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Verdazyl Radical Building Blocks : Synthesis, Structure, and Sonogashira Cross-Coupling Reactions. / Petunin, Pavel V.; Martynko, Ekaterina A.; Trusova, Marina E. et al.

In: European Journal of Organic Chemistry, Vol. 2018, No. 34, 16.09.2018, p. 4802-4811.

Research output: Contribution to journal › Article › peer-review

Harvard

Petunin, PV, Martynko, EA, Trusova, ME, Kazantsev, MS, Rybalova, TV, Valiev, RR, Uvarov, MN, Mostovich, EA & Postnikov, PS 2018, 'Verdazyl Radical Building Blocks: Synthesis, Structure, and Sonogashira Cross-Coupling Reactions', European Journal of Organic Chemistry, vol. 2018, no. 34, pp. 4802-4811. https://doi.org/10.1002/ejoc.201701783

APA

Petunin, P. V., Martynko, E. A., Trusova, M. E., Kazantsev, M. S., Rybalova, T. V., Valiev, R. R., Uvarov, M. N., Mostovich, E. A., & Postnikov, P. S. (2018). Verdazyl Radical Building Blocks: Synthesis, Structure, and Sonogashira Cross-Coupling Reactions. European Journal of Organic Chemistry, 2018(34), 4802-4811. https://doi.org/10.1002/ejoc.201701783

Vancouver

Petunin PV, Martynko EA, Trusova ME, Kazantsev MS, Rybalova TV, Valiev RR et al. Verdazyl Radical Building Blocks: Synthesis, Structure, and Sonogashira Cross-Coupling Reactions. European Journal of Organic Chemistry. 2018 Sept 16;2018(34):4802-4811. doi: 10.1002/ejoc.201701783

Author

Petunin, Pavel V. ; Martynko, Ekaterina A. ; Trusova, Marina E. et al. / Verdazyl Radical Building Blocks : Synthesis, Structure, and Sonogashira Cross-Coupling Reactions. In: European Journal of Organic Chemistry. 2018 ; Vol. 2018, No. 34. pp. 4802-4811.

BibTeX

@article{792a18719e694291abbb35b84dc081eb,
title = "Verdazyl Radical Building Blocks: Synthesis, Structure, and Sonogashira Cross-Coupling Reactions",
abstract = "A general and effective method for the synthesis of 3-phenylveradzyl radicals bearing a variety of iodophenyl substituents has been developed. The synthesized radicals have been characterized by ESR, UV/Vis spectroscopy, and cyclic voltammetry. Structures of biphenyl-substituted radicals have been solved by X-ray crystal structure analysis. The synthesized iodoverdazyls are applicable in the Sonogashira coupling reaction for the preparation of a wide range of ethynyl derivatives. Both N-2 and C-6 substituents were functionalized through Sonogashira coupling.",
keywords = "Cross-coupling, Density functional calculations, Nitrogen heterocycles, Verdazyl radicals",
author = "Petunin, {Pavel V.} and Martynko, {Ekaterina A.} and Trusova, {Marina E.} and Kazantsev, {Maxim S.} and Rybalova, {Tatyana V.} and Valiev, {Rashid R.} and Uvarov, {Mikhail N.} and Mostovich, {Evgeny A.} and Postnikov, {Pavel S.}",
note = "Publisher Copyright: {\textcopyright} 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",
year = "2018",
month = sep,
day = "16",
doi = "10.1002/ejoc.201701783",
language = "English",
volume = "2018",
pages = "4802--4811",
journal = "European Journal of Organic Chemistry",
issn = "1434-193X",
publisher = "Wiley-Blackwell",
number = "34",

}

RIS

TY - JOUR

T1 - Verdazyl Radical Building Blocks

T2 - Synthesis, Structure, and Sonogashira Cross-Coupling Reactions

AU - Petunin, Pavel V.

AU - Martynko, Ekaterina A.

AU - Trusova, Marina E.

AU - Kazantsev, Maxim S.

AU - Rybalova, Tatyana V.

AU - Valiev, Rashid R.

AU - Uvarov, Mikhail N.

AU - Mostovich, Evgeny A.

AU - Postnikov, Pavel S.

N1 - Publisher Copyright: © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

PY - 2018/9/16

Y1 - 2018/9/16

N2 - A general and effective method for the synthesis of 3-phenylveradzyl radicals bearing a variety of iodophenyl substituents has been developed. The synthesized radicals have been characterized by ESR, UV/Vis spectroscopy, and cyclic voltammetry. Structures of biphenyl-substituted radicals have been solved by X-ray crystal structure analysis. The synthesized iodoverdazyls are applicable in the Sonogashira coupling reaction for the preparation of a wide range of ethynyl derivatives. Both N-2 and C-6 substituents were functionalized through Sonogashira coupling.

AB - A general and effective method for the synthesis of 3-phenylveradzyl radicals bearing a variety of iodophenyl substituents has been developed. The synthesized radicals have been characterized by ESR, UV/Vis spectroscopy, and cyclic voltammetry. Structures of biphenyl-substituted radicals have been solved by X-ray crystal structure analysis. The synthesized iodoverdazyls are applicable in the Sonogashira coupling reaction for the preparation of a wide range of ethynyl derivatives. Both N-2 and C-6 substituents were functionalized through Sonogashira coupling.

KW - Cross-coupling

KW - Density functional calculations

KW - Nitrogen heterocycles

KW - Verdazyl radicals

UR - http://www.scopus.com/inward/record.url?scp=85053324309&partnerID=8YFLogxK

U2 - 10.1002/ejoc.201701783

DO - 10.1002/ejoc.201701783

M3 - Article

AN - SCOPUS:85053324309

VL - 2018

SP - 4802

EP - 4811

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

SN - 1434-193X

IS - 34

ER -

ID: 16600127