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Why non-heme Mn complexes of amino 2-quinolylmethyl ligands are inactive in oxidation catalysis? An insight from X-ray data. / Ottenbacher, Roman V.; Medvedev, Alexander G.; Nefedov, Andrey A. et al.

In: Inorganic Chemistry Communications, Vol. 156, 111282, 10.2023.

Research output: Contribution to journal › Article › peer-review

Harvard

Ottenbacher, RV, Medvedev, AG, Nefedov, AA & Bryliakov, KP 2023, 'Why non-heme Mn complexes of amino 2-quinolylmethyl ligands are inactive in oxidation catalysis? An insight from X-ray data', Inorganic Chemistry Communications, vol. 156, 111282. https://doi.org/10.1016/j.inoche.2023.111282

APA

Ottenbacher, R. V., Medvedev, A. G., Nefedov, A. A., & Bryliakov, K. P. (2023). Why non-heme Mn complexes of amino 2-quinolylmethyl ligands are inactive in oxidation catalysis? An insight from X-ray data. Inorganic Chemistry Communications, 156, [111282]. https://doi.org/10.1016/j.inoche.2023.111282

Vancouver

Ottenbacher RV, Medvedev AG, Nefedov AA, Bryliakov KP. Why non-heme Mn complexes of amino 2-quinolylmethyl ligands are inactive in oxidation catalysis? An insight from X-ray data. Inorganic Chemistry Communications. 2023 Oct;156:111282. doi: 10.1016/j.inoche.2023.111282

Author

Ottenbacher, Roman V. ; Medvedev, Alexander G. ; Nefedov, Andrey A. et al. / Why non-heme Mn complexes of amino 2-quinolylmethyl ligands are inactive in oxidation catalysis? An insight from X-ray data. In: Inorganic Chemistry Communications. 2023 ; Vol. 156.

BibTeX

@article{af40e1161a604ef3af2543c2023f54a9,
title = "Why non-heme Mn complexes of amino 2-quinolylmethyl ligands are inactive in oxidation catalysis? An insight from X-ray data",
abstract = "In the last decade, manganese complexes with bis-amino-bis-pyridylmethyl and structurally related N4 donor ligands have emerged as efficient catalysts of selective epoxidations and C–H oxidations of organic substrates with H2O2. Although a plethora of various ligand structures have been designed, (quinolin-2-yl)methyl moieties have not been involved in constructing such catalysts. Herewith we report crystal structures of several Mn complexes with (quinolin-2-yl)methyl and discuss possible reasons of their inactivity in oxidation catalysis.",
keywords = "Biomimetic chemistry, C–H activation, Hydroxylation, Manganese, Oxidation",
author = "Ottenbacher, {Roman V.} and Medvedev, {Alexander G.} and Nefedov, {Andrey A.} and Bryliakov, {Konstantin P.}",
note = "KPB thanks the Russian Science Foundation (grant 20-13-00032) for financial support. The X-ray diffraction study was performed using the equipment of the JRC PMR IGIC RAS, and the HR-MS study was performed using the equipment of Vorozhtsov Institute of Organic Chemistry RAS (#1021051503141-0-1.4.1).",
year = "2023",
month = oct,
doi = "10.1016/j.inoche.2023.111282",
language = "English",
volume = "156",
journal = "Inorganic Chemistry Communication",
issn = "1387-7003",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Why non-heme Mn complexes of amino 2-quinolylmethyl ligands are inactive in oxidation catalysis? An insight from X-ray data

AU - Ottenbacher, Roman V.

AU - Medvedev, Alexander G.

AU - Nefedov, Andrey A.

AU - Bryliakov, Konstantin P.

N1 - KPB thanks the Russian Science Foundation (grant 20-13-00032) for financial support. The X-ray diffraction study was performed using the equipment of the JRC PMR IGIC RAS, and the HR-MS study was performed using the equipment of Vorozhtsov Institute of Organic Chemistry RAS (#1021051503141-0-1.4.1).

PY - 2023/10

Y1 - 2023/10

N2 - In the last decade, manganese complexes with bis-amino-bis-pyridylmethyl and structurally related N4 donor ligands have emerged as efficient catalysts of selective epoxidations and C–H oxidations of organic substrates with H2O2. Although a plethora of various ligand structures have been designed, (quinolin-2-yl)methyl moieties have not been involved in constructing such catalysts. Herewith we report crystal structures of several Mn complexes with (quinolin-2-yl)methyl and discuss possible reasons of their inactivity in oxidation catalysis.

AB - In the last decade, manganese complexes with bis-amino-bis-pyridylmethyl and structurally related N4 donor ligands have emerged as efficient catalysts of selective epoxidations and C–H oxidations of organic substrates with H2O2. Although a plethora of various ligand structures have been designed, (quinolin-2-yl)methyl moieties have not been involved in constructing such catalysts. Herewith we report crystal structures of several Mn complexes with (quinolin-2-yl)methyl and discuss possible reasons of their inactivity in oxidation catalysis.

KW - Biomimetic chemistry

KW - C–H activation

KW - Hydroxylation

KW - Manganese

KW - Oxidation

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85169014620&origin=inward&txGid=ec8160bf3e55cf6141238b83cb72e6a6

UR - https://www.mendeley.com/catalogue/cca0a60c-e07f-3e0a-98cc-9a9013499a56/

U2 - 10.1016/j.inoche.2023.111282

DO - 10.1016/j.inoche.2023.111282

M3 - Article

VL - 156

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

M1 - 111282

ER -

ID: 55497556