Research output: Contribution to journal › Article › peer-review
X-ray photoelectron and X-ray emission study of the electronic structure of hexanuclear Mn(II,III) pivalate complexes. / Fedorenko, A. D.; Mazalov, L. N.; Fursova, E. Yu et al.
In: Journal of Structural Chemistry, Vol. 58, No. 6, 01.11.2017, p. 1166-1172.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - X-ray photoelectron and X-ray emission study of the electronic structure of hexanuclear Mn(II,III) pivalate complexes
AU - Fedorenko, A. D.
AU - Mazalov, L. N.
AU - Fursova, E. Yu
AU - Ovcharenko, V. I.
AU - Kalinkin, A. V.
AU - Lavrukhina, S. A.
PY - 2017/11/1
Y1 - 2017/11/1
N2 - The electronic structure of hexanuclear Mn(II,III) pivalate complexes with tetrahydrofuran and isonicotinamide are studied by X-ray photoelectron spectroscopy and X-ray emission spectroscopy. It is shown that when isonicotinamide substitutes for tetrahydrofuran the spin state of manganese ions is retained; the electron density increases on the manganese and oxygen atoms of the [Mn6(O)2Piv10] core.
AB - The electronic structure of hexanuclear Mn(II,III) pivalate complexes with tetrahydrofuran and isonicotinamide are studied by X-ray photoelectron spectroscopy and X-ray emission spectroscopy. It is shown that when isonicotinamide substitutes for tetrahydrofuran the spin state of manganese ions is retained; the electron density increases on the manganese and oxygen atoms of the [Mn6(O)2Piv10] core.
KW - manganese pivalate with isonicotinamide
KW - XES
KW - XPS
UR - http://www.scopus.com/inward/record.url?scp=85036582913&partnerID=8YFLogxK
U2 - 10.1134/S0022476617060142
DO - 10.1134/S0022476617060142
M3 - Article
AN - SCOPUS:85036582913
VL - 58
SP - 1166
EP - 1172
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 6
ER -
ID: 9648654