Standard

Water-Gas shift reaction over Ni/CeO2 catalysts. / Bobrova, Ludmilla; Andreev, Dmitry; Ivanov, Eugene et al.

In: Catalysts, Vol. 7, No. 10, 310, 01.10.2017.

Research output: Contribution to journal › Article › peer-review

Harvard

Bobrova, L, Andreev, D, Ivanov, E, Mezentseva, N, Simonov, M, Makarshin, L, Gribovskii, A & Sadykov, V 2017, 'Water-Gas shift reaction over Ni/CeO2 catalysts', Catalysts, vol. 7, no. 10, 310. https://doi.org/10.3390/catal7100310

APA

Bobrova, L., Andreev, D., Ivanov, E., Mezentseva, N., Simonov, M., Makarshin, L., Gribovskii, A., & Sadykov, V. (2017). Water-Gas shift reaction over Ni/CeO2 catalysts. Catalysts, 7(10), [310]. https://doi.org/10.3390/catal7100310

Vancouver

Bobrova L, Andreev D, Ivanov E, Mezentseva N, Simonov M, Makarshin L et al. Water-Gas shift reaction over Ni/CeO2 catalysts. Catalysts. 2017 Oct 1;7(10):310. doi: 10.3390/catal7100310

Author

Bobrova, Ludmilla ; Andreev, Dmitry ; Ivanov, Eugene et al. / Water-Gas shift reaction over Ni/CeO2 catalysts. In: Catalysts. 2017 ; Vol. 7, No. 10.

BibTeX

@article{d441679fe9bb409b958c72087feec0c9,
title = "Water-Gas shift reaction over Ni/CeO2 catalysts",
abstract = "This paper reports the results of a study of a water-gas shift reaction over nickel-ceria catalysts with different metal loading. Within this study, the overall CO conversion and observed kinetic behavior were investigated over the temperature range of 250-550 °C in different reactor configurations (fixed-bed and microchannel reactors). The quasi-steady state kinetics of the CO water-gas shift reaction was studied for fractions of Ni-containing cerium oxide catalysts in fixed-bed experiments at lab-scale level using a very dilute gas (1% CO + 1.8% H2O in Не). A set of experiments with a microchannel reactor was performed using the feed composition (CO:H2O:H2:N2 = 1:2:2:2), representing a product gas from methane partial oxidation. The results were interpreted using computational models. The kinetic parameters were determined by regression analysis, while mechanistic aspects were considered only briefly. Simulation of the WGS reaction in the microreactor was also carried out by using the COMSOL Multiphysics program.",
keywords = "Fraction, Microchannel, Nickel-ceria catalyst, Water-gas shift, water-gas shift, OXIDATION, microchannel, COMBUSTION, KINETIC MEASUREMENTS, PERFORMANCE, fraction, CO METHANATION, nickel-ceria catalyst, STRUCTURED REACTORS, DISSOCIATION, CERIA, METAL, NI",
author = "Ludmilla Bobrova and Dmitry Andreev and Eugene Ivanov and Natalia Mezentseva and Mikhail Simonov and Lev Makarshin and Alexander Gribovskii and Vladislav Sadykov",
year = "2017",
month = oct,
day = "1",
doi = "10.3390/catal7100310",
language = "English",
volume = "7",
journal = "Catalysts",
issn = "2073-4344",
publisher = "MDPI AG",
number = "10",

}

RIS

TY - JOUR

T1 - Water-Gas shift reaction over Ni/CeO2 catalysts

AU - Bobrova, Ludmilla

AU - Andreev, Dmitry

AU - Ivanov, Eugene

AU - Mezentseva, Natalia

AU - Simonov, Mikhail

AU - Makarshin, Lev

AU - Gribovskii, Alexander

AU - Sadykov, Vladislav

PY - 2017/10/1

Y1 - 2017/10/1

N2 - This paper reports the results of a study of a water-gas shift reaction over nickel-ceria catalysts with different metal loading. Within this study, the overall CO conversion and observed kinetic behavior were investigated over the temperature range of 250-550 °C in different reactor configurations (fixed-bed and microchannel reactors). The quasi-steady state kinetics of the CO water-gas shift reaction was studied for fractions of Ni-containing cerium oxide catalysts in fixed-bed experiments at lab-scale level using a very dilute gas (1% CO + 1.8% H2O in Не). A set of experiments with a microchannel reactor was performed using the feed composition (CO:H2O:H2:N2 = 1:2:2:2), representing a product gas from methane partial oxidation. The results were interpreted using computational models. The kinetic parameters were determined by regression analysis, while mechanistic aspects were considered only briefly. Simulation of the WGS reaction in the microreactor was also carried out by using the COMSOL Multiphysics program.

AB - This paper reports the results of a study of a water-gas shift reaction over nickel-ceria catalysts with different metal loading. Within this study, the overall CO conversion and observed kinetic behavior were investigated over the temperature range of 250-550 °C in different reactor configurations (fixed-bed and microchannel reactors). The quasi-steady state kinetics of the CO water-gas shift reaction was studied for fractions of Ni-containing cerium oxide catalysts in fixed-bed experiments at lab-scale level using a very dilute gas (1% CO + 1.8% H2O in Не). A set of experiments with a microchannel reactor was performed using the feed composition (CO:H2O:H2:N2 = 1:2:2:2), representing a product gas from methane partial oxidation. The results were interpreted using computational models. The kinetic parameters were determined by regression analysis, while mechanistic aspects were considered only briefly. Simulation of the WGS reaction in the microreactor was also carried out by using the COMSOL Multiphysics program.

KW - Fraction

KW - Microchannel

KW - Nickel-ceria catalyst

KW - Water-gas shift

KW - water-gas shift

KW - OXIDATION

KW - microchannel

KW - COMBUSTION

KW - KINETIC MEASUREMENTS

KW - PERFORMANCE

KW - fraction

KW - CO METHANATION

KW - nickel-ceria catalyst

KW - STRUCTURED REACTORS

KW - DISSOCIATION

KW - CERIA

KW - METAL

KW - NI

UR - http://www.scopus.com/inward/record.url?scp=85032579276&partnerID=8YFLogxK

U2 - 10.3390/catal7100310

DO - 10.3390/catal7100310

M3 - Article

AN - SCOPUS:85032579276

VL - 7

JO - Catalysts

JF - Catalysts

SN - 2073-4344

IS - 10

M1 - 310

ER -

ID: 9745984