
1,3-Bis(1,2,4-triazol-1-yl)adamantane. / Marchenko, Roman; Potapov, Andrei.
в: MolBank, Том 2017, № 4, M968, 12.12.2017.Результаты исследований: Научные публикации в периодических изданиях › письмо/краткое сообщение › Рецензирование
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TY - JOUR
T1 - 1,3-Bis(1,2,4-triazol-1-yl)adamantane
AU - Marchenko, Roman
AU - Potapov, Andrei
PY - 2017/12/12
Y1 - 2017/12/12
N2 - Functional adamantane derivatives are interesting as active pharmaceutical ingredients, building blocks for supramolecular ensembles, and ligands in light of the coordination chemistry of functional materials. In this communication, synthesis of two isomeric 1,3-bis(1,2,4- triazolyl)adamantanes by the reaction of 1,3-dibromoadamantane with 1,2,4-triazole in the absence of solvent is reported. The products, namely 1,3-bis(1,2,4-triazol-1-yl)adamantane and 1-(1,2,4-triazol- 1-yl)-3-(1,2,4-triazol-4-yl)adamantane were separated by column chromatography and identified by NMR and mass-spectrometry.
AB - Functional adamantane derivatives are interesting as active pharmaceutical ingredients, building blocks for supramolecular ensembles, and ligands in light of the coordination chemistry of functional materials. In this communication, synthesis of two isomeric 1,3-bis(1,2,4- triazolyl)adamantanes by the reaction of 1,3-dibromoadamantane with 1,2,4-triazole in the absence of solvent is reported. The products, namely 1,3-bis(1,2,4-triazol-1-yl)adamantane and 1-(1,2,4-triazol- 1-yl)-3-(1,2,4-triazol-4-yl)adamantane were separated by column chromatography and identified by NMR and mass-spectrometry.
KW - 1,2,4-triazole
KW - Adamantane
KW - Adamantylation
KW - Alkylation
KW - Bitopic ligand
KW - Substitution reaction
KW - 1-(1-ADAMANTYL)PYRAZOLES
KW - COMPLEXES
KW - DIAMONDOIDS
KW - adamantane
KW - TECTONS
KW - FUNCTIONALIZED ADAMANTANES
KW - alkylation
KW - ANTIVIRAL ACTIVITY
KW - bitopic ligand
KW - REVERSAL AGENTS
KW - LIGAND
KW - adamantylation
KW - COORDINATION POLYMERS
KW - substitution reaction
KW - DERIVATIVES
UR - http://www.scopus.com/inward/record.url?scp=85040053501&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/592391e3-e732-3c7c-874f-e6c57ad8e002/
U2 - 10.3390/M968
DO - 10.3390/M968
M3 - Letter
AN - SCOPUS:85040053501
VL - 2017
JO - MolBank
JF - MolBank
SN - 1422-8599
IS - 4
M1 - M968
ER -
ID: 25397825