Standard

W5Br12·BiBr3 Cluster Phases with Different Crystal Structures. / Mikhaylov, M. A.; Sukhikh, T. S.; Guselnikova, T. Ya et al.

In: Journal of Structural Chemistry, Vol. 65, No. 11, 11.2024, p. 2285-2294.

Research output: Contribution to journal › Article › peer-review

Harvard

Mikhaylov, MA, Sukhikh, TS, Guselnikova, TY, Tsygankova, AR, Kleiman, EE & Sokolov, MN 2024, 'W5Br12·BiBr3 Cluster Phases with Different Crystal Structures', Journal of Structural Chemistry, vol. 65, no. 11, pp. 2285-2294. https://doi.org/10.1134/S0022476624110155

APA

Mikhaylov, M. A., Sukhikh, T. S., Guselnikova, T. Y., Tsygankova, A. R., Kleiman, E. E., & Sokolov, M. N. (2024). W5Br12·BiBr3 Cluster Phases with Different Crystal Structures. Journal of Structural Chemistry, 65(11), 2285-2294. https://doi.org/10.1134/S0022476624110155

Vancouver

Mikhaylov MA, Sukhikh TS, Guselnikova TY, Tsygankova AR, Kleiman EE, Sokolov MN. W5Br12·BiBr3 Cluster Phases with Different Crystal Structures. Journal of Structural Chemistry. 2024 Nov;65(11):2285-2294. doi: 10.1134/S0022476624110155

Author

Mikhaylov, M. A. ; Sukhikh, T. S. ; Guselnikova, T. Ya et al. / W5Br12·BiBr3 Cluster Phases with Different Crystal Structures. In: Journal of Structural Chemistry. 2024 ; Vol. 65, No. 11. pp. 2285-2294.

BibTeX

@article{bb84c5f7436547de9be7124b455eccf9,
title = "W5Br12·BiBr3 Cluster Phases with Different Crystal Structures",
abstract = "A mixture of two structurally different cluster phases I and II with the general chemical formula W5Br12·BiBr3 is obtained as a product of the WBr6 reduction reaction with elemental bismuth at 280 °C. The elemental composition of the mixture is determined by the energy-dispersive X-ray spectroscopy and inductively coupled plasma atomic emission spectrometry. For the single crystals selected from a mixture of phases I and II their crystal structures are determined, and the powder X-ray diffraction analysis is performed for the polycrystalline mixture. In the crystal structure of I, square-pyramidal cluster fragments are bridged by bromine atoms into infinite chains by the W–Bra–a–W interaction. In the structure of II, BiBr3 (W–{BraBiBrBra}–W) molecules incorporate into the chain instead of the bridging bromine atom.",
keywords = "ICP-AES, bismuth, bromides, clusters, low-temperature synthesis, polymer compounds, single crystal X-ray diffraction analysis, tungsten",
author = "Mikhaylov, {M. A.} and Sukhikh, {T. S.} and Guselnikova, {T. Ya} and Tsygankova, {A. R.} and Kleiman, {E. E.} and Sokolov, {M. N.}",
note = "The work was supported by Russian Science Foundation grant No. 24-23-00397.",
year = "2024",
month = nov,
doi = "10.1134/S0022476624110155",
language = "English",
volume = "65",
pages = "2285--2294",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "11",

}

RIS

TY - JOUR

T1 - W5Br12·BiBr3 Cluster Phases with Different Crystal Structures

AU - Mikhaylov, M. A.

AU - Sukhikh, T. S.

AU - Guselnikova, T. Ya

AU - Tsygankova, A. R.

AU - Kleiman, E. E.

AU - Sokolov, M. N.

N1 - The work was supported by Russian Science Foundation grant No. 24-23-00397.

PY - 2024/11

Y1 - 2024/11

N2 - A mixture of two structurally different cluster phases I and II with the general chemical formula W5Br12·BiBr3 is obtained as a product of the WBr6 reduction reaction with elemental bismuth at 280 °C. The elemental composition of the mixture is determined by the energy-dispersive X-ray spectroscopy and inductively coupled plasma atomic emission spectrometry. For the single crystals selected from a mixture of phases I and II their crystal structures are determined, and the powder X-ray diffraction analysis is performed for the polycrystalline mixture. In the crystal structure of I, square-pyramidal cluster fragments are bridged by bromine atoms into infinite chains by the W–Bra–a–W interaction. In the structure of II, BiBr3 (W–{BraBiBrBra}–W) molecules incorporate into the chain instead of the bridging bromine atom.

AB - A mixture of two structurally different cluster phases I and II with the general chemical formula W5Br12·BiBr3 is obtained as a product of the WBr6 reduction reaction with elemental bismuth at 280 °C. The elemental composition of the mixture is determined by the energy-dispersive X-ray spectroscopy and inductively coupled plasma atomic emission spectrometry. For the single crystals selected from a mixture of phases I and II their crystal structures are determined, and the powder X-ray diffraction analysis is performed for the polycrystalline mixture. In the crystal structure of I, square-pyramidal cluster fragments are bridged by bromine atoms into infinite chains by the W–Bra–a–W interaction. In the structure of II, BiBr3 (W–{BraBiBrBra}–W) molecules incorporate into the chain instead of the bridging bromine atom.

KW - ICP-AES

KW - bismuth

KW - bromides

KW - clusters

KW - low-temperature synthesis

KW - polymer compounds

KW - single crystal X-ray diffraction analysis

KW - tungsten

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85211175717&origin=inward&txGid=511e728fc6c726baf41d585df6dedff1

UR - https://www.mendeley.com/catalogue/1013d3ee-4025-37be-84d4-ba5c405264f0/

U2 - 10.1134/S0022476624110155

DO - 10.1134/S0022476624110155

M3 - Article

VL - 65

SP - 2285

EP - 2294

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 11

ER -

ID: 61285002