Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
0D to 3D Coordination Assemblies Engineered on Silver(I) Salts and 2-(Alkylsulfanyl)azine Ligands : Crystal Structures, Dual Luminescence, and Cytotoxic Activity. / Rogovoy, Maxim I.; Frolova, Tatiana S.; Samsonenko, Denis G. и др.
в: European Journal of Inorganic Chemistry, Том 2020, № 17, 10.05.2020, стр. 1635-1644.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - 0D to 3D Coordination Assemblies Engineered on Silver(I) Salts and 2-(Alkylsulfanyl)azine Ligands
T2 - Crystal Structures, Dual Luminescence, and Cytotoxic Activity
AU - Rogovoy, Maxim I.
AU - Frolova, Tatiana S.
AU - Samsonenko, Denis G.
AU - Berezin, Alexey S.
AU - Bagryanskaya, Irina Yu
AU - Nedolya, Nina A.
AU - Tarasova, Olga A.
AU - Fedin, Vladimir P.
AU - Artem'ev, Alexander V.
N1 - Publisher Copyright: © 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2020/5/10
Y1 - 2020/5/10
N2 - The potential of 2-(alkylsulfanyl)azine ligands for crystal engineering of functional Ag(I) complexes has been firstly demonstrated. The reaction of AgNO3, AgClO4 and AgOTf with 2-(alkylsulfanyl)pyridines, -pyrimidines, and -quinolines gives a series of new Ag(I) compounds that range from mono- and dinuclear complexes to chain (1D), layered (2D) and framework (3D) coordination polymers (CPs). 2-(Alkylsulfanyl)pyridines and -pyrimidines, depending on the reaction conditions, are assembled either into molecular complexes or CPs, while 2-(alkylsulfanyl)quinolines afford dinuclear complexes exclusively. The most of compounds engineered feature site-specific interactions such as Ag···Ag, Ag···O, and Ag···S ones. The 2-(methylsulfanyl)quinoline (2-MeSQn) complex, [Ag2(2-MeSQn)2(NO3)2], displays room temperature intraligand (IL) phosphorescence, while the 2-(methylsulfanyl)pyridine-derived CPs emit dual luminescence expressed by IL fluorescence and phosphorescence. Moreover, cytotoxic activity of the compounds synthesized has been evaluated against hTERT lung fibroblasts, HeLa, MCF7, HepG2 and A549 cancer cells.
AB - The potential of 2-(alkylsulfanyl)azine ligands for crystal engineering of functional Ag(I) complexes has been firstly demonstrated. The reaction of AgNO3, AgClO4 and AgOTf with 2-(alkylsulfanyl)pyridines, -pyrimidines, and -quinolines gives a series of new Ag(I) compounds that range from mono- and dinuclear complexes to chain (1D), layered (2D) and framework (3D) coordination polymers (CPs). 2-(Alkylsulfanyl)pyridines and -pyrimidines, depending on the reaction conditions, are assembled either into molecular complexes or CPs, while 2-(alkylsulfanyl)quinolines afford dinuclear complexes exclusively. The most of compounds engineered feature site-specific interactions such as Ag···Ag, Ag···O, and Ag···S ones. The 2-(methylsulfanyl)quinoline (2-MeSQn) complex, [Ag2(2-MeSQn)2(NO3)2], displays room temperature intraligand (IL) phosphorescence, while the 2-(methylsulfanyl)pyridine-derived CPs emit dual luminescence expressed by IL fluorescence and phosphorescence. Moreover, cytotoxic activity of the compounds synthesized has been evaluated against hTERT lung fibroblasts, HeLa, MCF7, HepG2 and A549 cancer cells.
KW - Coordination polymers
KW - Cytotoxicity
KW - Dual luminescence
KW - Silver
KW - Sulfide ligands
KW - POLYMERS
KW - DESIGN
KW - ACID
KW - PHOTOLUMINESCENCE
KW - COMPLEXES
KW - PYRIMIDINE
KW - BEARING
KW - ARCHITECTURES
UR - http://www.scopus.com/inward/record.url?scp=85083663579&partnerID=8YFLogxK
U2 - 10.1002/ejic.202000109
DO - 10.1002/ejic.202000109
M3 - Article
AN - SCOPUS:85083663579
VL - 2020
SP - 1635
EP - 1644
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
SN - 1434-1948
IS - 17
ER -
ID: 24076856