Using Low-Temperature Molten Dialkylimidazole Salts in the Catalytic Reactions of Alkylation and Hydrodechlorination. / Klimenko, A. S.; Prikhod’ko, S. A.; Beskopyl’nyi, A. M. et al.
In: Catalysis in Industry, Vol. 10, No. 4, 01.10.2018, p. 313-320.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Using Low-Temperature Molten Dialkylimidazole Salts in the Catalytic Reactions of Alkylation and Hydrodechlorination
AU - Klimenko, A. S.
AU - Prikhod’ko, S. A.
AU - Beskopyl’nyi, A. M.
AU - Tertishnikov, I. V.
AU - Adonin, N. Yu
N1 - Publisher Copyright: © 2018, Pleiades Publishing, Ltd.
PY - 2018/10/1
Y1 - 2018/10/1
N2 - The possibility of preparing a mixture of 1,3-dialkylimidazole salts from commercially available reagents via multicomponent condensation is considered. The main factors affecting the yield of the target product, and the experimental data needed for scaling up the process, are discussed. It is shown that the prepared mixtures are close in some key properties (e.g., viscosity at different temperatures, heat capacity) to the pure salts. The possibility of using the prepared salts as solvents for catalytic hydrodechlorination and catalyst components for the alkylation of aromatic compounds is demonstrated.
AB - The possibility of preparing a mixture of 1,3-dialkylimidazole salts from commercially available reagents via multicomponent condensation is considered. The main factors affecting the yield of the target product, and the experimental data needed for scaling up the process, are discussed. It is shown that the prepared mixtures are close in some key properties (e.g., viscosity at different temperatures, heat capacity) to the pure salts. The possibility of using the prepared salts as solvents for catalytic hydrodechlorination and catalyst components for the alkylation of aromatic compounds is demonstrated.
KW - alkylation
KW - condensation
KW - hydrodechlorination
KW - ionic liquids
KW - persistent organic pollutants
KW - polychlorinated aromatic compounds
UR - http://www.scopus.com/inward/record.url?scp=85060138239&partnerID=8YFLogxK
U2 - 10.1134/S2070050418040086
DO - 10.1134/S2070050418040086
M3 - Article
AN - SCOPUS:85060138239
VL - 10
SP - 313
EP - 320
JO - Catalysis in Industry
JF - Catalysis in Industry
SN - 2070-0504
IS - 4
ER -
ID: 25412585