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UV-photoexcitation of encounter complexes of oxygen O2–O2 as a source of singlet oxygen O2(1Δg) in gas phase. / Пыряева, Александра Павловна; Goldort, Veniamin G.; Kochubei, Sergei A. et al.

In: Chemical Physics Letters, Vol. 485, No. 1-3, 18.01.2010, p. 11-15.

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Пыряева АП, Goldort VG, Kochubei SA, Бакланов АВ. UV-photoexcitation of encounter complexes of oxygen O2–O2 as a source of singlet oxygen O2(1Δg) in gas phase. Chemical Physics Letters. 2010 Jan 18;485(1-3):11-15. doi: 10.1016/j.cplett.2009.11.058

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Пыряева, Александра Павловна ; Goldort, Veniamin G. ; Kochubei, Sergei A. et al. / UV-photoexcitation of encounter complexes of oxygen O2–O2 as a source of singlet oxygen O2(1Δg) in gas phase. In: Chemical Physics Letters. 2010 ; Vol. 485, No. 1-3. pp. 11-15.

BibTeX

@article{d7ba9e386fa94ddca8f42a6d9a54b309,
title = "UV-photoexcitation of encounter complexes of oxygen O2–O2 as a source of singlet oxygen O2(1Δg) in gas phase",
abstract = "The photogeneration of singlet oxygen O2(a1Δg) resulted from the photoexcitation at 248 nm of gaseous oxygen at elevated pressure (3-80 atm) has been investigated. Singlet oxygen monitored by its IR-luminescence at 1.27 μm was found to appear via two processes which are identified to be due to absorption of individual O2 molecules and encounter complexes O2-O2, respectively. The one-quantum absorption of complexes gives rise to appearance of oxygen in Herzberg III state O2(3Δu) which is supposed to be a triplet sensitizer responsible for singlet oxygen O2(a1Δg) production observed in our experiments. {\textcopyright} 2009 Elsevier B.V. All rights reserved.",
author = "Пыряева, {Александра Павловна} and Goldort, {Veniamin G.} and Kochubei, {Sergei A.} and Бакланов, {Алексей Васильевич}",
note = "The financial support of this work by Russian Foundation for Basic Research (Grant No. 09-03-00310-a) is gratefully acknowledged.",
year = "2010",
month = jan,
day = "18",
doi = "10.1016/j.cplett.2009.11.058",
language = "English",
volume = "485",
pages = "11--15",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "1-3",

}

RIS

TY - JOUR

T1 - UV-photoexcitation of encounter complexes of oxygen O2–O2 as a source of singlet oxygen O2(1Δg) in gas phase

AU - Пыряева, Александра Павловна

AU - Goldort, Veniamin G.

AU - Kochubei, Sergei A.

AU - Бакланов, Алексей Васильевич

N1 - The financial support of this work by Russian Foundation for Basic Research (Grant No. 09-03-00310-a) is gratefully acknowledged.

PY - 2010/1/18

Y1 - 2010/1/18

N2 - The photogeneration of singlet oxygen O2(a1Δg) resulted from the photoexcitation at 248 nm of gaseous oxygen at elevated pressure (3-80 atm) has been investigated. Singlet oxygen monitored by its IR-luminescence at 1.27 μm was found to appear via two processes which are identified to be due to absorption of individual O2 molecules and encounter complexes O2-O2, respectively. The one-quantum absorption of complexes gives rise to appearance of oxygen in Herzberg III state O2(3Δu) which is supposed to be a triplet sensitizer responsible for singlet oxygen O2(a1Δg) production observed in our experiments. © 2009 Elsevier B.V. All rights reserved.

AB - The photogeneration of singlet oxygen O2(a1Δg) resulted from the photoexcitation at 248 nm of gaseous oxygen at elevated pressure (3-80 atm) has been investigated. Singlet oxygen monitored by its IR-luminescence at 1.27 μm was found to appear via two processes which are identified to be due to absorption of individual O2 molecules and encounter complexes O2-O2, respectively. The one-quantum absorption of complexes gives rise to appearance of oxygen in Herzberg III state O2(3Δu) which is supposed to be a triplet sensitizer responsible for singlet oxygen O2(a1Δg) production observed in our experiments. © 2009 Elsevier B.V. All rights reserved.

UR - https://www.mendeley.com/catalogue/8e2efdcc-b904-3611-87fa-ec6ea79090c6/

U2 - 10.1016/j.cplett.2009.11.058

DO - 10.1016/j.cplett.2009.11.058

M3 - Article

VL - 485

SP - 11

EP - 15

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 1-3

ER -

ID: 56406709