Standard

Zn(II), Cd(II), and Pd(II) Complexes with a 1,10-Phenanthroline Derivative Bearing Diisopropylidene Glucose: Synthesis, Structure, Properties. / Kokina, T. E.; Agafontsev, A. M.; Sizintseva, K. D. et al.

In: Journal of Structural Chemistry, Vol. 64, No. 12, 12.2023, p. 2311-2325.

Research output: Contribution to journal › Article › peer-review

Harvard

Kokina, TE, Agafontsev, AM, Sizintseva, KD, Komarov, VY, Rakhmanova, MI, Golubeva, YA & Klyushova, LS 2023, 'Zn(II), Cd(II), and Pd(II) Complexes with a 1,10-Phenanthroline Derivative Bearing Diisopropylidene Glucose: Synthesis, Structure, Properties', Journal of Structural Chemistry, vol. 64, no. 12, pp. 2311-2325. https://doi.org/10.1134/s002247662312003x

APA

Kokina, T. E., Agafontsev, A. M., Sizintseva, K. D., Komarov, V. Y., Rakhmanova, M. I., Golubeva, Y. A., & Klyushova, L. S. (2023). Zn(II), Cd(II), and Pd(II) Complexes with a 1,10-Phenanthroline Derivative Bearing Diisopropylidene Glucose: Synthesis, Structure, Properties. Journal of Structural Chemistry, 64(12), 2311-2325. https://doi.org/10.1134/s002247662312003x

Vancouver

Kokina TE, Agafontsev AM, Sizintseva KD, Komarov VY, Rakhmanova MI, Golubeva YA et al. Zn(II), Cd(II), and Pd(II) Complexes with a 1,10-Phenanthroline Derivative Bearing Diisopropylidene Glucose: Synthesis, Structure, Properties. Journal of Structural Chemistry. 2023 Dec;64(12):2311-2325. doi: 10.1134/s002247662312003x

Author

Kokina, T. E. ; Agafontsev, A. M. ; Sizintseva, K. D. et al. / Zn(II), Cd(II), and Pd(II) Complexes with a 1,10-Phenanthroline Derivative Bearing Diisopropylidene Glucose: Synthesis, Structure, Properties. In: Journal of Structural Chemistry. 2023 ; Vol. 64, No. 12. pp. 2311-2325.

BibTeX

@article{876b980849dd4eeeb9ff3e709fcc24cd,
title = "Zn(II), Cd(II), and Pd(II) Complexes with a 1,10-Phenanthroline Derivative Bearing Diisopropylidene Glucose: Synthesis, Structure, Properties",
abstract = "Complexes [Cd4L4Cl8]·2H2O (I), ZnLCl2 (II), and PdLCl2·CH2Cl2 (III) (L = chiral derivative of 1,10-phenanthroline bearing diisopropylidene glucose) are synthesized. Single crystals of [Cd4L4Cl8] (IV) are prepared. According to the XRD data, the crystal structure of IV consists of molecules of the tetranuclear complex; the coordination number of two terminal and two central Cd2+ ions is 5 (Cl2N3) and 6 (Cl4N2), respectively. In the structure of IV, the L ligand is a bidentate cyclic ligand; Cl atoms exhibit both bridging and monodentate ligand functions. Complexes I–III are characterized by powder XRD and IR spectroscopy. According to the powder XRD data, I is isostructural to IV. Photophysical properties of solid samples of L, I, II are studied. Compound L exhibits excitation-wavelength dependent emission, the excited state lifetimes varying within nano- and microsecond regions. Complexes I and II exhibit ligand-centered photoluminescence. The luminescence quantum yields are as high as 15%. Cytotoxic properties of L, cadmium chloride, and I–III solutions are studied on the human laryngeal carcinoma cell line Hep2.",
author = "Kokina, {T. E.} and Agafontsev, {A. M.} and Sizintseva, {K. D.} and Komarov, {V. Y.} and Rakhmanova, {M. I.} and Golubeva, {Y. A.} and Klyushova, {L. S.}",
note = "This work was funded by the Ministry of Science and Higher Education of the Russian Federation. The studies were conducted within the State Assignment for N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences and Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences (No. 121031700321-3). This work was conducted using the equipment of the Center for Collective Use “Proteomic Analysis” funded by the Ministry of Science and Higher Education of the Russian Federation (agreement No. 075-15-2021-691) and the equipment of the Core Facilities Shared Research Facilities {"}High Technologies and Analytics of Nanosystems{"}, Novosibirsk State University. Публикация для корректировки.",
year = "2023",
month = dec,
doi = "10.1134/s002247662312003x",
language = "English",
volume = "64",
pages = "2311--2325",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "12",

}

RIS

TY - JOUR

T1 - Zn(II), Cd(II), and Pd(II) Complexes with a 1,10-Phenanthroline Derivative Bearing Diisopropylidene Glucose: Synthesis, Structure, Properties

AU - Kokina, T. E.

AU - Agafontsev, A. M.

AU - Sizintseva, K. D.

AU - Komarov, V. Y.

AU - Rakhmanova, M. I.

AU - Golubeva, Y. A.

AU - Klyushova, L. S.

N1 - This work was funded by the Ministry of Science and Higher Education of the Russian Federation. The studies were conducted within the State Assignment for N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences and Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences (No. 121031700321-3). This work was conducted using the equipment of the Center for Collective Use “Proteomic Analysis” funded by the Ministry of Science and Higher Education of the Russian Federation (agreement No. 075-15-2021-691) and the equipment of the Core Facilities Shared Research Facilities "High Technologies and Analytics of Nanosystems", Novosibirsk State University. Публикация для корректировки.

PY - 2023/12

Y1 - 2023/12

N2 - Complexes [Cd4L4Cl8]·2H2O (I), ZnLCl2 (II), and PdLCl2·CH2Cl2 (III) (L = chiral derivative of 1,10-phenanthroline bearing diisopropylidene glucose) are synthesized. Single crystals of [Cd4L4Cl8] (IV) are prepared. According to the XRD data, the crystal structure of IV consists of molecules of the tetranuclear complex; the coordination number of two terminal and two central Cd2+ ions is 5 (Cl2N3) and 6 (Cl4N2), respectively. In the structure of IV, the L ligand is a bidentate cyclic ligand; Cl atoms exhibit both bridging and monodentate ligand functions. Complexes I–III are characterized by powder XRD and IR spectroscopy. According to the powder XRD data, I is isostructural to IV. Photophysical properties of solid samples of L, I, II are studied. Compound L exhibits excitation-wavelength dependent emission, the excited state lifetimes varying within nano- and microsecond regions. Complexes I and II exhibit ligand-centered photoluminescence. The luminescence quantum yields are as high as 15%. Cytotoxic properties of L, cadmium chloride, and I–III solutions are studied on the human laryngeal carcinoma cell line Hep2.

AB - Complexes [Cd4L4Cl8]·2H2O (I), ZnLCl2 (II), and PdLCl2·CH2Cl2 (III) (L = chiral derivative of 1,10-phenanthroline bearing diisopropylidene glucose) are synthesized. Single crystals of [Cd4L4Cl8] (IV) are prepared. According to the XRD data, the crystal structure of IV consists of molecules of the tetranuclear complex; the coordination number of two terminal and two central Cd2+ ions is 5 (Cl2N3) and 6 (Cl4N2), respectively. In the structure of IV, the L ligand is a bidentate cyclic ligand; Cl atoms exhibit both bridging and monodentate ligand functions. Complexes I–III are characterized by powder XRD and IR spectroscopy. According to the powder XRD data, I is isostructural to IV. Photophysical properties of solid samples of L, I, II are studied. Compound L exhibits excitation-wavelength dependent emission, the excited state lifetimes varying within nano- and microsecond regions. Complexes I and II exhibit ligand-centered photoluminescence. The luminescence quantum yields are as high as 15%. Cytotoxic properties of L, cadmium chloride, and I–III solutions are studied on the human laryngeal carcinoma cell line Hep2.

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85180876500&origin=inward&txGid=fdc4aab46ef881ffdf8c5f37459d8e29

UR - https://www.mendeley.com/catalogue/6aace55a-4204-3362-a9f1-2a55af8de33d/

U2 - 10.1134/s002247662312003x

DO - 10.1134/s002247662312003x

M3 - Article

VL - 64

SP - 2311

EP - 2325

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 12

ER -

ID: 59544061